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4-Butylphenylboronic acid

Product Name
4-Butylphenylboronic acid
CAS No.
145240-28-4
Chemical Name
4-Butylphenylboronic acid
Synonyms
AKOS BRN-0152;CAS:145240-28-4;4-Butylphenylboronic;4-n-butylboronic acid;4-N-Butylphenylboronic;4-Butylphenylboronicaci;4-BUTYLPHENYLBORONIC ACID;4-butylbenzeneboronic acid;4-Bbutylphenylboronic acid;4-N-BUTYLPHENYLBORONIC ACID
CBNumber
CB7256509
Molecular Formula
C10H15BO2
Formula Weight
178.04
MOL File
145240-28-4.mol
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4-Butylphenylboronic acid Property

Melting point:
91-97 °C(lit.)
Boiling point:
313.5±35.0 °C(Predicted)
Density 
1.03±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Soluble in methanol.
form 
powder to crystal
pka
8.78±0.10(Predicted)
color 
White to Orange to Green
BRN 
6920034
CAS DataBase Reference
145240-28-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,F
Risk Statements 
36/37/38-10
Safety Statements 
26-36/37/39-16-7/9-24/25
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
521493
Product name
4-Butylphenylboronic acid
Packaging
1g
Price
$63.77
Updated
2025/07/31
Sigma-Aldrich
Product number
521493
Product name
4-Butylphenylboronic acid
Packaging
5g
Price
$80.5
Updated
2025/07/31
TCI Chemical
Product number
B2589
Product name
4-Butylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$31
Updated
2025/07/31
TCI Chemical
Product number
B2589
Product name
4-Butylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$111
Updated
2025/07/31
TRC
Product number
B809358
Product name
4-N-Butylphenylboronicacid
Packaging
250mg
Price
$55
Updated
2021/12/16
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4-Butylphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Reactant for Suzuki-Miyaura cross-couplings, NHC-Iron-catalyzed aerobic oxidative aromatic esterification of aldehydes, Palladium-catalyzed oxidative Heck-type reactions.

Uses

Intermediates of Liquid Crystals

Uses

suzuki reaction

Synthesis

121-43-7

41492-05-1

145240-28-4

A. Synthesis of 4-n-butylphenylboronic acid To a mixed solution of tetrahydrofuran (32 mL) and ether (96 mL) of 1-bromo-4-n-butylbenzene (6.24 g, 29.3 mmol) was added dropwise n-butyllithium (1.6 M hexane solution, 21.9 mL, 35.1 mmol) at -78 °C. The reaction mixture was stirred at -78 °C for 30 min, and then slowly added dropwise over 20 min to a solution of trimethyl borate (6.1 g, 58.6 mmol) in ether (64 mL) pre-cooled to -78 °C. After the dropwise addition was completed, the reaction mixture was continued to be stirred at -78 °C for 30 minutes, then slowly warmed to room temperature and stirred overnight. After the reaction was completed, 10% aqueous hydrochloric acid solution (150 mL) was added, shaken vigorously for 10 minutes, and left to stratify. The ether layer was separated and the aqueous layer was extracted with ether (100 mL). All organic phases were combined and extracted with 1N sodium hydroxide solution (3 x 100mL). Combine the alkaline aqueous phases, wash once with ether, then acidify to pH 1 with 6N hydrochloric acid and extract with ether (3 x 100mL). All organic phases were combined, washed with water, dried with anhydrous magnesium sulfate, and concentrated under reduced pressure to afford the target product 4-n-butylphenylboronic acid (2.0 g, 38% yield).

References

[1] Patent: US5514696, 1996, A
[2] Advanced Functional Materials, 2017, vol. 27, # 45,

4-Butylphenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Butylphenylboronic acid manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(4-Butylphenyl)boronic acid 145240-28-4
Price
US $2.20-8.80/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2025-06-13
Guangzhou Sunton Biotechnology Co., Ltd.
Product
4-n-Butylbenzeneboronic acid 145240-28-4
Price
US $48.00-40.00/Kg
Min. Order
1KG
Purity
99%
Supply Ability
200tons
Release date
2021-04-18
Shijiazhuang tongyang Import and Export Co., LTD
Product
4-Propylphenylboronic acid 145240-28-4
Price
US $10.00/KG
Min. Order
10g
Purity
99
Supply Ability
50 Ton/Tons per Month
Release date
2021-08-12

145240-28-4, 4-Butylphenylboronic acidRelated Search:


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