ChemicalBook > CAS DataBase List > DI(1H-IMIDAZOL-1-YL)METHANIMINE

DI(1H-IMIDAZOL-1-YL)METHANIMINE

Product Name
DI(1H-IMIDAZOL-1-YL)METHANIMINE
CAS No.
104619-51-4
Chemical Name
DI(1H-IMIDAZOL-1-YL)METHANIMINE
Synonyms
EOS-60817;Di(1-iMidazolyl)MethaniMine;Di (1H imidazol-1-yl) imine;di(imidazol-1-yl)methanimine;Di(1H-imidazol-2-yl)methanimine;DI(1H-IMIDAZOL-1-YL)METHANIMINE;Di (1 hydrogen imidazolyl) imine;C,C-di(imidazol-1-yl)methaneimine;1,1'-Carbonimidoylbis-1H-imidazole;1,1'-Carbonimidoylbis[1H-imidazole
CBNumber
CB72454846
Molecular Formula
C7H7N5
Formula Weight
161.16
MOL File
104619-51-4.mol
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DI(1H-IMIDAZOL-1-YL)METHANIMINE Property

Melting point:
103-104℃
Boiling point:
355℃
Density 
1.38
Flash point:
169℃
storage temp. 
Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka
4.19±0.70(Predicted)
Appearance
White to off-white Solid
InChI
InChI=1S/C7H7N5/c8-7(11-3-1-9-5-11)12-4-2-10-6-12/h1-6,8H
InChIKey
FKGQRXQOODICAT-UHFFFAOYSA-N
SMILES
C(N1C=NC=C1)(N1C=NC=C1)=N
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Safety

HS Code 
2933299090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC
Product number
D476993
Product name
Di(1H-imidazol-1-yl)methanimine
Packaging
50mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC45505
Product name
1,1'-Carbonimidoylbis-1H-imidazole
Packaging
2g
Price
$110
Updated
2021/12/16
Apolloscientific
Product number
OR917034
Product name
1,1'-Carbonimidoylbis-1H-imidazole
Purity
95%
Packaging
1g
Price
$155
Updated
2021/12/16
ChemScene
Product number
CS-D0450
Product name
1,1'-Carbonimidoylbis[1H-imidazole]
Packaging
5g
Price
$184
Updated
2021/12/16
ChemScene
Product number
CS-D0450
Product name
1,1'-Carbonimidoylbis[1H-imidazole]
Packaging
1g
Price
$55
Updated
2021/12/16
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DI(1H-IMIDAZOL-1-YL)METHANIMINE Chemical Properties,Usage,Production

Synthesis

288-32-4

506-68-3

104619-51-4

Cyanogen bromide (22.5 g, 212 mmol) was slowly added to a solution of 1H-imidazole (42 g, 617 mmol) in dichloromethane (1 L) and the reaction mixture was heated to reflux for 30 min. After completion of the reaction, it was cooled to room temperature and white solid was observed to precipitate. The solid was separated by filtration. The filtrate was concentrated under reduced pressure to about 100 mL and subsequently allowed to stand in a refrigerator for 3 days to promote crystallization. The precipitated solid was collected by filtration to give the final bis(1H-imidazol-1-yl)methanimine (8 g, 49.6 mmol, 8% yield).

References

[1] Patent: US2012/149718, 2012, A1. Location in patent: Page/Page column 35
[2] Journal of Organic Chemistry, 2002, vol. 67, # 21, p. 7553 - 7556
[3] Journal of Heterocyclic Chemistry, 2003, vol. 40, # 1, p. 191 - 193
[4] Chemical Communications, 2014, vol. 50, # 91, p. 14257 - 14260
[5] Patent: WO2012/85586, 2012, A1. Location in patent: Page/Page column 66; 68

DI(1H-IMIDAZOL-1-YL)METHANIMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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DI(1H-IMIDAZOL-1-YL)METHANIMINE Suppliers

Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
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View Lastest Price from DI(1H-IMIDAZOL-1-YL)METHANIMINE manufacturers

Career Henan Chemical Co
Product
DI(1H-IMIDAZOL-1-YL)METHANIMINE 104619-51-4
Price
US $2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
customise
Release date
2018-08-09

104619-51-4, DI(1H-IMIDAZOL-1-YL)METHANIMINERelated Search:


  • DI(1H-IMIDAZOL-1-YL)METHANIMINE
  • C,C-di(imidazol-1-yl)methaneimine
  • 1,1'-Carbonimidoylbis-1H-imidazole
  • Di(1-iMidazolyl)MethaniMine
  • Di(1H-imidazol-2-yl)methanimine
  • 1-(1H-imidazole-1-carboximidoyl)-1H-imidazole
  • di(imidazol-1-yl)methanimine
  • EOS-60817
  • 1H-IMidazole, 1,1'-carboniMidoylbis-
  • C-(Di-iMidazol-1-yl)-MethyleneaMine
  • 1,1-Di(1H-imidazol-1-yl)methanimine
  • Di (1H imidazol-1-yl) imine
  • 1,1'-Carbonimidoylbis[1H-imidazole
  • 1-(IMIDAZOLE-1-CARBOXIMIDOYL)IMIDAZOLE
  • Di (1 hydrogen imidazolyl) imine
  • 104619-51-4