ChemicalBook > CAS DataBase List > Carbonylbis(triphenylphosphine)rhodium(I) chloride
Carbonylbis(triphenylphosphine)rhodium(I) chloride
- Product Name
- Carbonylbis(triphenylphosphine)rhodium(I) chloride
- CAS No.
- 13938-94-8
- Chemical Name
- Carbonylbis(triphenylphosphine)rhodium(I) chloride
- Synonyms
- Carbonylbis(tripheny;Bis(Triphenylphosphine)rhodium(I) carbon;BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I;Carbonylbis(triphenylphosphine)rhodium(I);Carbonychlorobis(triphenylphosphine)rhodium;carbonylchlorobis(triphenylphosphine)rhodium;Carbonyl diphenyl phosphine rhodium chloride;Carbonylbis(triphenylphosphine)rhodium(I)chlo;Chlorocarbonyl bis(triphenylphosphine) rhodium;Triphenylphosphine carbonyl ruthenium chloride
- CBNumber
- CB7376852
- Molecular Formula
- C37H30ClOP2Rh
- Formula Weight
- 690.94
- MOL File
- 13938-94-8.mol
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Carbonylbis(triphenylphosphine)rhodium(I) chloride Property
- Melting point:
- 224-227 °C (dec.)(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in acetone, chloroform, ethanol
- form
- crystal
- color
- yellow
- BRN
- 4618896
- Exposure limits
- ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 - CAS DataBase Reference
- 13938-94-8(CAS DataBase Reference)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 204242
- Product name
- Bis(triphenylphosphine)rhodium(I) carbonyl chloride
- Purity
- 99.9%
- Packaging
- 1g
- Price
- $336
- Updated
- 2022/05/15
TCI Chemical
- Product number
- B1692
- Product name
- Carbonylbis(triphenylphosphine)rhodium(I) Chloride
- Packaging
- 1g
- Price
- $237
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 45-0350
- Product name
- Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
- Packaging
- 250mg
- Price
- $83
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 45-0350
- Product name
- Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
- Packaging
- 1g
- Price
- $246
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 45-0350
- Product name
- Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99%
- Packaging
- 5g
- Price
- $988
- Updated
- 2024/03/01
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Carbonylbis(triphenylphosphine)rhodium(I) chloride Chemical Properties,Usage,Production
Chemical Properties
yellow crystals
Uses
Used for cyclometallation.
Application
Used as catalyst for carbonylation，decarbonylation, carbonyl exchange, reduction, hydrometalation, and C-H activation reactions; reagent for alkylation of acid chlorides.
reaction suitability
core: rhodium
reagent type: catalyst
Synthesis
To a solution of RhCl3.3H2O (2 g, 7.6 mmol) in 70 mL of absolute ethanol is slowly added triphenylphosphine (7.2 g, 2.75 mmol) in 300 mL of boiling absolute ethanol. The solution becomes clear within 5 min, at which point sufficient (10-20 mL) 37% formaldehyde solution is added, causing the red solution to become pale yellow. After several minutes, yellow microcrystals precipitate. Upon cooling, the resulting crystals are washed with ethanol and diethyl ether, dried (4.5 g, 85%) and recrystallized from hot toluene.
storage
The complex is air-stable as a crystalline solid and can be stored without special precautions. In solution it readily reacts with oxygen, which therefore must be excluded during preparation and use of this reagent.
Carbonylbis(triphenylphosphine)rhodium(I) chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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Carbonylbis(triphenylphosphine)rhodium(I) chloride Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
- Tel
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- Fax
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- ffwk-cservice@fujifilm.com
- Country
- Japan
- ProdList
- 6222
- Advantage
- 58
- Tel
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- Fax
- --
- reag-info@gms.kanto.co.jp
- Country
- Japan
- ProdList
- 6756
- Advantage
- 74
- Tel
- --
- Fax
- --
- labchem-tec@wako-chem.co.jp
- Country
- Japan
- ProdList
- 6819
- Advantage
- 80
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View Lastest Price from Carbonylbis(triphenylphosphine)rhodium(I) chloride manufacturers
Longyan Tianhua Biological Technology Co., Ltd
- Product
- Carbonylbis(triphenylphosphine)rhodium(I) chloride 13938-94-8
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-18
Career Henan Chemical Co
- Product
- Carbonylbis(triphenylphosphine)rhodium(I) chloride 13938-94-8
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 95%-99%
- Supply Ability
- 100kg
- Release date
- 2018-12-22
13938-94-8, Carbonylbis(triphenylphosphine)rhodium(I) chlorideRelated Search:
Cobalt carbonyl
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Hydridotetrakis(triphenylphosphine)rhodium(I)
RUBIDIUM OXIDE
Rubidium chloride
Rhodium
Rhodium(III) Chloride
Rhodium carbonyl chloride
RUBIDIUM
Triphenylphosphine
(FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
Carbonylbis(triphenylphosphine)rhodium(I) chloride