ChemicalBook > CAS DataBase List > 2-Amino-4-(benzyloxy)pyridine

2-Amino-4-(benzyloxy)pyridine

Product Name: 2-Amino-4-(benzyloxy)pyridine
CAS No.: 85333-26-2
Chemical Name: 2-Amino-4-(benzyloxy)pyridine
Synonyms: 4-(Benzyloxy)pyridin-2-amine;2-Amino-4-(benzyloxy)pyridine;4-phenylmethoxypyridin-2-amine;4-phenylmethoxy-2-pyridinamine;2-Pyridinamine, 4-(phenylmethoxy)-;4-(benzyloxy)pyridin-2-amine - [B87559]
CBNumber: CB72470314
Molecular Formula: C12H12N2O
Formula Weight: 200.24
MOL File: 85333-26-2.mol

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2-Amino-4-(benzyloxy)pyridine Property

Boiling point:: 379.7±27.0 °C(Predicted)
Density: 1.180
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 7.76±0.11(Predicted)
Appearance: Light yellow to yellow Solid
InChI: InChI=1S/C12H12N2O/c13-12-8-11(6-7-14-12)15-9-10-4-2-1-3-5-10/h1-8H,9H2,(H2,13,14)
InChIKey: RAFCWIXBEWVPGL-UHFFFAOYSA-N
SMILES: C1(N)=NC=CC(OCC2=CC=CC=C2)=C1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B288050
Product name: 4-(Benzyloxy)pyridin-2-amine
Packaging: 500mg
Price: $110
Updated: 2021/12/16

AK Scientific

Product number: W8806
Product name: 4-(Benzyloxy)-2-pyridinamine
Packaging: 1g
Price: $117
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB153561
Product name: 4-(Benzyloxy)pyridin-2-amine
Packaging: 2g
Price: $170
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB153561
Product name: 4-(Benzyloxy)pyridin-2-amine
Packaging: 500mg
Price: $55
Updated: 2021/12/16

Matrix Scientific

Product number: 075559
Product name: 4-(Benzyloxy)pyridin-2-amine
Purity: 95+%
Packaging: 1g
Price: $278
Updated: 2021/12/16

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2-Amino-4-(benzyloxy)pyridine Chemical Properties,Usage,Production

Synthesis

182556-72-5

85333-26-2

Step A: Preparation of 4-(benzyloxy)pyridin-2-amine: 4-(benzyloxy)-2-chloropyridine (1.10 g, 5.01 mmol), Pd2dba3 (46 mg, 0.05 mmol), and 2-(dicyclohexylphosphino)-2',4',6'-tripropyl-1,1 '-biphenyl (57 mg, 0.120 mmol) were dissolved in THF (10 mL) in THF (10 mL) and a 1.0 M solution of ammonia in THF (6 mL) was added. The mixture was heated to 65 °C for 30 min of reaction and then cooled to room temperature. The reaction mixture was concentrated by a silica gel column and eluted with a 20:1 solvent mixture of ethyl acetate/methanol to give a light golden solid product (0.97 g, 96% yield).

References

[1] Patent: EP2090575, 2009, A1. Location in patent: Page/Page column 54-55
[2] Patent: WO2018/65365, 2018, A1. Location in patent: Page/Page column 114-115
[3] Patent: WO2007/89512, 2007, A1. Location in patent: Page/Page column 181

2-Amino-4-(benzyloxy)pyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-Amino-4-(benzyloxy)pyridine manufacturers

Shanghai Rlavie Technology Co ltd

Product: 4-phenylmethoxy-2-pyridinamine 85333-26-2
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 98%minHPLC
Supply Ability: 500kgs/month
Release date: 2021-11-20

85333-26-2, 2-Amino-4-(benzyloxy)pyridineRelated Search:

2-Amino-4-(benzyloxy)pyridine

4-(Benzyloxy)pyridin-2-amine

4-phenylmethoxy-2-pyridinamine

4-phenylmethoxypyridin-2-amine

2-Pyridinamine, 4-(phenylmethoxy)-

4-(benzyloxy)pyridin-2-amine - [B87559]

85333-26-2