ETHYL 4-AMINO-3-NITROBENZOATE

Product Name: ETHYL 4-AMINO-3-NITROBENZOATE
CAS No.: 76918-64-4
Chemical Name: ETHYL 4-AMINO-3-NITROBENZOATE
Synonyms: ethyl 3-nitro-4-aminobenzoate;ETHYL 4-AMINO-3-NITROBENZOATE;4-Amino-3-nitrobenzoic acid ethyl ester;Benzoic acid, 4-aMino-3-nitro-, ethyl ester
CBNumber: CB7281912
Molecular Formula: C9H10N2O4
Formula Weight: 210.19
MOL File: 76918-64-4.mol

More

Less

ETHYL 4-AMINO-3-NITROBENZOATE Property

Melting point:: 132 °C(Solv: methanol (67-56-1))
Boiling point:: 398.5±22.0 °C(Predicted)
Density: 1.330±0.06 g/cm3(Predicted)
pka: -2.52±0.10(Predicted)

More

Less

Safety

HS Code: 2922498590

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

TRC

Product number: E899585
Product name: Ethyl4-amino-3-nitrobenzoate
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Usbiological

Product number: 449209
Product name: Ethyl 4-amino-3-nitrobenzoate
Packaging: 100mg
Price: $305
Updated: 2021/12/16

AK Scientific

Product number: X5379
Product name: Ethyl4-Amino-3-nitrobenzoate
Packaging: 25g
Price: $416
Updated: 2021/12/16

Matrix Scientific

Product number: 088302
Product name: Ethyl 4-amino-3-nitrobenzoate
Packaging: 25g
Price: $439
Updated: 2021/12/16

Matrix Scientific

Product number: 088302
Product name: Ethyl 4-amino-3-nitrobenzoate
Packaging: 5g
Price: $148
Updated: 2021/12/16

More

Less

ETHYL 4-AMINO-3-NITROBENZOATE Chemical Properties,Usage,Production

Synthesis

64-17-5

1588-83-6

76918-64-4

Step 1. 4-Amino-3-nitrobenzoic acid (5.0 g, 27.4 mmol) was dissolved in anhydrous ethanol (100 mL) and an ether solution of 2N HCl (30 mL) was slowly added. The reaction mixture was heated to reflux and kept for 16 hours. After completion of the reaction, the solvent was removed by rotary evaporator under reduced pressure. The crude product was dissolved in dichloromethane (100 mL) and washed with 0.5N aqueous NaOH solution (50 mL x 3). The organic phase was dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give ethyl 4-amino-3-nitrobenzoate as a yellow solid (4.6 g, 79% yield). Mass spectrum (ISP): m/e = 211.1 ([M + H]+). The crude product obtained was used directly in the next step of the reaction.

References

[1] Patent: CN105636956, 2016, A. Location in patent: Paragraph 0212; 0213
[2] Patent: US2016/200709, 2016, A1. Location in patent: Paragraph 0186
[3] Patent: US2007/191603, 2007, A1. Location in patent: Page/Page column 27
[4] Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1988, vol. 27, # 1-12, p. 1106 - 1109
[5] Justus Liebigs Annalen der Chemie, 1909, vol. 371, p. 165

ETHYL 4-AMINO-3-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

ETHYL 4-AMINO-3-NITROBENZOATE Suppliers

China 27 France 1 India 5 United Kingdom 4 United States 5 Global 42

Hangzhou Sage Chemical Co., Ltd.

Tel: +86057186818502 13588463833
Fax: Pls mail us for more information!
Email: info@sagechem.com
Country: China
ProdList: 10266
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12346
Advantage: 58

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692;
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

Changzhou Hopschain Chemical Co.,Ltd.

Tel: 0519-85528066 13775048983
Fax: 0519-85528066
Email: sales@hopschem.com
Country: China
ProdList: 31553
Advantage: 55

Shanghai Chaolan Chemical Technology Center

Tel: 021-QQ：65489617 15618227136
Fax: 21-5161 9052
Email: Sales@ATKchemical.com
Country: China
ProdList: 9125
Advantage: 58

Shanghai CR Corporation Limited

Tel: 13062833949; 4006653949 4006653949
Fax: QQ: 2136646215
Email: fred.wen@crcorporation.cn
Country: China
ProdList: 9756
Advantage: 58

Hangzhou Molcore Biopharmatech Co.,Ltd

Tel: 400-711-5280 86-571-81025280
Fax: 86-571-85806285
Email: sales@molcore.com
Country: China
ProdList: 9967
Advantage: 58

Aikon International Limited

Tel: 025-58859352 18068836627
Fax: (5)02557626880
Email: dt3@aikonchem.com
Country: China
ProdList: 15493
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6039 18920764717
Email: sales@heowns.com
Country: China
ProdList: 23771
Advantage: 60

76918-64-4, ETHYL 4-AMINO-3-NITROBENZOATERelated Search:

Ethyl4-methylamino-3-nitrobenzoate ETHYL 4-ACETAMIDO-3-NITROBENZOATE ETHYL 3-NITRO-4-(PIPERIDIN-4-OL-1-YL)BENZOATE ETHYL 3-NITRO-4-(4-METHYLPIPERIDIN-1-YL)BENZOATE ETHYL 4-AMINO-3-NITROBENZOATE Ethyl 4-(4-methylpiperazin-1-yl)-3-nitrobenzoate ETHYL 4-(3-METHYLPIPERAZIN-1-YL)-3-NITROBENZOATE HYDROCHLORIDE ETHYL 3-NITRO-4-(HEXAMETHYLENEIMIN-1-YL)BENZOATE ETHYL 3-NITRO-4-PIPERAZIN-1-YLBENZOATE ETHYL 3-NITRO-4-[4-(2-HYDROXYETHYL)PIPERAZIN-1-YL]BENZOATE 4-ETHYLAMINO-3-NITRO-BENZOIC ACID ETHYL ESTER ETHYL 3-NITRO-4-(PIPERIDIN-4-CARBOXAMID-1-YL)BENZOATE ETHYL 3-NITRO-4-(PROPYLAMINO)BENZOATE RARECHEM AL BI 0479 RARECHEM AL BI 1086 4-IMIDAZOL-1-YL-3-NITRO-BENZOIC ACID ETHYL ESTER RARECHEM AL BI 0459 SPECS AG-690/15429508

4-Amino-3-nitrobenzoic acid ethyl ester

Benzoic acid, 4-aMino-3-nitro-, ethyl ester

ETHYL 4-AMINO-3-NITROBENZOATE

ethyl 3-nitro-4-aminobenzoate

76918-64-4

Aromatic Esters