Carbonylbis(triphenylphosphine)rhodium(I) chloride

Product Name: Carbonylbis(triphenylphosphine)rhodium(I) chloride
CAS No.: 13938-94-8
Chemical Name: Carbonylbis(triphenylphosphine)rhodium(I) chloride
Synonyms: Carbonylbis(tripheny;Bis(Triphenylphosphine)rhodium(I) carbon;BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I;Carbonylbis(triphenylphosphine)rhodium(I);Carbonychlorobis(triphenylphosphine)rhodium;carbonylchlorobis(triphenylphosphine)rhodium;Carbonyl diphenyl phosphine rhodium chloride;Carbonylbis(triphenylphosphine)rhodium(I)chlo;Chlorocarbonyl bis(triphenylphosphine) rhodium;Triphenylphosphine carbonyl ruthenium chloride
CBNumber: CB7376852
Molecular Formula: C37H30ClOP2Rh
Formula Weight: 690.94
MOL File: 13938-94-8.mol

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Carbonylbis(triphenylphosphine)rhodium(I) chloride Property

Melting point:: 224-227 °C (dec.)(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in acetone, chloroform, ethanol
form: crystal
color: yellow
BRN: 4618896
Exposure limits: ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference: 13938-94-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,T
Risk Statements: 20/21/22
Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 28439090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 204242
Product name: Bis(triphenylphosphine)rhodium(I) carbonyl chloride
Purity: 99.9%
Packaging: 1g
Price: $336
Updated: 2022/05/15

TCI Chemical

Product number: B1692
Product name: Carbonylbis(triphenylphosphine)rhodium(I) Chloride
Packaging: 1g
Price: $237
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0350
Product name: Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
Packaging: 250mg
Price: $83
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0350
Product name: Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
Packaging: 1g
Price: $246
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0350
Product name: Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
Packaging: 5g
Price: $988
Updated: 2024/03/01

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Carbonylbis(triphenylphosphine)rhodium(I) chloride Chemical Properties,Usage,Production

Chemical Properties

yellow crystals

Uses

Used for cyclometallation.

Application

Used as catalyst for carbonylation，decarbonylation, carbonyl exchange, reduction, hydrometalation, and C-H activation reactions; reagent for alkylation of acid chlorides.

reaction suitability

core: rhodium
reagent type: catalyst

Synthesis

To a solution of RhCl3.3H2O (2 g, 7.6 mmol) in 70 mL of absolute ethanol is slowly added triphenylphosphine (7.2 g, 2.75 mmol) in 300 mL of boiling absolute ethanol. The solution becomes clear within 5 min, at which point sufficient (10-20 mL) 37% formaldehyde solution is added, causing the red solution to become pale yellow. After several minutes, yellow microcrystals precipitate. Upon cooling, the resulting crystals are washed with ethanol and diethyl ether, dried (4.5 g, 85%) and recrystallized from hot toluene.

storage

The complex is air-stable as a crystalline solid and can be stored without special precautions. In solution it readily reacts with oxygen, which therefore must be excluded during preparation and use of this reagent.

Carbonylbis(triphenylphosphine)rhodium(I) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonylbis(triphenylphosphine)rhodium(I) chloride Suppliers

Americas 1 Belgium 2 China 160 Europe 1 France 2 Germany 9 India 5 Japan 4 Switzerland 2 The Netherlands 1 United Kingdom 5 United States 34 Global 226

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Maya High Purity Chemicals

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View Lastest Price from Carbonylbis(triphenylphosphine)rhodium(I) chloride manufacturers

Longyan Tianhua Biological Technology Co., Ltd

Product: Carbonylbis(triphenylphosphine)rhodium(I) chloride 13938-94-8
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-18

Career Henan Chemical Co

Product: Carbonylbis(triphenylphosphine)rhodium(I) chloride 13938-94-8
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: 100kg
Release date: 2018-12-22

13938-94-8, Carbonylbis(triphenylphosphine)rhodium(I) chlorideRelated Search:

Cobalt carbonyl Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Hydridotetrakis(triphenylphosphine)rhodium(I) RUBIDIUM OXIDE Rubidium chloride Rhodium Rhodium(III) Chloride Rhodium carbonyl chloride RUBIDIUM Triphenylphosphine (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Carbonylbis(triphenylphosphine)rhodium(I) chloride

RHODIUM-BIS(TRIPHENYLPHOSPHINE) CARBONYL CHLORIDE

TRANS-BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL CHLORIDE

CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE

CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE

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BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL CHLORIDE

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BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(L) CHLORIDE

Carbonylbis(triphenylphosphine)rhodium(I) chloride~Carbonylchlorobis(triphenylphosphine)rhodium(I)~Chlorocarbonylbis(triphenylphosphine)rhodium(I)

carbonylchlorobis(triphenylphosphine)rhodium

CARBONYLCHLORO-BIS-(TRIPHENYLPHOSPHANO)RHODIUM(I)

Chlorocarbonyl bis(triphenylphosphine) rhodium

Bis(triphenylphosphine) rhodium carbonyl chloride

Chlorocarbonylbis(triphenylphosphine)rhodium(I),99%

Rhodium, carbonylchlorobis(triphenylphosphine)-

CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I ) CHLORIDE, 99.99%

carbonyl bis(triphenylphosphine) rhodium chloride

Carbonylchlorobis(triphenylphosphine)rhodium(I), Rh 14.9% min

trans-Bis(triphenylphosphine)rhodium(I) carbonyl chloride, 98+%

rhodium(I)-bis(triphenylphosphine) carbonyl chloride

Chlorocarbonylbis(triphenylphosphine)rhodium(I), Rhodiumbis(triphenylphosphine) carbonyl chloride

Carbonyl diphenyl phosphine rhodium chloride

Carbonylbis(triphenylphosphine)rhodium(I) chloride,99%

Carconylchlorobis(triphenylphosphine)rhodium(I)

Bis(Triphenylphosphine)rhodium(I) carbon

Bis(triphenylphosphine)rhodium(I) carbonyl chloride ,98%

Chlorocarbonylbis(triphenylphosphine)rhodiuM(I),98%

Bis(triphenylphosphine)carbonylrhodium(I) Chloride Carbonylchlorobis(triphenylphosphine)rhodium(I)

Bis(triphenylphosphine)carbonylrhodiuM chloride

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BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I

Formylbis(triphenylphosphoranyl)-rhodium(IV) chloride

Carbonychlorobis(triphenylphosphine)rhodium

Carbonylbis(triphenylphosphine)rhodium(I) chloride ISO 9001：2015 REACH

Carbonylbis(triphenylphosphine)rhodium(I)chlo

Triphenylphosphine carbonyl ruthenium chloride

Carbonylchlorobis(triphenylphosphane)- rhodium(I)

Carbonylbis(triphenylphosphine)rhodium(I)

13938-94-8

C37H31ClOP2Rh

RhClCOPC6H532

RhClCOPPh32

C6H53P2RhClCO

C37H30ClOP2Rh

2C18H15PCOClRh

Catalysis and Inorganic Chemistry

Metal Complexes

Transition Metal Compounds

Homogeneous Catalysts

Catalysts for Organic Synthesis

Rh (Rhodium) Compounds

Classes of Metal Compounds

metal carbonyl complexes

Rh

chemical reaction,pharm,electronic,materials

Catalysts for Organic Synthesis

Classes of Metal Compounds