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BROMUCONAZOLE

Product Name
BROMUCONAZOLE
CAS No.
116255-48-2
Chemical Name
BROMUCONAZOLE
Synonyms
VECTRA;GRANIT;Hsdb 7419;LS 860263;1-((2RS,4RS;2,4-triazole;BROMUCONAZOL;Bromucanozol;BROMUCONAZOLE;BROMOCONAZOLE
CBNumber
CB7299007
Molecular Formula
C13H12BrCl2N3O
Formula Weight
377.06
MOL File
116255-48-2.mol
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BROMUCONAZOLE Property

Melting point:
84℃
Boiling point:
504.3±60.0 °C(Predicted)
Density 
1.71
vapor pressure 
50 mg 1-1
refractive index 
1.6110 (estimate)
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
2.75±0.10(Predicted)
BRN 
8393967
LogP
3.240
EPA Substance Registry System
Bromuconazole (116255-48-2)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
36
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
RTECS 
XZ4130000
HazardClass 
6.1
PackingGroup 
III
Hazardous Substances Data
116255-48-2(Hazardous Substances Data)
Toxicity
LD50 orally in rats, mice: 365, 1151 mg/kg; LD50 dermally in rats: >2000 mg/kg; LD50 by inhalation in rabbits: >5 mg/l; LC50(96 hr) in rainbow trout, bluegill sunfish (mg/l): 1.7, 3.1 (Pepin)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
31644
Product name
Bromuconazol
Purity
mixture of diastereomers
Packaging
100mg
Price
$138
Updated
2024/03/01
TRC
Product number
B695380
Product name
Bromuconazole
Packaging
5mg
Price
$50
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AGR0000784
Product name
BROMUCONAZOLE
Purity
95.00%
Packaging
5MG
Price
$498.67
Updated
2021/12/16
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BROMUCONAZOLE Chemical Properties,Usage,Production

Uses

Bromuconazole is used on winter wheat and barley for the control of foliar mildews, rusts and other diseases.

Uses

Agricultural fungicide.

Definition

ChEBI: A member of the class of oxolanes carrying 1,2,4-triazol-ylmethyl and 2,4-dichlorophenyl substituents at position 2 as well as a bromo substituent at position 4. A foliar applied conazole fungicide for a range of crops including cereals, fruit, vegetables and vines.

Metabolic pathway

Bromuconazole is a relatively stable compound which is not readily hydrolysed, is quite persistent in soil and is subject to relatively slow photodegradation. It is metabolised in plants but the parent compound tends to be the major residue. However, bromuconazole is almost completely metabolised in animals and birds (chickens) and its metabolites are rapidly eliminated.
As with many other triazole fungicides, metabolism is very complex. Bromuconazole exists in four forms (two diastereoisomeric pairs). There are numerous sites available for biotransformation (lack of regioselectivity) and there is also a lack of stereoselectivity at most sites. For example, there are also four forms of metabolite 5 (4-hydroxybromuconazole) (two diastereoisomeric pairs as with bromuconazole itself). Oxidation of secondary alcohols to ketones and the thiolation of certain sites further complicate the picture. Thiolation presumably occurs via the involvement of glutathione but mercapturic acid conjugates (N-acetylcysteines) do not appear to have been isolated.
Bromuconazole has been the subject of an evaluation by the Pesticide Safety Directorate of UK MAFF. All of the information presented below is derived from this source (PSD, 1996). All reported radiolabelled studies were conducted using [14C-phenyl]bromuconazole.

Degradation

Bromuconazole was found to be stable in buffer at pH 5,7 and 9 at 25 °C over 30 days.
Aqueous photolysis using filtered light to simulate mid-summer sun at 50" N conducted at 25 °C and pH 4 caused slow photodegradation. The DT50 of bromuconazole was 18.2 days. Over 28 days a 10% yield of CO2 was obtained and six or more photoproducts were detected with none accounting for more than 8% of the total. No degradation occurred in dark controls.

BROMUCONAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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116255-48-2, BROMUCONAZOLERelated Search:


  • BROMOCONAZOLE
  • BROMUCONAZOL
  • BROMUCONAZOLE
  • GRANIT
  • VECTRA
  • 1-((2rs,4rs,2rs,4sr)-4-bromo-2-(2,4-dichlorophenyl)tetrahydrofurfuryl)-1h-1,
  • 1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methyl)-1h-1,2,4-tria
  • 1h-1,2,4-triazole,1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methy
  • 2,4-triazole
  • 4-triazole,1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methyl)-1h-2
  • 1-((2RS,4RS
  • 1-((4-bromo-2-(2,4-dichlorophenyl)tetra hydro-2-furanyl)methyl)-1H-1,2,4-triazole
  • 2RS,4RS)-4-bromo-2-(2,4-dichlorophenyl)tetrahydrofurfuryl)-1H-1,2,4-triazole
  • BROMUCONAZOL MIXTURE OF DIASTEREO-MERS, PESTANAL
  • Bromucanozol
  • 1-((2Rs,4rs,2rs,4sr)-4-bromo-2-(2,4-dichlorophenyl)tetrahydrofurfuryl)-1H-1,2,4-triazole
  • 1H-1,2,4-Triazole, 1-((4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl)methyl)-
  • Bromuconazole [iso]
  • Chipco(R) bromuconazole
  • Hsdb 7419
  • Bromuconazole 100mg [116255-48-2]
  • 2,5-Anhydro-4-bromo-1,3,4-trideoxy-2-C-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)pentitol
  • LS 860263
  • Bromuconazole Standard(mixture of isomers)
  • Bromuconazol @100 μg/mL in AcCN
  • BromuconazoleSolution(MixtureofIsomers),100mg/L,1ml
  • Pentitol, 2,5-anhydro-4-bromo-1,3,4-trideoxy-2-C-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)-
  • Atrazine Impurity 6
  • Bromuconazole 10 μg/ml Cyclohexane
  • Bromuconazole 10.0 μg/ml Acetonitrile
  • C10802200 Bromuconazole
  • L10802200ALBromuconazolE10μg/mLin Acetonitr
  • L10802200CY BromuconazolE10μg/mLin Cyclohexa
  • Bromuconazole in Acetonitrile
  • 116255-48-2
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