2-Amino-4-(benzyloxy)pyridine
- Product Name
- 2-Amino-4-(benzyloxy)pyridine
- CAS No.
- 85333-26-2
- Chemical Name
- 2-Amino-4-(benzyloxy)pyridine
- Synonyms
- 4-(Benzyloxy)pyridin-2-amine;2-Amino-4-(benzyloxy)pyridine;4-phenylmethoxypyridin-2-amine;4-phenylmethoxy-2-pyridinamine;2-Pyridinamine, 4-(phenylmethoxy)-;4-(benzyloxy)pyridin-2-amine - [B87559]
- CBNumber
- CB72470314
- Molecular Formula
- C12H12N2O
- Formula Weight
- 200.24
- MOL File
- 85333-26-2.mol
2-Amino-4-(benzyloxy)pyridine Property
- Boiling point:
- 379.7±27.0 °C(Predicted)
- Density
- 1.180
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 7.76±0.11(Predicted)
- Appearance
- Light yellow to yellow Solid
- InChI
- InChI=1S/C12H12N2O/c13-12-8-11(6-7-14-12)15-9-10-4-2-1-3-5-10/h1-8H,9H2,(H2,13,14)
- InChIKey
- RAFCWIXBEWVPGL-UHFFFAOYSA-N
- SMILES
- C1(N)=NC=CC(OCC2=CC=CC=C2)=C1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B288050
- Product name
- 4-(Benzyloxy)pyridin-2-amine
- Packaging
- 500mg
- Price
- $110
- Updated
- 2021/12/16
- Product number
- FB153561
- Product name
- 4-(Benzyloxy)pyridin-2-amine
- Packaging
- 500mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- W8806
- Product name
- 4-(Benzyloxy)-2-pyridinamine
- Packaging
- 1g
- Price
- $117
- Updated
- 2021/12/16
- Product number
- FB153561
- Product name
- 4-(Benzyloxy)pyridin-2-amine
- Packaging
- 2g
- Price
- $170
- Updated
- 2021/12/16
- Product number
- 075559
- Product name
- 4-(Benzyloxy)pyridin-2-amine
- Purity
- 95+%
- Packaging
- 1g
- Price
- $278
- Updated
- 2021/12/16
2-Amino-4-(benzyloxy)pyridine Chemical Properties,Usage,Production
Synthesis
182556-72-5
85333-26-2
Step A: Preparation of 4-(benzyloxy)pyridin-2-amine: 4-(benzyloxy)-2-chloropyridine (1.10 g, 5.01 mmol), Pd2dba3 (46 mg, 0.05 mmol), and 2-(dicyclohexylphosphino)-2',4',6'-tripropyl-1,1 '-biphenyl (57 mg, 0.120 mmol) were dissolved in THF (10 mL) in THF (10 mL) and a 1.0 M solution of ammonia in THF (6 mL) was added. The mixture was heated to 65 °C for 30 min of reaction and then cooled to room temperature. The reaction mixture was concentrated by a silica gel column and eluted with a 20:1 solvent mixture of ethyl acetate/methanol to give a light golden solid product (0.97 g, 96% yield).
References
[1] Patent: EP2090575, 2009, A1. Location in patent: Page/Page column 54-55
[2] Patent: WO2018/65365, 2018, A1. Location in patent: Page/Page column 114-115
[3] Patent: WO2007/89512, 2007, A1. Location in patent: Page/Page column 181
2-Amino-4-(benzyloxy)pyridine Preparation Products And Raw materials
Raw materials
Preparation Products
2-Amino-4-(benzyloxy)pyridine Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from 2-Amino-4-(benzyloxy)pyridine manufacturers
- Product
- 4-phenylmethoxy-2-pyridinamine 85333-26-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 98%minHPLC
- Supply Ability
- 500kgs/month
- Release date
- 2021-11-20