ChemicalBook > CAS DataBase List > 4-Boc-2-(broMoMethyl)Morpholine

4-Boc-2-(broMoMethyl)Morpholine

Product Name
4-Boc-2-(broMoMethyl)Morpholine
CAS No.
765914-78-1
Chemical Name
4-Boc-2-(broMoMethyl)Morpholine
Synonyms
4-Boc-broMoMethylMorpholine;4-Boc-2-(broMoMethyl)Morpholine;n-boc-(2)-(broMoMethyl)Morpholine;tert-butyl 2-(broMoMethyl)Morpholine-4-carboxylate;2-Bromomethylmorpholine-4-carboxylic acid tert-butyl ester;4-Morpholinecarboxylic acid, 2-(bromomethyl)-, 1,1-dimethylethyl ester
CBNumber
CB72651737
Molecular Formula
C10H18BrNO3
Formula Weight
280.16
MOL File
765914-78-1.mol
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4-Boc-2-(broMoMethyl)Morpholine Property

Boiling point:
328.8±32.0 °C(Predicted)
Density 
1.334±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
-2.34±0.40(Predicted)
Appearance
White to yellow Solid
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Activate Scientific
Product number
AS3686
Product name
N-Boc-(2)-(Bromomethyl)morpholine
Purity
95+%
Packaging
250mg
Price
$308
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0365482
Product name
4-BOC-2-(BROMOMETHYL)MORPHOLINE
Purity
95.00%
Packaging
5MG
Price
$503.42
Updated
2021/12/16
Activate Scientific
Product number
AS3686
Product name
N-Boc-(2)-(Bromomethyl)morpholine
Purity
95+%
Packaging
1g
Price
$620
Updated
2021/12/16
Matrix Scientific
Product number
093665
Product name
4-Boc-2-(bromomethyl)morpholine
Purity
95+%
Packaging
250mg
Price
$756
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-9-5R
Product name
4-Boc-2-(bromomethyl)morpholine
Packaging
1g
Price
$1440
Updated
2021/12/16
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4-Boc-2-(broMoMethyl)Morpholine Chemical Properties,Usage,Production

Synthesis

135065-69-9

765914-78-1

To a solution of tert-butyl 2-(hydroxymethyl)morpholine-4-carboxylate (0.67 g, 3.1 mmol) in dichloromethane (35 mL) was added carbon tetrabromide (CBr4, 2.06 g, 6.17 mmol) at -20 °C, followed by the slow dropwise addition of a solution of triphenylphosphine (PPh3, 1.70 g, 6.48 mmol) in dichloromethane (25 mL). The reaction mixture was maintained at -15 °C for 18 h, and subsequently brought to room temperature with continued stirring for 1.5 h. The reaction was carried out under reduced pressure. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure and the residue was purified by silica gel column chromatography (eluent: ethyl acetate/hexane) to afford the target product tert-butyl 2-(bromomethyl)morpholine-4-carboxylate 0.55 g in 63% yield, which was used directly in the subsequent reaction.

References

[1] Patent: WO2007/58850, 2007, A2. Location in patent: Page/Page column 44

4-Boc-2-(broMoMethyl)Morpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Boc-2-(broMoMethyl)Morpholine Suppliers

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765914-78-1, 4-Boc-2-(broMoMethyl)MorpholineRelated Search:

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  • 765914-78-1