BROMUCONAZOLE

Product Name: BROMUCONAZOLE
CAS No.: 116255-48-2
Chemical Name: BROMUCONAZOLE
Synonyms: VECTRA;GRANIT;Hsdb 7419;LS 860263;1-((2RS,4RS;2,4-triazole;BROMUCONAZOL;Bromucanozol;BROMUCONAZOLE;BROMOCONAZOLE
CBNumber: CB7299007
Molecular Formula: C13H12BrCl2N3O
Formula Weight: 377.06
MOL File: 116255-48-2.mol

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BROMUCONAZOLE Property

Melting point:: 84℃
Boiling point:: 504.3±60.0 °C(Predicted)
Density: 1.71
vapor pressure: 50 mg 1^-1
refractive index: 1.6110 (estimate)
solubility: Chloroform (Slightly), Methanol (Slightly)
pka: 2.75±0.10(Predicted)
BRN: 8393967
LogP: 3.240
EPA Substance Registry System: Bromuconazole (116255-48-2)

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 36
RIDADR: UN 3077 9 / PGIII
WGK Germany: 3
RTECS: XZ4130000
HazardClass: 6.1
PackingGroup: III
Hazardous Substances Data: 116255-48-2(Hazardous Substances Data)
Toxicity: LD50 orally in rats, mice: 365, 1151 mg/kg; LD50 dermally in rats: >2000 mg/kg; LD50 by inhalation in rabbits: >5 mg/l; LC50(96 hr) in rainbow trout, bluegill sunfish (mg/l): 1.7, 3.1 (Pepin)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 31644
Product name: Bromuconazol
Purity: mixture of diastereomers
Packaging: 100mg
Price: $138
Updated: 2024/03/01

TRC

Product number: B695380
Product name: Bromuconazole
Packaging: 5mg
Price: $50
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AGR0000784
Product name: BROMUCONAZOLE
Purity: 95.00%
Packaging: 5MG
Price: $498.67
Updated: 2021/12/16

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BROMUCONAZOLE Chemical Properties,Usage,Production

Uses

Bromuconazole is used on winter wheat and barley for the control of foliar mildews, rusts and other diseases.

Uses

Agricultural fungicide.

Definition

ChEBI: A member of the class of oxolanes carrying 1,2,4-triazol-ylmethyl and 2,4-dichlorophenyl substituents at position 2 as well as a bromo substituent at position 4. A foliar applied conazole fungicide for a range of crops including cereals, fruit, vegetables and vines.

Metabolic pathway

Bromuconazole is a relatively stable compound which is not readily hydrolysed, is quite persistent in soil and is subject to relatively slow photodegradation. It is metabolised in plants but the parent compound tends to be the major residue. However, bromuconazole is almost completely metabolised in animals and birds (chickens) and its metabolites are rapidly eliminated.
As with many other triazole fungicides, metabolism is very complex. Bromuconazole exists in four forms (two diastereoisomeric pairs). There are numerous sites available for biotransformation (lack of regioselectivity) and there is also a lack of stereoselectivity at most sites. For example, there are also four forms of metabolite 5 (4-hydroxybromuconazole) (two diastereoisomeric pairs as with bromuconazole itself). Oxidation of secondary alcohols to ketones and the thiolation of certain sites further complicate the picture. Thiolation presumably occurs via the involvement of glutathione but mercapturic acid conjugates (N-acetylcysteines) do not appear to have been isolated.
Bromuconazole has been the subject of an evaluation by the Pesticide Safety Directorate of UK MAFF. All of the information presented below is derived from this source (PSD, 1996). All reported radiolabelled studies were conducted using [¹⁴C-phenyl]bromuconazole.

Degradation

Bromuconazole was found to be stable in buffer at pH 5,7 and 9 at 25 °C over 30 days.
Aqueous photolysis using filtered light to simulate mid-summer sun at 50" N conducted at 25 °C and pH 4 caused slow photodegradation. The DT₅₀ of bromuconazole was 18.2 days. Over 28 days a 10% yield of CO₂ was obtained and six or more photoproducts were detected with none accounting for more than 8% of the total. No degradation occurred in dark controls.

BROMUCONAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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BROMUCONAZOLE Suppliers

Canada 1 China 50 Europe 1 France 1 Germany 1 South Korea 1 Switzerland 1 United States 8 Global 64

J & K SCIENTIFIC LTD.

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BOC Sciences

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Raw material medicin reagent co.,Ltd

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Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
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116255-48-2, BROMUCONAZOLERelated Search:

Penconazole 1-[[(2S,3S)-3-(2-Chlorophenyl)-2-(4-fluorophenyl)oxiran-2-yl]methyl]-1,2,4-triazole IMIBENCONAZOLE Cyproconazole Triadimenol SIMECONAZOLE TRITICONAZOLE Tebuconazole Flutriafol Diniconazole Propiconazole Ethychlozate Xiwojunan Benzyl 2-bromoethyl ether 3-BROMOTETRAHYDROFURAN ALPHA-(2,4-DICHLOROPHENYL)-1H-1,2,4-TRIAZOLE-1-ETHANOL BROMUCONAZOLE tetrahydrofurfuryl-2-methylamine

BROMOCONAZOLE

BROMUCONAZOL

BROMUCONAZOLE

GRANIT

VECTRA

1-((2rs,4rs,2rs,4sr)-4-bromo-2-(2,4-dichlorophenyl)tetrahydrofurfuryl)-1h-1,

1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methyl)-1h-1,2,4-tria

1h-1,2,4-triazole,1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methy

2,4-triazole

4-triazole,1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methyl)-1h-2

1-((2RS,4RS

1-((4-bromo-2-(2,4-dichlorophenyl)tetra hydro-2-furanyl)methyl)-1H-1,2,4-triazole

2RS,4RS)-4-bromo-2-(2,4-dichlorophenyl)tetrahydrofurfuryl)-1H-1,2,4-triazole

BROMUCONAZOL MIXTURE OF DIASTEREO-MERS, PESTANAL

Bromucanozol

1-((2Rs,4rs,2rs,4sr)-4-bromo-2-(2,4-dichlorophenyl)tetrahydrofurfuryl)-1H-1,2,4-triazole

1H-1,2,4-Triazole, 1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methyl)-

Bromuconazole [iso]

Chipco(R) bromuconazole

Hsdb 7419

Bromuconazole 100mg [116255-48-2]

2,5-Anhydro-4-bromo-1,3,4-trideoxy-2-C-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)pentitol

LS 860263

Bromuconazole Standard(mixture of isomers)

Bromuconazol @100 μg/mL in AcCN

BromuconazoleSolution(MixtureofIsomers),100mg/L,1ml

Pentitol, 2,5-anhydro-4-bromo-1,3,4-trideoxy-2-C-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)-

Atrazine Impurity 6

116255-48-2

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