ChemicalBook > CAS DataBase List > Carbonylbis(triphenylphosphine)rhodium(I) chloride

Carbonylbis(triphenylphosphine)rhodium(I) chloride

Product Name
Carbonylbis(triphenylphosphine)rhodium(I) chloride
CAS No.
13938-94-8
Chemical Name
Carbonylbis(triphenylphosphine)rhodium(I) chloride
Synonyms
Carbonylbis(tripheny;Bis(Triphenylphosphine)rhodium(I) carbon;BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I;Carbonylbis(triphenylphosphine)rhodium(I);Carbonychlorobis(triphenylphosphine)rhodium;carbonylchlorobis(triphenylphosphine)rhodium;Carbonyl diphenyl phosphine rhodium chloride;Carbonylbis(triphenylphosphine)rhodium(I)chlo;Chlorocarbonyl bis(triphenylphosphine) rhodium;Triphenylphosphine carbonyl ruthenium chloride
CBNumber
CB7376852
Molecular Formula
C37H30ClOP2Rh
Formula Weight
690.94
MOL File
13938-94-8.mol
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Carbonylbis(triphenylphosphine)rhodium(I) chloride Property

Melting point:
224-227 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in acetone, chloroform, ethanol
form 
crystal
color 
yellow
BRN 
4618896
Exposure limits
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference
13938-94-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,T
Risk Statements 
20/21/22
Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
28439090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
204242
Product name
Bis(triphenylphosphine)rhodium(I) carbonyl chloride
Purity
99.9%
Packaging
1g
Price
$336
Updated
2022/05/15
TCI Chemical
Product number
B1692
Product name
Carbonylbis(triphenylphosphine)rhodium(I) Chloride
Packaging
1g
Price
$237
Updated
2025/07/31
Strem Chemicals
Product number
45-0350
Product name
Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
Packaging
250mg
Price
$83
Updated
2024/03/01
Strem Chemicals
Product number
45-0350
Product name
Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
Packaging
1g
Price
$246
Updated
2024/03/01
Strem Chemicals
Product number
45-0350
Product name
Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
Packaging
5g
Price
$988
Updated
2024/03/01
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Carbonylbis(triphenylphosphine)rhodium(I) chloride Chemical Properties,Usage,Production

Chemical Properties

yellow crystals

Uses

Used for cyclometallation.

Application

Used as catalyst for carbonylation，decarbonylation, carbonyl exchange, reduction, hydrometalation, and C-H activation reactions; reagent for alkylation of acid chlorides.

reaction suitability

core: rhodium
reagent type: catalyst

Synthesis

To a solution of RhCl3.3H2O (2 g, 7.6 mmol) in 70 mL of absolute ethanol is slowly added triphenylphosphine (7.2 g, 2.75 mmol) in 300 mL of boiling absolute ethanol. The solution becomes clear within 5 min, at which point sufficient (10-20 mL) 37% formaldehyde solution is added, causing the red solution to become pale yellow. After several minutes, yellow microcrystals precipitate. Upon cooling, the resulting crystals are washed with ethanol and diethyl ether, dried (4.5 g, 85%) and recrystallized from hot toluene.

storage

The complex is air-stable as a crystalline solid and can be stored without special precautions. In solution it readily reacts with oxygen, which therefore must be excluded during preparation and use of this reagent.

Carbonylbis(triphenylphosphine)rhodium(I) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Carbonylbis(triphenylphosphine)rhodium(I) chloride manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Carbonylbis(triphenylphosphine)rhodium(I) chloride 13938-94-8
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-18
Longyan Tianhua Biological Technology Co., Ltd
Product
Carbonylbis(triphenylphosphine)rhodium(I) chloride 13938-94-8
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-18
Career Henan Chemical Co
Product
Carbonylbis(triphenylphosphine)rhodium(I) chloride 13938-94-8
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
100kg
Release date
2018-12-22

13938-94-8, Carbonylbis(triphenylphosphine)rhodium(I) chlorideRelated Search:

Cobalt carbonyl Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Hydridotetrakis(triphenylphosphine)rhodium(I) RUBIDIUM OXIDE Rubidium chloride Rhodium Rhodium(III) Chloride Rhodium carbonyl chloride RUBIDIUM Triphenylphosphine (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Carbonylbis(triphenylphosphine)rhodium(I) chloride

  • RHODIUM-BIS(TRIPHENYLPHOSPHINE) CARBONYL CHLORIDE
  • TRANS-BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL CHLORIDE
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  • CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE
  • CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
  • CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM (I)
  • BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I) CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(L) CHLORIDE
  • Carbonylbis(triphenylphosphine)rhodium(I) chloride~Carbonylchlorobis(triphenylphosphine)rhodium(I)~Chlorocarbonylbis(triphenylphosphine)rhodium(I)
  • carbonylchlorobis(triphenylphosphine)rhodium
  • CARBONYLCHLORO-BIS-(TRIPHENYLPHOSPHANO)RHODIUM(I)
  • Chlorocarbonyl bis(triphenylphosphine) rhodium
  • Bis(triphenylphosphine) rhodium carbonyl chloride
  • Chlorocarbonylbis(triphenylphosphine)rhodium(I),99%
  • Rhodium, carbonylchlorobis(triphenylphosphine)-
  • CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I ) CHLORIDE, 99.99%
  • carbonyl bis(triphenylphosphine) rhodium chloride
  • Carbonylchlorobis(triphenylphosphine)rhodium(I), Rh 14.9% min
  • trans-Bis(triphenylphosphine)rhodium(I) carbonyl chloride, 98+%
  • rhodium(I)-bis(triphenylphosphine) carbonyl chloride
  • Chlorocarbonylbis(triphenylphosphine)rhodium(I), Rhodiumbis(triphenylphosphine) carbonyl chloride
  • Carbonyl diphenyl phosphine rhodium chloride
  • Carbonylbis(triphenylphosphine)rhodium(I) chloride,99%
  • Carconylchlorobis(triphenylphosphine)rhodium(I)
  • Bis(Triphenylphosphine)rhodium(I) carbon
  • Bis(triphenylphosphine)rhodium(I) carbonyl chloride ,98%
  • Chlorocarbonylbis(triphenylphosphine)rhodiuM(I),98%
  • Bis(triphenylphosphine)carbonylrhodium(I) Chloride Carbonylchlorobis(triphenylphosphine)rhodium(I)
  • Bis(triphenylphosphine)carbonylrhodiuM chloride
  • Carbonylbis(tripheny
  • BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I
  • Formylbis(triphenylphosphoranyl)-rhodium(IV) chloride
  • Carbonychlorobis(triphenylphosphine)rhodium
  • Carbonylbis(triphenylphosphine)rhodium(I) chloride ISO 9001：2015 REACH
  • Carbonylbis(triphenylphosphine)rhodium(I)chlo
  • Triphenylphosphine carbonyl ruthenium chloride
  • Carbonylchlorobis(triphenylphosphane)- rhodium(I)
  • Carbonylbis(triphenylphosphine)rhodium(I)
  • 13938-94-8
  • C37H31ClOP2Rh
  • RhClCOPC6H532
  • RhClCOPPh32
  • C6H53P2RhClCO
  • C37H30ClOP2Rh
  • 2C18H15PCOClRh
  • Catalysis and Inorganic Chemistry
  • Metal Complexes
  • Transition Metal Compounds
  • Homogeneous Catalysts
  • Catalysts for Organic Synthesis
  • Rh (Rhodium) Compounds
  • Classes of Metal Compounds
  • metal carbonyl complexes
  • Rh
  • chemical reaction,pharm,electronic,materials
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds