ChemicalBook > CAS DataBase List > Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Reaction- Product Name
- Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
- CAS No.
- 863971-62-4
- Chemical Name
- Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
- Synonyms
- Milstein Catalyst Precursor;[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II);CARBONYLCHLOROHYDRIDO[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride;Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%;Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)
pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) - CBNumber
- CB72526815
- Molecular Formula
- C20H37ClN2OPRu
- Formula Weight
- 489.02
- MOL File
- 863971-62-4.mol
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Property
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- solid
- color
- pale yellow
- Sensitive
- air sensitive
- InChI
- InChI=1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;
- InChIKey
- PZGQZQZSJOXPGP-UHFFFAOYSA-N
- SMILES
- C([Ru+2]12(N(CC3C=CC=C(CP1(C(C)(C)C)C(C)(C)C)N2=3)(CC)CC)([H-])[Cl-])#O
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
H351Suspected of causing cancer
- Precautionary statements
-
P281Use personal protective equipment as required.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 735809
- Product name
- [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
- Packaging
- 100mg
- Price
- $133
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 735809
- Product name
- [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
- Packaging
- 500mg
- Price
- $513
- Updated
- 2022/05/15
Strem Chemicals
- Product number
- 44-0081
- Product name
- Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
- Packaging
- 100mg
- Price
- $105
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0081
- Product name
- Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
- Packaging
- 500mg
- Price
- $417
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0013316
- Product name
- CARBONYLCHLOROHYDRIDO-[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II)
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $503.67
- Updated
- 2021/12/16
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Chemical Properties,Usage,Production
Reaction
- Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
- Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
- Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
- Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.
- Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone
Uses
Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2
General Description
May contain up to 10% acetone and/or THF.
reaction suitability
core: ruthenium
reagent type: catalyst
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Preparation Products And Raw materials
Raw materials
Preparation Products
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