ChemicalBook > CAS DataBase List > Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate

Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate

Product Name
Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate
CAS No.
118159-48-1
Chemical Name
Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate
Synonyms
SY801;CS-1347;Bicyclol;Bicyclol, SY 801;Bicyclol USP/EP/BP;Bifendate Impurity 17;Bicyclol, 10 mM in DMSO;Bifendate Impurity 6 (Bicyclol);Bicyclol,SY 801,SY-801,Inhibitor,Hepatitis B virus,Autophagy,inhibit,HBV;Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate
CBNumber
CB72693359
Molecular Formula
C19H18O9
Formula Weight
390.34
MOL File
118159-48-1.mol
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Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate Property

Boiling point:
608.1±55.0 °C(Predicted)
Density 
1.410±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,2-8°C
solubility 
DMSO: >10mg/mL
pka
13.85±0.10(Predicted)
form 
powder
color 
white to off-white
InChI
InChI=1S/C19H18O9/c1-22-11-4-9(6-20)13(17-15(11)25-7-27-17)14-10(19(21)24-3)5-12(23-2)16-18(14)28-8-26-16/h4-5,20H,6-8H2,1-3H3
InChIKey
KXMTXZACPVCDMH-UHFFFAOYSA-N
SMILES
O1C2=C(OC)C=C(C(OC)=O)C(C3=C4C(=C(OC)C=C3CO)OCO4)=C2OC1
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Safety

Hazard Codes 
N
Risk Statements 
50/53
Safety Statements 
60-61
RIDADR 
UN 3077 9 / PGIII
RTECS 
DT4312000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Cayman Chemical
Product number
21551
Product name
Bicyclol
Purity
≥98%
Packaging
1mg
Price
$37
Updated
2024/03/01
Cayman Chemical
Product number
21551
Product name
Bicyclol
Purity
≥98%
Packaging
5mg
Price
$81
Updated
2024/03/01
Cayman Chemical
Product number
21551
Product name
Bicyclol
Purity
≥98%
Packaging
10mg
Price
$142
Updated
2024/03/01
TRC
Product number
B382913
Product name
Bicyclol
Packaging
10mg
Price
$100
Updated
2021/12/16
ChemScene
Product number
CS-2968
Product name
Bicyclol
Purity
99.97%
Packaging
5mg
Price
$72
Updated
2021/12/16
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Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate Chemical Properties,Usage,Production

Description

Bicyclol is a hepatoprotective agent. It has antiviral activity against hepatitis B (HBV), reducing viral DNA and the secretion of the HBV antigens HBsAg and HBeAg by 59 and 35%, respectively, in infected 2.2.15 HepG2 cells. In vivo, bicyclol reduces duck HBV (DHBV) DNA in DHBV-infected ducks at doses ≥0.4 g/kg. It also reduces the expression of TNF-α and the accumulation of lymphocytes in the liver in a mouse model of liver injury induced by concanavalin A . Oral administration of bicyclol prior to injection of diethylnitrosamine (DEN) and phenobarbital (PB; Item Nos. 9001494 | 20987) prevents formation of DEN/PB-induced hepatocellular carcinomas. It also reduces liver fibrosis in a rat model of bile duct ligation-induced hepatic fibrosis.

Uses

Bicyclol is a novel hepatoprotectant shown to protect against liver injury by inducing Hsps, including Hsp27 and Hsp 70; Anti-inflammatory activity.

in vivo

Bicyclol (50, 100 and 200 mg/kg; p.o.; single dose) has a dose-dependent protective effect against liver damage induced by different drugs in mice[1]. Bicyclol (50 and 150 mg/kg; p.o.; once a day for 3 days) has a significant protective effect against Acetaminophen (HY-66005) induced mitochondrial damage in mouse hepatocytes[1]. Bicyclol (150 mg/kg; p.o.; once a day for 3 days) inhibits the expression of Fas/FasL mRNA and the release of TNF-α in mouse hepatocytes induced by ConA and plays an anti-apoptotic role in hepatocytes[1]. Bicyclol (300 mg/kg; p.o.; once daily for 3 days) alleviates ConA- and Acetaminophen (HY-66005) induced liver damage in mice, reducing serum transaminases, liver necrosis, mitochondrial cytochrome C and apoptosis-inducing factor (AIF) release, and liver DNA fragmentation[1]. Bicyclol (75 and 150 mg/kg; p.o.; 6 times per week except Sunday for 7 weeks) significantly improves liver damage and fibrosis in rats and mice induces by chronic CCl4 and Dimethylnitosamine hepatotoxicity1]. Bicyclol (25 and 50 mg/kg; p.o.; once every other day for 4 weeks) alleviates hyperlipidemia and liver damage and inhibites inflammatory signaling pathways in HFD-induced NAFLD mice[2]. Bicyclol (200 mg/kg; i.p.; 3 times a day for 2 days) inhibits iron-induced apoptosis in the liver of CCl4-induced ALI mice and exerts a hepatoprotective effect[5].

