ChemicalBook > CAS DataBase List > 1,3-CYCLOHEXADIENE

1,3-CYCLOHEXADIENE

Product Name
1,3-CYCLOHEXADIENE
CAS No.
592-57-4
Chemical Name
1,3-CYCLOHEXADIENE
Synonyms
Cyclohexadiene;Cyclohexa-1,3-diene;DIHYDROBENZENE;1,3-CYCLOHEXADIENE, STAB.;SKL284;1,3-CycL;1,3-cyclohexdiene;l，3-Cyclohexadiene;1,2-DIHYDROBENZENE;1,3-CYCLOHEXADIENE
CBNumber
CB7277188
Molecular Formula
C6H8
Formula Weight
80.13
MOL File
592-57-4.mol
More
Less

1,3-CYCLOHEXADIENE Property

Melting point:
-98 °C
Boiling point:
80 °C (lit.)
Density 
0.841 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.474(lit.)
Flash point:
−2 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear colorless to light yellow
Water Solubility 
Slightly miscible with methanol. Immiscible with water.
BRN 
506024
Dielectric constant
2.6600000000000001
Stability:
Light Sensitive
LogP
2.470
CAS DataBase Reference
592-57-4(CAS DataBase Reference)
EPA Substance Registry System
1,3-Cyclohexadiene (592-57-4)
More
Less

Safety

Hazard Codes 
F
Risk Statements 
11-10-37
Safety Statements 
9-16-29-33
RIDADR 
UN 3295 3/PG 2
WGK Germany 
3
RTECS 
GU4702350
F 
9
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29021990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C100005
Product name
1,3-Cyclohexadiene
Purity
contains 0.05% BHT as inhibitor, 97%
Packaging
5ml
Price
$73.2
Updated
2024/03/01
Sigma-Aldrich
Product number
C100005
Product name
1,3-Cyclohexadiene
Purity
contains 0.05% BHT as inhibitor, 97%
Packaging
25ml
Price
$284
Updated
2024/03/01
Alfa Aesar
Product number
A19394
Product name
1,3-Cyclohexadiene, 96%, stab. with 0.1% BHT
Packaging
5g
Price
$66.5
Updated
2024/03/01
Alfa Aesar
Product number
A19394
Product name
1,3-Cyclohexadiene, 96%, stab. with 0.1% BHT
Packaging
25g
Price
$281
Updated
2024/03/01
Sigma-Aldrich
Product number
C100005
Product name
1,3-Cyclohexadiene
Purity
contains 0.05% BHT as inhibitor, 97%
Packaging
100ml
Price
$1020
Updated
2024/03/01
More
Less

1,3-CYCLOHEXADIENE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

1,3-Cyclohexadiene can undergo:
C-C coupling with aromatic alcohols via iridium-catalyzed hydrogen auto-transfer and with aldehydes via transfer hydrogenation mediated by isopropanol to form carbonyl addition products.
Living anionic polymerization with n-BuLi/TMEDA system to form polycyclohexadiene.
Platinum-catalyzed silaboration to form (1R,4S)-1-(dimethylphenylsilyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-cyclohexene.
Aerobic palladium-catalyzed 1,4-diacetoxylation in the presence of cobalt tetra(hydroquinone)porphyrin as an electron transfer reagent.

Uses

1,3-Cyclohexadiene is used as a hydrogen donor in transfer hydrogenation. It is used in the conversion to benzene. It is useful in the study of proteomics research.

Uses

1,3-Cyclohexadiene can undergo:

  • C-C coupling with aromatic alcohols via iridium-catalyzed hydrogen auto-transfer and with aldehydes via transfer hydrogenation mediated by isopropanol to form carbonyl addition products.
  • Living anionic polymerization with n-BuLi/TMEDA system to form polycyclohexadiene.
  • Platinum-catalyzed silaboration to form (1R,4S)-1-(dimethylphenylsilyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-cyclohexene.
  • Aerobic palladium-catalyzed 1,4-diacetoxylation in the presence of cobalt tetra(hydroquinone)porphyrin as an electron transfer reagent.

Definition

ChEBI: Cyclohexa-1,3-diene is a cyclohexadiene.

Preparation

1,3-Cyclohexadiene has been prepared by dehydration of cyclohexen-3-ol, by pyrolysis at 540° of the diacetate of cyclohexane-1,2-diol, by dehydrobromination with quinoline of 3-bromocyclohexene, by treating the ethyl ether of cyclohexen-3-ol with potassium bisulfate, by heating cyclohexene oxide with phthalic anhydride, by treating cyclohexane-1,2-diol with concentrated sulfuric acid, by treatment of 1,2-dibromocyclohexane with tributylamine, with sodium hydroxide in ethylene glycol, and with quinoline, and by treatment of 3,6-dibromo-cyclohexene with sodium.

Purification Methods

Distil the diene from NaBH4 or Na under N2 and collect it in a trap cooled in Dry Ice. It is highly flammable. [Marvel & Martell, J Am Chem Soc 81 450 1959, Beilstein 5 IV 382.]

