ChemicalBook > CAS DataBase List > Tetrabutylammonium fluoride trihydrate

Tetrabutylammonium fluoride trihydrate

Product Name
Tetrabutylammonium fluoride trihydrate
CAS No.
87749-50-6
Chemical Name
Tetrabutylammonium fluoride trihydrate
Synonyms
TBAF 3H2O;TETRABUTYLAMMONIUM FLUORIDE HYDRATE;TETRA-N-BUTYLAMMONIUM FLUORIDE 3 H2O;TBAF TRIHYDRATE;TBAF Hydrate;TETRABUTYLAMMONIUMFLUORID-3-HYDRAT;TETRA-N-BUTYLAMMONIUM FLUORIDE TRIHYDRATE;1-Butanaminium, N,N,N-tributyl-, fluoride, trihydrate;Tetra(but-1-;uoride hydrate
CBNumber
CB7247235
Molecular Formula
C16H38FNO
Formula Weight
279.48
MOL File
87749-50-6.mol
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Tetrabutylammonium fluoride trihydrate Property

Melting point:
62-63 °C(lit.)
Flash point:
-17℃
storage temp. 
Store below +30°C.
form 
Crystalline Powder, Crystals and/or Chunks
Specific Gravity
0.887
color 
White to slightly yellow
PH
pH (50g/l, 25℃) : 5.0～8.0
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
BRN 
3761900
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
InChI
InChI=1S/C16H36N.FH.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;/h5-16H2,1-4H3;1H;1H2/q+1;;/p-1
InChIKey
UQCWXKSHRQJGPH-UHFFFAOYSA-M
SMILES
[N+](CCCC)(CCCC)(CCCC)CCCC.[F-].O
CAS DataBase Reference
87749-50-6(CAS DataBase Reference)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34-36/37/38
Safety Statements 
26-36/37/39-45-26 37/39
RIDADR 
UN 1759 8/PG 1
WGK Germany 
3
F 
3-10
Hazard Note 
Irritant
TSCA 
T
HazardClass 
6.1
PackingGroup 
II
HS Code 
38220000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
86843
Product name
Tetrabutylammonium fluoride trihydrate
Purity
technical, ≥90% (T)
Packaging
50g
Price
$213
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18164
Product name
Tetra-n-butylammonium fluoride trihydrate
Purity
for synthesis
Packaging
5G
Price
$70.5
Updated
2024/03/01
Sigma-Aldrich
Product number
86843
Product name
Tetrabutylammonium fluoride trihydrate
Purity
technical, ≥90% (T)
Packaging
250g
Price
$608
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18164
Product name
Tetra-n-butylammonium fluoride trihydrate
Purity
for synthesis
Packaging
10g
Price
$79.1
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18164
Product name
Tetra-n-butylammonium fluoride trihydrate
Purity
for synthesis
Packaging
50g
Price
$356
Updated
2024/03/01
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Tetrabutylammonium fluoride trihydrate Chemical Properties,Usage,Production

Description

Tetrabutylammonium fluoride trihydrate is a commonly used salt within the realms of organic chemistry and biochemistry. This compound is employed as a potent base, finding extensive use in diverse applications, including organic compound synthesis, buffer preparation, and protein purification. It plays a pivotal role in the synthesis of various organic compounds, such as carboxylic acids, amines, and alcohols. Additionally, this compound facilitates the purification of nucleic acids, including DNA and RNA. Acting as a strong base, tetrabutylammonium fluoride trihydrate possesses the ability to deprotonate a wide range of organic compounds. It is commonly used in applications such as preparation of deprotecting agents, synthesis of lipophilic peprides during DNA transfections, and many more.

Chemical Properties

white crystals or crystalline powder

Uses

Reactant for:
Preparation of deprotecting agents in preparation of cellulose derivatives
Synthesis of lipophilic peptides for DNA transfections in vivo
Dehydrobromination reactions

General Description

Tetrabutylammonium fluoride trihydrate is a mild base used in reactions like aldol-type condensation reactions, Michael-type reactions, ring-opening reactions. Its is also used as a promoter in cross-coupling reactions and cyclization of carbocycles and heterocycles.

