ChemicalBook > CAS DataBase List > 4-METHOXY-3-METHYLBENZYL CHLORIDE

4-METHOXY-3-METHYLBENZYL CHLORIDE

Product Name
4-METHOXY-3-METHYLBENZYL CHLORIDE
CAS No.
60736-71-2
Chemical Name
4-METHOXY-3-METHYLBENZYL CHLORIDE
Synonyms
-1-methoxy-2-methylbenzene;4-METHOXY-3-METHYLBENZYL CHLORIDE;4-Methoxy-3-methylbenzyl chloride ,98%;4-(chloroMethyl)-1-Methoxy-2-Methylbenzene;4-(Chloromethyl)-2-methylphenyl methyl ether;Benzene, 4-(chloromethyl)-1-methoxy-2-methyl-;Benzene, 4-(chloromethyl)-1-methoxy-2-methyl- (9CI);4-Methoxy-3-methylbenzyl chloride (stabilised with calcium carbonate);4-METHOXY-3-METHYLBENZYL CHLORIDE (STABILIZED WITH CALCIUM CARBONATE);4-Methoxy-3-methylbenzyl chloride, 98% (Stabilized with Calcium carbote)
CBNumber
CB7244537
Molecular Formula
C9H11ClO
Formula Weight
170.64
MOL File
60736-71-2.mol
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4-METHOXY-3-METHYLBENZYL CHLORIDE Property

Boiling point:
143°C 25mm
Density 
1,11 g/cm3
storage temp. 
Storage temp. 2-8°C
Appearance
Colorless to light yellow Liquid
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
RIDADR 
UN1760
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
C597898
Product name
4-(Chloromethyl)-1-methoxy-2-methylbenzene
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
C597898
Product name
4-(Chloromethyl)-1-methoxy-2-methylbenzene
Packaging
100mg
Price
$60
Updated
2021/12/16
SynQuest Laboratories
Product number
2707-5-03
Product name
4-Methoxy-3-methylbenzyl chloride (Stabilized with Calcium carbonate)
Purity
98%
Packaging
250mg
Price
$52
Updated
2021/12/16
AK Scientific
Product number
9079AB
Product name
4-(Chloromethyl)-1-methoxy-2-methylbenzene
Packaging
250mg
Price
$104
Updated
2021/12/16
SynQuest Laboratories
Product number
2707-5-03
Product name
4-Methoxy-3-methylbenzyl chloride (Stabilized with Calcium carbonate)
Purity
98%
Packaging
1g
Price
$106
Updated
2021/12/16
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4-METHOXY-3-METHYLBENZYL CHLORIDE Chemical Properties,Usage,Production

Synthesis

67-72-1

114787-91-6

60736-71-2

The general procedure for the synthesis of 4-methoxy-3-methylbenzyl chloride from hexachloroethane and 4-methoxy-3-methylbenzyl alcohol is as follows: to a stirred solution of 4-methoxy-3-methylbenzyl alcohol (2.31 g, 15.18 mmol, 1 eq.) in anhydrous methylene chloride (50 mL, 0.3 M) was added hexachloroethane (3.59 g, 15.18 mmol, 1 eq.) and triphenylphosphine (3.98 g, 15.18 mmol, 1 eq.) in sequence. ) and triphenylphosphine (3.98 g, 15.18 mmol, 1 eq.). The reaction mixture was stirred at room temperature overnight. After completion of the reaction, the mixture was transferred to a partition funnel, washed sequentially with water and brine, the organic phase was dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: 30% ethyl acetate/hexane) to afford the target product 4-methoxy-3-methylbenzyl chloride (2.59 g, 100% yield). The structure of the product was confirmed by 1H NMR (CDCl3, 400 MHz): δ 7.16 (m, 2H), 6.76 (d, 1H, J = 8.10 Hz), 4.52 (s, 2H), 3.81 (s, 3H), 2.19 (s, 3H).

References

[1] Patent: US2004/72838, 2004, A1

4-METHOXY-3-METHYLBENZYL CHLORIDE Preparation Products And Raw materials

Raw materials

Formaldehyde 2-Methylanisole Hydrochloric acid

Preparation Products

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4-METHOXY-3-METHYLBENZYL CHLORIDE Suppliers

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60736-71-2, 4-METHOXY-3-METHYLBENZYL CHLORIDERelated Search:

4-METHOXY-3-METHYLBENZYL CHLORIDE 2,3-DIHYDRO-1-BENZOFURAN-5-CARBONYL CHLORIDE 4-METHOXY-3-(TRIFLUOROMETHYL)BENZOYL CHLORIDE 3-Methylbenzyl chloride 2-METHYL-2,3-DIHYDRO-BENZOFURAN-5-CARBONYL CHLORIDE 4-methoxyisophthaloyl dichloride HEXACHLOROMETHYL-HEXAMETHOXYCALIX-[6]ARENE 5-CHLOROMETHYL-2,3-DIHYDROBENZOFURAN 3-METHOXY-4-METHYLBENZYL CHLORIDE CARBONIC ACID 4-CHLOROMETHYL-2,3-DIMETHYL-PHENYL ESTER ETHYL ESTER AKOS B011890 Methyl 4-acetamido-5-(chloromethyl)-2-methoxybenzoate AKOS B020900 2,4-BIS(CHLOROMETHYL)DIPHENYLOXIDE 1-(5-CHLOROMETHYL-2,4-DIMETHOXY-PHENYL)-ETHANONE 1-(CHLOROMETHYL)-4-METHOXY-2,3-DIMETHYLBENZENE 5,11,17,23-CHLOROMETHYL-25,26,27,28-TETRAPROPOXY-CALIX[4]ARENE 7-(CHLOROMETHYL)-4,5,6-TRIETHOXY-2-BENZOFURAN-1(3H)-ONE

  • 4-(Chloromethyl)-2-methylphenyl methyl ether
  • 4-Methoxy-3-methylbenzyl chloride (stabilised with calcium carbonate)
  • 4-METHOXY-3-METHYLBENZYL CHLORIDE
  • Benzene, 4-(chloromethyl)-1-methoxy-2-methyl- (9CI)
  • 4-METHOXY-3-METHYLBENZYL CHLORIDE (STABILIZED WITH CALCIUM CARBONATE)
  • 4-Methoxy-3-methylbenzyl chloride ,98%
  • 4-(chloroMethyl)-1-Methoxy-2-Methylbenzene
  • 4-Methoxy-3-methylbenzyl chloride, 98% (Stabilized with Calcium carbote)
  • Benzene, 4-(chloromethyl)-1-methoxy-2-methyl-
  • -1-methoxy-2-methylbenzene
  • 60736-71-2
  • BENZYL HALIDE
  • HALOMETYL