ALDICARB-OXIME

Product Name: ALDICARB-OXIME
CAS No.: 1646-75-9
Chemical Name: ALDICARB-OXIME
Synonyms: Temik Oxime;ALDICARB-OXIME;2-methyl-2-(methylthio)-propanal oxime;2-methyl-2-(methylsulfanyl)propanaldoxime;Propanal, 2-methyl-2-(methylthio)-, oxime;Aldicarb-oxime, 10 μg /μL in acetonitrile;2-methyl-2-(methylthio)propionaldehydeoxime;Propionaldehyde, 2-methyl-2-(methylthio)-, oxime.;N-[2-methyl-2-(methylsulfanyl)propylidene]hydro xylamine;TIANFU-CHEM_Propanal,2-methyl-2-(methylthio)-, oxime 1646-75-9
CBNumber: CB7258255
Molecular Formula: C5H11NOS
Formula Weight: 133.21
MOL File: 1646-75-9.mol

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ALDICARB-OXIME Property

Melting point:: 21.1°C
Boiling point:: 210°C
Density: 1.037 (estimate)
refractive index: 1.5216 (estimate)
storage temp.: 0-6°C
form: liquid
EPA Substance Registry System: Aldicarb oxime (1646-75-9)

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Safety

Hazardous Substances Data: 1646-75-9(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: T164670
Product name: TemikOxime
Packaging: 10mg
Price: $780
Updated: 2021/12/16

TRC

Product number: T164670
Product name: TemikOxime
Packaging: 25mg
Price: $1710
Updated: 2021/12/16

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ALDICARB-OXIME Chemical Properties,Usage,Production

Uses

Temik Oxime is an intermediate in the synthesis of Aldicarb-d3 Sulfoxide (A514667), which is a labeled Aldicarb Sulfoxide (A514665). Aldicarb Sulfoxide is an analog of Aldicarb (A514650) detected in agricultural products as pesticide residue.

Definition

ChEBI: The oxime resulting from the formal condensation of 2-methyl-2-(methylsulfanyl)propanal with hydroxylamine. Addition of the oxime group to methyl isocyanate forms the final step in the synthesis of the systemic insecticide aldicarb.

General Description

Clear colorless,viscous liquid with an unpleasant sulfurous or musty odor.

Air & Water Reactions

Sensitive to heat. Water soluble. May decompose with prolonged exposure to moisture.

Reactivity Profile

ALDICARB-OXIME is incompatible with oxidizers, acids and alkalis [(NTP, 1992]. Several explosions or violent decompositions have occurred during distillation of alkoxides, which may be attributable to the formation of peroxides of various types. This is especially the case in the presence of acid, Chem. Eng. News, 1974, 52(35), 3. A nickel catalyzed aldoxime rearrangement to an amide, went out of control after changing the solvent employed, J. Loss Prev., 1993, 6(2), 69.

Fire Hazard

ALDICARB-OXIME is combustible.

ALDICARB-OXIME Preparation Products And Raw materials

Raw materials

Sodium thiomethoxide Vacuum pump 2-chloro-2-methyl propanal oxime dimer Isobutylene Nitrosyl chloride Storage tank Industrial ethanol Hydroxylamine sulfate Isobutyraldehyde

Preparation Products

ALDICARB

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ALDICARB-OXIME Suppliers

China 23 Germany 2 Japan 1 United States 4 Global 30

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1646-75-9, ALDICARB-OXIMERelated Search:

ALDICARB-SULFOXIDE ALDICARB ALDICARB-SULFONE ALDICARB-OXIME BANOL 2-METHYL-2-(PHENYLSULFANYL)PROPANAL O-(4-NITROBENZYL)OXIME 2-[(4-CHLOROPHENYL)SULFANYL]-2-METHYLPROPANAL O-(4-CHLOROBENZYL)OXIME 2-[(4-CHLOROPHENYL)SULFANYL]-2-METHYLPROPANAL O-METHYLOXIME 2-METHYL-2-(PHENYLSULFANYL)PROPANAL O-(4-CHLOROBENZYL)OXIME 2-METHYL-2-[(4-METHYLPHENYL)SULFANYL]PROPANAL O-(4-NITROBENZYL)OXIME 2-METHYL-2-(PHENYLSULFANYL)PROPANAL OXIME 2-METHYL-2-[(4-METHYLPHENYL)SULFANYL]PROPANAL O-METHYLOXIME 4-METHYL-2-(METHYLIMINO)-1,3-DITHIOLANE-4-CARBALDEHYDE OXIME 2-[(4-CHLOROPHENYL)SULFANYL]-2-METHYLPROPANAL O-(4-NITROBENZYL)OXIME 2-(DIMETHYLAMINO)-4-METHYL-1,3-DITHIOLANE-4-CARBALDEHYDEOXIME 2-[(4-CHLOROPHENYL)SULFANYL]-2-METHYLPROPANAL OXIME SPECS AG-664/25003364 2-METHYL-2-[(4-METHYLPHENYL)SULFANYL]PROPANAL OXIME

2-methyl-2-(methylthio)propionaldehydeoxime

ALDICARB-OXIME

Aldicarb-oxime, 10 μg /μL in acetonitrile

Propanal, 2-methyl-2-(methylthio)-, oxime

Propionaldehyde, 2-methyl-2-(methylthio)-, oxime.

2-methyl-2-(methylthio)-propanal oxime

2-methyl-2-(methylsulfanyl)propanaldoxime

N-[2-methyl-2-(methylsulfanyl)propylidene]hydro xylamine

Temik Oxime

TIANFU-CHEM_Propanal,2-methyl-2-(methylthio)-, oxime 1646-75-9

1646-75-9