1,3-CYCLOHEXADIENE Preparation Products And Raw materials

Raw materials

Sodium perborate tetrahydrate Hexamethylphosphoramide 1,2-DIBROMOCYCLOHEXANE Cyclohexene Sodium bromide Lithium carbonate Acetic acid Lithium chloride

Preparation Products

More
Less

1,3-CYCLOHEXADIENE Suppliers

Belgium 1 Canada 1 China 86 Czech 1 France 1 Germany 4 India 5 Japan 2 Slovakia 1 South Korea 1 Switzerland 1 United Kingdom 8 United States 22 Global 134
Jinan Kabotang Biological Technology Co.,Ltd.
Tel
0531-61320525 15866703830
Email
495745175@qq.com
Country
China
ProdList
6839
Advantage
58
Tongchuang Pharma(Suzhou). Co., Ltd.
Tel
0512-63263366 18912765016
Fax
0512-6326 3366
Email
tongtf110@sina.com
Country
China
ProdList
1000
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2882
Advantage
65
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12458
Advantage
60
ChengDu TongChuangYuan Pharmaceutical Co.Ltd
Tel
28-83379370 13880556291
Fax
028-87747383
Email
tcy@tcypharm.com
Country
China
ProdList
511
Advantage
57
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Chemsky（shanghai）International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32344
Advantage
50
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12990
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9823
Advantage
79
Nanjing Vital Chemical Co., Ltd.
Tel
Please Send Email 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
4388
Advantage
65
T&W GROUP
Tel
021-61551611 13296011611
Fax
＋86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9900
Advantage
58
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17779
Advantage
75
Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6181
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22519
Advantage
55
Shanghai Raise Chemical Technology Co.,Ltd
Tel
+86-021-50935922
Fax
+86-021-33847795
Country
China
ProdList
7876
Advantage
55
Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.
Tel
+86-28-85122536 85324413
Fax
+86-28-85326443
Email
market@astatech.cn
Country
China
ProdList
8033
Advantage
55
Shanghai BeiZhuo Biotech Co., Ltd.
Tel
021-61119791,13386096464
Fax
021-50190009
Email
bzswkf@foxmail.com
Country
China
ProdList
3924
Advantage
50
Wuxi Zhongkun Biochemical Technology Co., Ltd.
Tel
0510-85629785 18013409632
Fax
051085625359
Email
sales@reading-chemicals.com
Country
China
ProdList
15185
Advantage
58
Shanghai Song Yuan Chemical Technology Co., Ltd.
Tel
010-1234567 18521000990
Fax
86-021-33275113
Email
sonyuanchemical@163.com
Country
China
ProdList
6490
Advantage
50
Chizhou Kailong Import and Export Trade Co., Ltd.
Tel
Fax
-
Email
xg01_gj@163.com
Country
China
ProdList
9503
Advantage
50
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
Advantage
80
Quzhou Rundong Chemical (Technology) Co.
Tel
0570-8789886 18892685668
Fax
0570-8789985
Email
info@rundongchemical.com
Country
China
ProdList
3989
Advantage
60
NovoChemy Ltd.
Tel
86-(0)21-31261262 373522135
Fax
86-(0)21-33250524
Email
sales@novochemy.com
Country
China
ProdList
6508
Advantage
58
Chengdu Research Accelerators Technology Co., Ltd.
Tel
028-64353063
Fax
028-64353063 QQ:784253935
Email
reacchemical@163.com
Country
China
ProdList
5259
Advantage
58
Chengdu RunZeBenTu Chemical Co., Ltd
Tel
028-88469284 18000562381
Email
rzbtsj@163.com
Country
China
ProdList
9958
Advantage
56
BTC Pharmaceutical CO. Ltd
Tel
0513-0513-68015-397-397 15716293042
Fax
0513-68015394
Email
sales14@btcpharm.com
Country
China
ProdList
652
Advantage
55
Nanjing Vital Chemical Co., Ltd.
Tel
025-87193546 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
9030
Advantage
60
Hangzhou Dingyan Chem Co., LTD
Tel
0571-0571-87157530-8001-8006 18049756717
Fax
0571-87156470
Email
sales@dingyanchem.com
Country
China
ProdList
1997
Advantage
58
Henan CoreyChem Co., Ltd
Tel
0371-86658258
Fax
0371-60996044
Email
info@coreychem.com
Country
China
ProdList
10457
Advantage
58
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
3496
Advantage
58
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20810
Advantage
60
ChengDu TongChuangYuan Pharmaceutical Co.Ltd
Tel
028-83379370 13880556291
Fax
028-87747383
Email
tcy@tcypharm.com
Country
China
ProdList
5430
Advantage
58
Shanghai Kangman Biological Technology Co., Ltd.
Tel
18800375331
Fax
021-50908862
Email
kangmansales@163.com
Country
China
ProdList
7580
Advantage
55
Wuhan EEChem Technologies Co., Ltd
Tel
0711-3617768 13308685235
Fax
0711-3616558
Email
lihongcai4360@sina.com
Country
China
ProdList
1363
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
021-021-52271985 17721149837
Fax
+86 (21) 52271987
Email
sales@9dingchem.com
Country
China
ProdList
19806
Advantage
60
Capot Chemical Co.,Ltd.
Tel
571-85586718 +8613336195806
Fax
+86-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
29797
Advantage
60
Aikon International Limited
Tel
025-58859352 18068836627
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
15085
Advantage
58
Shanghai Time Chemicals CO., Ltd.
Tel
021-57951555
Fax
021-57951555
Email
tianshihuagong1111@163.com
Country
CHINA
ProdList
1360
Advantage
58
Alchemist-pharm chemical Technology Co. Ltd.
Tel
0371-67991738 13783628208
Fax
QQ 412703949
Email
carl@alchemist-pharm.com
Country
China
ProdList
1877
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20569
Advantage
58
Qingdao Sanrenxing Chemical Co., Ltd.
Tel
18505321860
Fax
18505321860
Email
qdsrxchem@163.com
Country
China
ProdList
327
Advantage
58
Jinan Carbotang Biotech Co.,Ltd.
Tel
+8615866703830
Email
figo.gao@foxmail.com
Country
China
ProdList
7019
Advantage
58
Henan Alfa Chemical Co., Ltd
Tel
+8618339805032
Email
alfa4@alfachem.cn
Country
China
ProdList
12755
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
0551-65418671
Fax
0551-65418697
Email
sales@tnjchem.com
Country
China
ProdList
34572
Advantage
58
AFINE CHEMICALS LIMITED
Tel
0571-85134551
Fax
008657185134895
Email
info@afinechem.com
Country
CHINA
ProdList
15377
Advantage
58
Shanxi Xuanran Import and Export Trade Co., Ltd.
Tel
+8617735180244
Email
mike_yan@xuanranglobal.com
Country
CHINA
ProdList
4022
Advantage
58
More
Less

