1-Bromo-4-iodonaphthalene
- Product Name
- 1-Bromo-4-iodonaphthalene
- CAS No.
- 63279-58-3
- Chemical Name
- 1-Bromo-4-iodonaphthalene
- Synonyms
- 1,4-BIN;1-Bromo-4-iodophthalene;-BroMo-4-iodonaphthalene;1-Iodo-4-bromonaphthalene;1-Bromo-4-iodonaphthalene;4-bromo-1-iodonaphthalene;1-Bromo-4-iodonaphthaIene;1-Bromo-4-Iodine Naphthalene;Naphthalene, 1-bromo-4-iodo-;1-Bromo-4-iodonaphthalene 98%
- CBNumber
- CB72506879
- Molecular Formula
- C10H6BrI
- Formula Weight
- 332.96
- MOL File
- 63279-58-3.mol
1-Bromo-4-iodonaphthalene Property
- Melting point:
- 88-89℃
- Boiling point:
- 357.3±15.0 °C(Predicted)
- Density
- 2.057
- storage temp.
- 2-8°C(protect from light)
- form
- Solid
- color
- White to Light yellow to Light orange
- Water Solubility
- Slightly soluble in water. (3.6 g/L) (25°C)
- Sensitive
- Light Sensitive
- InChI
- InChI=1S/C10H6BrI/c11-9-5-6-10(12)8-4-2-1-3-7(8)9/h1-6H
- InChIKey
- HQHHKYXPFKHLBF-UHFFFAOYSA-N
- SMILES
- C1(Br)=C2C(C=CC=C2)=C(I)C=C1
Safety
- HS Code
- 2903.99.8001
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B4864
- Product name
- 1-Bromo-4-iodonaphthalene
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $73
- Updated
- 2025/07/31
- Product number
- B4864
- Product name
- 1-Bromo-4-iodonaphthalene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $290
- Updated
- 2025/07/31
- Product number
- B686818
- Product name
- 1-Bromo-4-iodonaphthalene
- Packaging
- 30mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B686818
- Product name
- 1-Bromo-4-iodonaphthalene
- Packaging
- 60mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- B686818
- Product name
- 1-Bromo-4-iodonaphthalene
- Packaging
- 300mg
- Price
- $75
- Updated
- 2021/12/16
1-Bromo-4-iodonaphthalene Chemical Properties,Usage,Production
Uses
It is used as an OLED material.
Synthesis
2298-07-9
63279-58-3
General procedure for the synthesis of 1-bromo-4-iodonaphthalene from 4-bromo-1-naphthylamine: 1-amino-4-bromonaphthalene (60 g, 0.27 mol) was placed in a single-necked flask and the reaction was carried out under argon protection. Acetonitrile (500 ml) was added as a solvent and the reaction mixture was cooled to 0 °C and kept until 1-amino-4-bromonaphthalene was completely dissolved. Subsequently, boron nitrite (42 g, 49 ml, 0.41 mol) and copper bromide (73 g, 0.32 mol) were added sequentially with continuous stirring for 3 h at room temperature. Upon completion of the reaction, the reaction was terminated by slow addition of 1N HCl aqueous solution (600 ml). The resulting solid product was collected by filtration and washed sequentially with distilled water and ether to remove impurities. Finally, the target compound 1-bromo-4-iodonaphthalene (76 g, 85% yield) was purified by column chromatography.
References
[1] Patent: WO2011/105700, 2011, A1. Location in patent: Page/Page column 23
[2] Patent: US2011/152246, 2011, A1. Location in patent: Page/Page column 121-123
[3] Journal of the Chemical Society, 1885, vol. 47, p. 523
[4] Journal of the Chemical Society, 1895, vol. 67, p. 912
[5] Tetrahedron Letters, 2004, vol. 45, # 42, p. 7883 - 7885
1-Bromo-4-iodonaphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-Bromo-4-iodonaphthalene manufacturers
- Product
- 1-Bromo-4-iodonaphthalene 63279-58-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 2000
- Release date
- 2025-04-18
- Product
- 1-Bromo-4-iodonaphthalene 63279-58-3
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-18
- Product
- 1,4-BIN 63279-58-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11