Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

Reaction

Product Name: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
CAS No.: 863971-62-4
Chemical Name: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Synonyms: Milstein Catalyst Precursor;[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II);CARBONYLCHLOROHYDRIDO[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II);[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride;Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%;Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor);Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
CBNumber: CB72526815
Molecular Formula: C20H37ClN2OPRu
Formula Weight: 489.02
MOL File: 863971-62-4.mol

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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Property

storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
color: pale yellow
Sensitive: air sensitive

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Safety

Hazard Codes: Xn
Risk Statements: 19-40
Safety Statements: 36/37
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

H351Suspected of causing cancer

Precautionary statements

P281Use personal protective equipment as required.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 735809
Product name: [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
Packaging: 100mg
Price: $133
Updated: 2023/06/20

Sigma-Aldrich

Product number: 735809
Product name: [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
Packaging: 500mg
Price: $513
Updated: 2022/05/15

Strem Chemicals

Product number: 44-0081
Product name: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Packaging: 100mg
Price: $105
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0081
Product name: Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Packaging: 500mg
Price: $417
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: ING0013316
Product name: CARBONYLCHLOROHYDRIDO-[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II)
Purity: 95.00%
Packaging: 5MG
Price: $503.67
Updated: 2021/12/16

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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Chemical Properties,Usage,Production

Reaction

Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.
Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone

Uses

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

General Description

May contain up to 10% acetone and/or THF.

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Suppliers

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863971-62-4, Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)Related Search:

Cobalt carbonyl Carbonylbis(triphenylphosphine)rhodium(I) chloride

Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor)

[2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II)

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)<br />pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride

Milstein Catalyst Precursor

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%

CARBONYLCHLOROHYDRIDO[6-(DI-T-BUTYLPHOSPHINOMETHYL)-2-(N,N-DIETHYLAMINOMETHYL)PYRIDINE]RUTHENIUM(II)

863971-62-4

C20H36ClN2OPRu

Ru

organometallic complex