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ChemicalBook > CAS DataBase List > Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

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Product Name
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
CAS No.
863971-62-4
Chemical Name
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Synonyms
Milstein Catalyst Precursor;[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II);CARBONYLCHLOROHYDRIDO[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride;Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%;Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
CBNumber
CB72526815
Molecular Formula
C20H37ClN2OPRu
Formula Weight
489.02
MOL File
863971-62-4.mol
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Property

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
color 
pale yellow
Sensitive 
air sensitive
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Safety

Hazard Codes 
Xn
Risk Statements 
19-40
Safety Statements 
36/37
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

H351Suspected of causing cancer

Precautionary statements

P281Use personal protective equipment as required.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
735809
Product name
[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
Packaging
100mg
Price
$133
Updated
2023/06/20
Sigma-Aldrich
Product number
735809
Product name
[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
Packaging
500mg
Price
$513
Updated
2022/05/15
Strem Chemicals
Product number
44-0081
Product name
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Packaging
100mg
Price
$105
Updated
2024/03/01
Strem Chemicals
Product number
44-0081
Product name
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Packaging
500mg
Price
$417
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0013316
Product name
CARBONYLCHLOROHYDRIDO-[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II)
Purity
95.00%
Packaging
5MG
Price
$503.67
Updated
2021/12/16
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Chemical Properties,Usage,Production

Reaction

  1. Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
  2. Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
  3. Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
  4. Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.
  5. Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone

Uses

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

General Description

May contain up to 10% acetone and/or THF.

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Suppliers

Nanchang Zhenshi Biotechnology Co., Ltd
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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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Aikon International Limited
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863971-62-4, Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)Related Search:


  • Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor)
  • [2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II)
  • Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
  • Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)<br />pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
  • Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)
  • [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
  • Milstein Catalyst Precursor
  • Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%
  • CARBONYLCHLOROHYDRIDO[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II)
  • 863971-62-4
  • C20H36ClN2OPRu
  • Ru
  • organometallic complex