Methyl 3-amino-4-(methylamino)benzenecarboxylate

Product Name: Methyl 3-amino-4-(methylamino)benzenecarboxylate
CAS No.: 66315-16-0
Chemical Name: Methyl 3-amino-4-(methylamino)benzenecarboxylate
Synonyms: Methyl 3-aMino-4-(MethylaMino)benzoate;3-Amino-4-methylamino-benzoic acid methyl ester;3-Amino-4-(methylamino)benzoesaeure-methylester;Methyl 3-amino-4-(methylamino)benzenecarboxylate;Benzoic acid, 3-amino-4-(methylamino)-, methyl ester
CBNumber: CB72478299
Molecular Formula: C9H12N2O2
Formula Weight: 180.2
MOL File: 66315-16-0.mol

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Methyl 3-amino-4-(methylamino)benzenecarboxylate Property

Melting point:: 103-105°
Boiling point:: 346.5±32.0 °C(Predicted)
Density: 1.208±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 5.40±0.11(Predicted)
Appearance: Gray to dark gray Solid

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Safety

Hazard Codes: Xi
Risk Statements: 43
Safety Statements: 36/37
HazardClass: IRRITANT
HS Code: 2922498590

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M328570
Product name: Methyl3-amino-4-(methylamino)benzoate
Packaging: 1g
Price: $155
Updated: 2021/12/16

AK Scientific

Product number: V7181
Product name: Methyl3-amino-4-(methylamino)benzoate
Packaging: 10g
Price: $488
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0393028
Product name: METHYL-3-AMINO-4-(METHYLAMINO)BENZOATE
Purity: 95.00%
Packaging: 5MG
Price: $502.59
Updated: 2021/12/16

Matrix Scientific

Product number: 048619
Product name: Methyl 3-amino-4-(methylamino)benzenecarboxylate
Purity: >95%
Packaging: 500mg
Price: $55
Updated: 2021/12/16

Matrix Scientific

Product number: 048619
Product name: Methyl 3-amino-4-(methylamino)benzenecarboxylate
Purity: >95%
Packaging: 1g
Price: $84
Updated: 2021/12/16

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Methyl 3-amino-4-(methylamino)benzenecarboxylate Chemical Properties,Usage,Production

Synthesis

36242-50-9

66315-16-0

General procedure for the synthesis of methyl 3-amino-4-(methylamino)benzoate from methyl 4-(methylamino)-3-nitrobenzoate: Methyl 4-(methylamino)-3-nitrobenzoate (540 mg, 2.5 mmol) was dissolved in a solvent mixture of ethyl acetate and methanol (2:1 v/v/v, 20 mL). A 10% palladium-carbon catalyst (5 mol%) was added to the solution under nitrogen protection. The reaction mixture was placed in a hydrogen atmosphere and the reaction was stirred for 4 hours. Upon completion of the reaction, the catalyst was removed by diatomaceous earth filtration. The filtrate was concentrated under reduced pressure to afford the target product methyl 3-amino-4-(methylamino)benzoate. The product was characterized by LC-MS with molecular ion peak [M + 1] = 181.1. yield: 441 mg (100% yield).

References

[1] Patent: EP1502916, 2005, A1. Location in patent: Page 440
[2] Patent: WO2007/69053, 2007, A1. Location in patent: Page/Page column 34
[3] Patent: WO2008/65508, 2008, A1. Location in patent: Page/Page column 32-33; 38-40
[4] Patent: WO2017/147102, 2017, A1. Location in patent: Paragraph 00126-00127
[5] Patent: WO2017/100594, 2017, A1. Location in patent: Paragraph 00132

Methyl 3-amino-4-(methylamino)benzenecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 3-amino-4-(methylamino)benzenecarboxylate Suppliers

China 60 India 1 United States 7 Global 68

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66315-16-0, Methyl 3-amino-4-(methylamino)benzenecarboxylateRelated Search:

Methyl 3-amino-4-(methylamino)benzenecarboxylate

3-Amino-4-(methylamino)benzoesaeure-methylester

3-Amino-4-methylamino-benzoic acid methyl ester

Methyl 3-aMino-4-(MethylaMino)benzoate

Benzoic acid, 3-amino-4-(methylamino)-, methyl ester

66315-16-0