ChemicalBook > CAS DataBase List > 1-BROMO-3-METHOXY-2-METHYLBENZENE

1-BROMO-3-METHOXY-2-METHYLBENZENE

Product Name: 1-BROMO-3-METHOXY-2-METHYLBENZENE
CAS No.: 31804-36-1
Chemical Name: 1-BROMO-3-METHOXY-2-METHYLBENZENE
Synonyms: 2-Methyl-3-bromoanisole;3-Bromo-2-methylanisole;1-BROMO-3-METHOXY-2-METHYLBENZENE;Benzene, 1-bromo-3-methoxy-2-methyl-
CBNumber: CB72455883
Molecular Formula: C8H9BrO
Formula Weight: 201.06
MOL File: 31804-36-1.mol

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1-BROMO-3-METHOXY-2-METHYLBENZENE Property

Melting point:: 150-151 °C
Boiling point:: 108 °C(Press: 9 Torr)
Density: 1.378±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: liquid
color: Yellow
InChI: InChI=1S/C8H9BrO/c1-6-7(9)4-3-5-8(6)10-2/h3-5H,1-2H3
InChIKey: SBMVNLFBEJAXFY-UHFFFAOYSA-N
SMILES: C1(Br)=CC=CC(OC)=C1C

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Safety

HS Code: 2909309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B696963
Product name: 3-Bromo-2-methylanisole
Packaging: 500mg
Price: $85
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB156458
Product name: 3-Bromo-2-methylanisole
Packaging: 2g
Price: $112
Updated: 2021/12/16

Matrix Scientific

Product number: 074182
Product name: 3-Bromo-2-methylanisole
Purity: 95+%
Packaging: 1g
Price: $57
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB156458
Product name: 3-Bromo-2-methylanisole
Packaging: 1g
Price: $60
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2707-9-01
Product name: 3-Bromo-2-methylanisole
Purity: 95%
Packaging: 1g
Price: $168
Updated: 2021/12/16

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1-BROMO-3-METHOXY-2-METHYLBENZENE Chemical Properties,Usage,Production

Synthesis

7766-23-6

74-88-4

31804-36-1

General procedure for the synthesis of 3-bromo-2-methylanisole from 3-bromo-2-methylphenol and iodomethane: 1. 3-Bromo-2-methylphenol (500 mg, 2.67 mmol) and potassium carbonate (1108 mg, 8.02 mmol) were added to dry DMF (10 mL) and stirred for 5 minutes at room temperature. 2. To the above mixture, iodomethane (0.836 mL, 13.37 mmol) was slowly added, and the reaction system was subsequently warmed up to 50 °C with continuous stirring for 2 hours. 3. After completion of the reaction, the mixture was poured into water (30 mL) and extracted with ethyl acetate (20 mL + 3 x 20 mL). 4. The organic phases were combined and concentrated under reduced pressure to afford the target product 3-bromo-2-methylanisole (450 mg, 80% yield). 5. The product was analyzed by LC-MS. 5. The product was analyzed by LC-MS and showed m/z 305.9 (M + H)+ with a retention time of 1.09 min.

References

[1] Synlett, 2009, # 15, p. 2483 - 2486
[2] Angewandte Chemie - International Edition, 2018, vol. 57, # 34, p. 11040 - 11044
[3] Angew. Chem., 2018, vol. 130, # 34, p. 11206 - 11210,5
[4] Chemical Communications, 2003, # 10, p. 1170 - 1171
[5] Patent: WO2015/92713, 2015, A1. Location in patent: Page/Page column 201

1-BROMO-3-METHOXY-2-METHYLBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BROMO-3-METHOXY-2-METHYLBENZENE Suppliers

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View Lastest Price from 1-BROMO-3-METHOXY-2-METHYLBENZENE manufacturers

Career Henan Chemical Co

Product: 1-BROMO-3-METHOXY-2-METHYLBENZENE 31804-36-1
Price: US $3.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,50kg
Release date: 2020-01-18

31804-36-1, 1-BROMO-3-METHOXY-2-METHYLBENZENERelated Search:

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1-BROMO-3-METHOXY-2-METHYLBENZENE

3-Bromo-2-methylanisole

2-Methyl-3-bromoanisole

Benzene, 1-bromo-3-methoxy-2-methyl-

31804-36-1