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ALLYLIDENE DIACETATE

Product Name
ALLYLIDENE DIACETATE
CAS No.
869-29-4
Chemical Name
ALLYLIDENE DIACETATE
Synonyms
SD-345;shell345;diacetoxy;Shell 345;shellsd345;Shell SD 345;SD 345 (Ester);Diacetoxypropene;allylideneacetate;crolein diacetate
CBNumber
CB7260131
Molecular Formula
C7H10O4
Formula Weight
158.15
MOL File
869-29-4.mol
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ALLYLIDENE DIACETATE Property

Melting point:
-37.6°C
Boiling point:
180°C (estimate)
Density 
1.0760
refractive index 
1.4193 (estimate)
CAS DataBase Reference
869-29-4(CAS DataBase Reference)
EPA Substance Registry System
2-Propene-1,1-diol diacetate (869-29-4)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
RIDADR 
2810
HazardClass 
6.1(a)
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H300Fatal if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P311Call a POISON CENTER or doctor/physician.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
A544513
Product name
AllylideneDiacetate
Packaging
2.5g
Price
$330
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0005591
Product name
1,1-DIACETOXY-2-PROPENE
Purity
95.00%
Packaging
100G
Price
$3396.65
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0005591
Product name
1,1-DIACETOXY-2-PROPENE
Purity
95.00%
Packaging
250G
Price
$6422.58
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0005591
Product name
1,1-DIACETOXY-2-PROPENE
Purity
95.00%
Packaging
500G
Price
$8154.27
Updated
2021/12/16
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ALLYLIDENE DIACETATE Chemical Properties,Usage,Production

Uses

Allylidene Diacetate is a fungicide useful for the control of pea root rot and effective against Phytophthora palmivora. It may also be useful in the formation of vitamin C conjugate of acrolein.

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 1765, 1983 DOI: 10.1021/jo00158a036

Purification Methods

Check the NMR spectrum. If it is not satisfactory, then add Ac2O and a drop of conc H2SO4 and heat at 50o for 10minutes. Then add anhydrous NaOAc (ca 3g/ 100g of liquid) and fractionate. Note that it forms an azeotrope with H2O, so do not add H2O at any time. It is a highly flammable and TOXIC liquid; keep away from the skin. [Smith et al. J Am Chem Soc 73 5282 1951, Beilstein 2 H 154, 2 I 72, 2 III 356, 2 IV 291.]

ALLYLIDENE DIACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ALLYLIDENE DIACETATE Suppliers

Monomer Polymer & Dajac Labs
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info@monomerpolymer.com
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United States
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Aagile Labs Division of Tyger Scientific
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tygersci@yahoo.com
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ChemService Inc.
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3B Scientific Corporation
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HONEST JOY HOLDINGS LIMITED
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City Chemicals Corporation
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Monomer-Polymer & Dajac Laboratories, Inc.
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monomerpolymer@comcast.net
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United States
ProdList
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Eastern Chemical Corp.
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Davos Chemical Corporation
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Pfaltz & Bauer, Inc.
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ASDI Incorporated
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869-29-4, ALLYLIDENE DIACETATERelated Search:


  • ALLYLIDENE DIACETATE
  • ACROLEIN DIACETATE
  • 1,1-DIACETOXY-2-PROPENE
  • 2-PROPENYLIDENE DIACETATE
  • 2-PROPENE-1,1-DIOL DIACETATE
  • 3,3-DIACETOXY-1-PROPENE
  • ,3-Diacetoxy-1-propene
  • 1-(Acetyloxy)-2-propenyl acetate
  • 1,1-Diacetoxypropene-2
  • 2-Propenal, monohydrate, diacetate
  • 2-Propentyl diacetate
  • 3,3-Diacetoxypropene
  • Acrolein diacetyl acetal
  • Acrolein hydrate diacetate
  • Acrolein, monohydrate, diacetate
  • Allylidene acetate
  • allylideneacetate
  • cetic acid 1-acetoxy-allyl ester
  • crolein diacetate
  • diacetoxy
  • Diacetoxypropene
  • SD 345 (Ester)
  • SD-345
  • Shell 345
  • Shell SD 345
  • shell345
  • shellsd345
  • 1-acetyloxyprop-2-enyl acetate
  • 1-acetyloxyprop-2-enyl ethanoate
  • acetic acid 1-acetoxyallyl ester
  • 2-Propene-1,1-diol,1,1-diacetate
  • 869-29-4
  • monomer