View Lastest Price from 1,3-CYCLOHEXADIENE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
1,3-Cyclohexadiene 592-57-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Nanjing jinheyou Trading Co., Ltd.
Product
1,3-CYCLOHEXADIENE 592-57-4
Price
US $0.00/g
Min. Order
1g
Purity
99.5%min
Supply Ability
20kg/week
Release date
2019-10-31
Career Henan Chemical Co
Product
1,3-CYCLOHEXADIENE 592-57-4
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
10kg
Release date
2018-12-18

592-57-4, 1,3-CYCLOHEXADIENERelated Search:

1,3-Cyclopentanedione O-BROMANIL 1,3,5,5-tetramethyl-3-cyclohexadien ALPHA-PHELLANDRENE Ergosterol CYCLOHEXADIENE IRON TRICARBONYL METHYL CYCLOHEXADIENE alpha-Terpinene 1,3-CYCLOHEXADIENE 1,4-Diamino-2,3-dihydroanthraquinone 7-DEHYDROCHOLESTEROL ACETATE CIS-1,2-DIHYDROCATECHOL THEBAINE 3,5-DI-TERT-BUTYL-O-BENZOQUINONE Tetrachloro-o-benzoquinone (-)-P-MENTHA-1,5-DIENE 2,3,4,5,6,6-HEXACHLORO-2,4-CYCLOHEXADIEN-1-ONE CHORISMIC ACID BARIUM SALT

  • 1,3-CYCLOHEXADIENE
  • 1,2-DIHYDROBENZENE
  • l，3-Cyclohexadiene
  • DIHYDROBENZENE
  • 1,3-CycL
  • Cyclohexa-1,3-diene
  • 1,3-Cyclohexadiene (stabilized with BHT)
  • Cyclohexadiene
  • 1,3-CYCLOHEXADIENE, STAB.
  • 1,3-Cyclohexadiene,96%
  • 1,3-Cyclohexadiene, stabilized, 96%
  • 1,3-Cyclohexadiene, 96%, stab.
  • 1,3-Cyclohexadiene, 96%, stabilized
  • 1,3-Cyclohexanediene
  • 1,3-Cyclohexadiene, 96%, stab. with 0.1% BHT
  • 1,3-Cyclohexadiene,99%
  • 1,3-Cyclohexadiene ,97%
  • 1,3-Cyclohexadiene,1,2-Dihydrobenzene
  • 1,3-CYCLOHEXADIENE 97%
  • 1,3-Cyclohexadiene contains 0.05% BHT as inhibitor, 97%
  • 1,3-Cyclohexadiene stab. with 0.1% BHT
  • 1,3-Cyclohexadiene, 96%, stab. with 0.1% BHT clear, colorless liquid
  • 1,3-Cyclohexadiene, stabilized with 0.1% BHT
  • 1,3-cyclohexdiene
  • SKL284
  • 592-57-4
  • 592574
  • Alkenes
  • Building Blocks
  • Organic Building Blocks
  • Cyclic
  • Miscellaneous Reagents
  • Miscellaneous