Tetrabutylammonium fluoride trihydrate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Tetrabutylammonium fluoride trihydrate manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Tetrabutylammonium fluoride trihydrate 87749-50-6
Price
US $1000.00-800.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-16
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Tetrabutylammonium Fluoride Trihydrate 87749-50-6
Price
US $180.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-28
hebei hongtan Biotechnology Co., Ltd
Product
Tetrabutylammonium fluoride trihydrate 87749-50-6
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-03-22

87749-50-6, Tetrabutylammonium fluoride trihydrateRelated Search:

TETRABUTYL AMMONIUM BROMIDE Tetrabutylammonium bromide Tributyltin chloride Tetrabutylammonium fluoride FLUORIDE STANDARD Ammonium fluoride Tetrabutylammonium hydroxide Tetrabutylammonium tribromide Tetrabutylammonium borohydride Tetrabutylammonium iodide Tetrabutylammonium hexafluorophosphate Tetrabutylammonium tetra (tert butyl alcohol) coordination fluoride Tetrabutylammonium phosphate Tetrabutylphosphonium fluoride Tetrapropylammonium hydroxide Tetrabutyl ammonium chloride Tetrabutylammonium acetate Tetrapropylammonium bromide

  • TETRA-N-BUTYLAMMONIUM FLUORIDE 3 H2O
  • Tetrabutylammonium f
  • Tetrakis(but-1-yl)ammonium fluoride trihydrate 97%
  • TetrabutylaMMoniuM fluoride trihydrate, 99% 10GR
  • TetrabutylaMMoniuM fluoride trihydrate, 99% 50GR
  • 1-Butanaminium, N,N,N-tributyl-, fluoride, trihydrate
  • Tetrabutylammonium fluoride trihydrate 97%
  • Tetrabutylammoniumfluoridetrihydrate97%
  • Tetra(but-1-
  • Tetrakis(but-1-yl)ammonium fluoride trihydrate
  • Tetrabutylammonium fluoride trihydrate,99%
  • Tetrabutylammonium fluoride trihydrateTBAF
  • uoride hydrate
  • TETRA-N-BUTYLAMMONIUM FLUORIDE TRIHYDRAT
  • Tetra(but-1-yl)ammonium fluoride trihydrate 97%
  • TBAF)TetrabutylaMMoniuM fluoride trihy
  • 1-ButanaMiniuM,N,N,N-tributyl-, fluoride, hydrate (1:1:3)
  • Tetrabutylammonium fluoride trihydrate technical, >=90% (T)
  • TetrabutylaMMoniuM fluoride trihydrate >=97.0% (NT)
  • Tetrabutylammonium fluoride trihydrate≥ 99% (Assay)
  • Tetra butyl ammonium fluoride trihydrate Solid
  • TBAF Hydrate
  • Tetra-n-butylammonium fluoride trihydrate for synthesis
  • TBAF 3H2O
  • TBAF TRIHYDRATE
  • TETRABUTYLAMMONIUM FLUORIDE TRIHYDRATE
  • TETRABUTYLAMMONIUM FLUORIDE HYDRATE
  • TETRA-N-BUTYLAMMONIUM FLUORIDE TRIHYDRATE
  • TETRABUTYLAMMONIUMFLUORID-3-HYDRAT
  • etrabutylammonium fluoride trihydrate
  • Tetrabutyl Ammonium Fluoride Trihydrate,98%
  • Tetra-n-butylammonium fluoride 3-hydrate
  • Tetrabutylammonium trihydrate
  • Tetrabutylammonium Fluoride Trihydrate extrapure, 98%
  • N,N,N-Tributyl-1-butanaminium fluoride hydrate (1:1:3)
  • Tetrabutylammonium Fluoride Tetrahydrate (TBAFT)
  • Tetrabutylammonium Fluoride Trihydrate(TBAF.3H20)
  • 87749-50-6
  • C16F1H36N1
  • C16H36FN3H2O
  • C16H36NF3H2O
  • C16H42FNO3
  • CH3CH2CH2CH24NF3H2O
  • CH3CH234NF3H2O
  • Synthetic Reagents
  • Protection and Derivatization
  • Fluoride Sources
  • Deprotection
  • Pyridines ,Heterocyclic Acids
  • Pharmaceutical intermediates
  • bc0001