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ALDICARB-OXIME

Product Name
ALDICARB-OXIME
CAS No.
1646-75-9
Chemical Name
ALDICARB-OXIME
Synonyms
Temik Oxime;ALDICARB-OXIME;2-methyl-2-(methylthio)-propanal oxime;2-methyl-2-(methylsulfanyl)propanaldoxime;Propanal, 2-methyl-2-(methylthio)-, oxime;Aldicarb-oxime, 10 μg /μL in acetonitrile;2-methyl-2-(methylthio)propionaldehydeoxime;Propionaldehyde, 2-methyl-2-(methylthio)-, oxime.;N-[2-methyl-2-(methylsulfanyl)propylidene]hydro xylamine;TIANFU-CHEM_Propanal,2-methyl-2-(methylthio)-, oxime 1646-75-9
CBNumber
CB7258255
Molecular Formula
C5H11NOS
Formula Weight
133.21
MOL File
1646-75-9.mol
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ALDICARB-OXIME Property

Melting point:
21.1°C
Boiling point:
210°C
Density 
1.037 (estimate)
refractive index 
1.5216 (estimate)
storage temp. 
0-6°C
form 
liquid
EPA Substance Registry System
Aldicarb oxime (1646-75-9)
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Safety

Hazardous Substances Data
1646-75-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
T164670
Product name
TemikOxime
Packaging
10mg
Price
$780
Updated
2021/12/16
TRC
Product number
T164670
Product name
TemikOxime
Packaging
25mg
Price
$1710
Updated
2021/12/16
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ALDICARB-OXIME Chemical Properties,Usage,Production

Uses

Temik Oxime is an intermediate in the synthesis of Aldicarb-d3 Sulfoxide (A514667), which is a labeled Aldicarb Sulfoxide (A514665). Aldicarb Sulfoxide is an analog of Aldicarb (A514650) detected in agricultural products as pesticide residue.

Definition

ChEBI: The oxime resulting from the formal condensation of 2-methyl-2-(methylsulfanyl)propanal with hydroxylamine. Addition of the oxime group to methyl isocyanate forms the final step in the synthesis of the systemic insecticide aldicarb.

General Description

Clear colorless,viscous liquid with an unpleasant sulfurous or musty odor.

Air & Water Reactions

Sensitive to heat. Water soluble. May decompose with prolonged exposure to moisture.

Reactivity Profile

ALDICARB-OXIME is incompatible with oxidizers, acids and alkalis [(NTP, 1992]. Several explosions or violent decompositions have occurred during distillation of alkoxides, which may be attributable to the formation of peroxides of various types. This is especially the case in the presence of acid, Chem. Eng. News, 1974, 52(35), 3. A nickel catalyzed aldoxime rearrangement to an amide, went out of control after changing the solvent employed, J. Loss Prev., 1993, 6(2), 69.

Fire Hazard

ALDICARB-OXIME is combustible.

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