4-BROMO-3-IODOANISOLE
- Product Name
- 4-BROMO-3-IODOANISOLE
- CAS No.
- 4897-68-1
- Chemical Name
- 4-BROMO-3-IODOANISOLE
- Synonyms
- 4-BROMO-3-IODOANISOLE;4-Bromo-3-iodoanisole95%;4-Bromo-3-iodoanisole 95%;2-Iodo-4-methoxybromobenzene;1-Bromo-2-iodo-4-methoxybenzene;Benzene, 1-bromo-2-iodo-4-methoxy-;1-Bromo-2-iodo-4-methoxybenzene, 4-Bromo-3-iodophenyl methyl ether
- CBNumber
- CB7288128
- Molecular Formula
- C7H6BrIO
- Formula Weight
- 312.93
- MOL File
- 4897-68-1.mol
4-BROMO-3-IODOANISOLE Property
- Melting point:
- 124-126°C
- Boiling point:
- 124-126 °C(Press: 2 Torr)
- Density
- 2.062±0.06 g/cm3(Predicted)
- refractive index
- 1.65
- storage temp.
- 2-8°C(protect from light)
- form
- liquid
- color
- Clear, faint khaki
Safety
- HS Code
- 2909309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- OR40681
- Product name
- 4-Bromo-3-iodoanisole
- Purity
- 95%
- Packaging
- 250mg
- Price
- $27
- Updated
- 2021/12/16
- Product number
- 2607-S-02
- Product name
- 4-Bromo-3-iodoanisole
- Packaging
- 250mg
- Price
- $29
- Updated
- 2021/12/16
- Product number
- OR40681
- Product name
- 4-Bromo-3-iodoanisole
- Purity
- 95%
- Packaging
- 1g
- Price
- $76
- Updated
- 2021/12/16
- Product number
- 6659AB
- Product name
- 1-Bromo-2-iodo-4-methoxybenzene
- Packaging
- 250mg
- Price
- $81
- Updated
- 2021/12/16
- Product number
- 2607-S-02
- Product name
- 4-Bromo-3-iodoanisole
- Packaging
- 1g
- Price
- $84
- Updated
- 2021/12/16
4-BROMO-3-IODOANISOLE Chemical Properties,Usage,Production
Synthesis
766-85-8
4897-68-1
General procedure for the synthesis of 1-bromo-2-iodo-4-methoxybenzene from 3-iodoanisole: 1. dissolve 3-iodoanisole (10.01 g, 42.77 mmol) in glacial acetic acid (65 mL). 2. 1-bromo-2-iodo-4-methoxybenzene bromide (2.8 mL, 54.49 mmol) was added dropwise to the above solution over 5 minutes. 3. The reaction mixture was stirred at room temperature for 24 hours to obtain an orange solution. 4. The reaction mixture was diluted with water and extracted with hexane. 5. The organic phases were combined and washed sequentially with 5% aqueous sodium thiosulfate and brine. 6. 6. The organic phase was dried over magnesium sulfate and concentrated under reduced pressure to give 1-bromo-2-iodo-4-methoxybenzene (13.51 g, quantitative yield). 7. The product was analyzed by 1H NMR. 7. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 7.47 (d, 1H), 7.39 (d, 1H), 6.77 (dd, 1H), 3.77 (s, 3H).
References
[1] Patent: WO2010/132016, 2010, A1. Location in patent: Page/Page column 127-128
[2] Chemistry - A European Journal, 2006, vol. 12, # 28, p. 7398 - 7410
[3] Organic Letters, 2011, vol. 13, # 10, p. 2614 - 2617
[4] Journal of Materials Chemistry C, 2016, vol. 4, # 25, p. 5981 - 5987
[5] Angewandte Chemie - International Edition, 2007, vol. 46, # 25, p. 4744 - 4747
4-BROMO-3-IODOANISOLE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-BROMO-3-IODOANISOLE manufacturers
- Product
- 4-BROMO-3-IODOANISOLE 4897-68-1
- Price
- US $1.00-2.10/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20000KG
- Release date
- 2024-08-08