Animal Model:CCl4, D-Galactosamine, Acetaminophen-Induced Liver Injury in Mice [1]
Dosage:50, 100 and 200 mg/kg
Administration:Oral gavage (p.o.) Single dose administration
Result:Reduced the elevated serum ALT and AST levels in a dose-dependent manner, and also ameliorated the liver lesions.
Animal Model:Acetaminophen-Induced Liver Injury in Mice [1]
Dosage:50 and 150 mg/kg
Administration:Oral gavage (p.o.); Once a day for 3 days
Result:Reduced mitochondrial ultrastructural damage, mitochondrial AST release, mitochondrial fluidity and mitochondrial swelling, and mitochondrial cytochrome C release.
Animal Model:ConA and acetaminophen-Induced Liver Injury in Mice [1]
Dosage:300 mg/kg
Administration:Oral gavage (p.o.); Once a day for 3 days
Result:Induced the expression of HSP70/27 mRNA and protein in mouse liver and activated heat shock factor-1 (HSF1) in mouse liver.
Animal Model:HFD-induced liver inflammation in mice[2]
Dosage:25 and 50 mg/kg
Administration:Oral gavage (p.o.); once every other day for the last four weeks of the 16-week HFD induction
Result:Inhibited the expression levels of pro-inflammatory genes IL-6, TNF-α, IL-1β, COX-2, ICAM-1, VCAM-1, and MCP-1.
Animal Model:CCl4-induced ALI mice[6].
Dosage:200 mg/kg
Administration:Intraperitoneal injection (i.p.); 3 times a day for 2 days
Result:Inhibited iron accumulation, excessive production of reactive oxygen species, enhanced lipid peroxidation, altered mitochondrial morphology, and decreased GPx4 and xCT protein levels in mouse liver.

References

[1] LIU G T. Bicyclol: a novel drug for treating chronic viral hepatitis B and C.[J]. Medicinal Chemistry, 2009, 5 1: 29-43. DOI: 10.2174/157340609787049316
[2] MIN LI  Geng T L. Inhibition of Fas/FasL mRNA expression and TNF-alpha release in concanavalin A-induced liver injury in mice by bicyclol.[J]. World Journal of Gastroenterology, 2004, 10 12: 1775-1779. DOI: 10.3748/wjg.v10.i12.1775
[3] HUA SUN. A novel antihepatitis drug, bicyclol, prevents liver carcinogenesis in diethylnitrosamine-initiated and phenobarbital-promoted mice tumor model.[J]. Journal of Biomedicine and Biotechnology, 2012: 584728. DOI: 10.1155/2012/584728
[4] YONG-ZHAN ZHEN. Protective effect of bicyclol against bile duct ligation-induced hepatic fibrosis in rats.[J]. World Journal of Gastroenterology, 2015, 21 23: 7155-7164. DOI: 10.3748/wjg.v21.i23.7155

Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate Suppliers

Allikang Pharmaceutical Co., LTD
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0573-87390950 13806705416
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China
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BOC Sciences
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United States
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021-58170097
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Haoyuan Chemexpress Co., Ltd.
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021-58950125
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(86) 21-58955996
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MedChemexpress LLC
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021-58955995
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609-228-5909
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sales@medchemexpress.cn
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United States
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Nanjing Sunlida Biological Technology Co., Ltd.
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Bide Pharmatech Ltd.
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View Lastest Price from Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate 118159-48-1
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-13
Career Henan Chemical Co
Product
Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate 118159-48-1
Price
US $0.01/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
1kg; 100kg; 500kg
Release date
2019-12-24

118159-48-1, Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylateRelated Search:


  • Methyl 5'-(hydroxymethyl)-7,7'-dimethoxy-[4,4'-bibenzo[d][1,3]dioxole]-5-carboxylate
  • Bicyclol
  • 4, 4′-dimethoxy-2, 3, 2′, 3′-bis(methylenedioxy)-6-hydroxymethyl-6′-methoxy-carbonyl biphenyl
  • Bicyclol, SY 801
  • CS-1347
  • methyl 4-[5-(hydroxymethyl)-7-methoxy-1,3-benzodioxol-4-yl]-7-methoxy-1,3-benzodioxole-5-carboxylate
  • SY801
  • [4,4'-Bi-1,3-benzodioxole]-5-carboxylic acid, 5'-(hydroxymethyl)-7,7'-dimethoxy-, methyl ester
  • Bicyclol USP/EP/BP
  • Bicyclol,SY 801,SY-801,Inhibitor,Hepatitis B virus,Autophagy,inhibit,HBV
  • Bifendate Impurity 17
  • Bifendate Impurity 6 (Bicyclol)
  • Bicyclol, 10 mM in DMSO
  • 118159-48-1
  • C19H18O9