ChemicalBook > CAS DataBase List > 2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE

2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE

Product Name
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
CAS No.
98015-45-3
Chemical Name
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
Synonyms
BEMP;>=97% (GC);Hexanal ≥imino-2-diethyL;L-Norleucinol ≥DL-Nornicotine ≥2-Pentyne-1-ol ≥amino-1,3-dimethyL;3-Methoxyphenol ≥3-Cyanocoumarin &ge
CBNumber
CB7301715
Molecular Formula
C13H31N4P
Formula Weight
274.39
MOL File
98015-45-3.mol
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2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE Property

Boiling point:
74 °C0.03 mm Hg(lit.)
Density 
0.948 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.477(lit.)
Flash point:
127 °F
storage temp. 
Room Temperature
solubility 
Acetonitrile (Slightly), Water (Slightly)
form 
Liquid
color 
Colorless
BRN 
5534901
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Safety

Hazard Codes 
C,N,F
Risk Statements 
34-67-65-62-51/53-48/20-11
Safety Statements 
26-36/37/39-45-62-61-16
RIDADR 
UN 2920 8/PG 2
WGK Germany 
3
10-34
HazardClass 
3.2
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
20025
Product name
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine
Purity
purum, ≥98.0% (GC)
Packaging
1ml
Price
$138
Updated
2024/03/01
Sigma-Aldrich
Product number
20025
Product name
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine
Purity
purum, ≥98.0% (GC)
Packaging
5ml
Price
$658
Updated
2024/03/01
Sigma-Aldrich
Product number
728411
Product name
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution
Purity
1 M in hexane, ≥97% (GC), 97% (GC)
Packaging
25ml
Price
$285
Updated
2024/03/01
Sigma-Aldrich
Product number
728411
Product name
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution
Purity
1 M in hexane, ≥97% (GC), 97% (GC)
Packaging
100ml
Price
$887
Updated
2024/03/01
Sigma-Aldrich
Product number
20025
Product name
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine
Purity
purum, ≥98.0% (GC)
Packaging
25ml
Price
$804
Updated
2024/03/01
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2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE Chemical Properties,Usage,Production

Uses

Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases

General Description

2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine (BEMP) is a phosphazene base. BEMP participates in the mild base catalyzed nucleophilic ring opening of N-sulfonyl aziridines. BEMP supported on polystyrene (PS-BEMP) has been reported as an efficient catalyst for the ring-opening of epoxides with phenols. BEMP is about 2000 times more basic and also much more sterically hindered than DBU (l,8-diazabicyclo[5.4.0]undecene).

2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE Suppliers

SIGMA-RBI
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Country
Switzerland
ProdList
6896
Advantage
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98015-45-3, 2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINERelated Search:


  • BEMP
  • 1,3-Dimethyl-2-(diethylamino)-2-(tert-butylimino)-1,3-diaza-2-phospha(V)cyclohexane
  • 1,3-Dimethyl-2-(diethylamino)-2-(tert-butylimino)hexahydro-1,3,2-diazaphosphorine
  • 2-(tert-Butylimino)-2-(diethylamino)-1,3-dimethylhexahydro-1,3,2-diazaphosphorine
  • 2,6-Dimethyl-1-(tert-butylimino)-N,N-diethyl-1,1-dihydro-2,6-diazaphosphorinane-1-amine
  • 2-tert-Butylimino-2-diethylamino-1,3-dimethylhexahydro-1,3,2-diazaphosphorine
  • N,N-Diethyl-1,3-dimethyl-2-(tert-butylimino)-1,2,3,4,5,6-hexahydro-2H,2H-1,3,2-diazaphosphorine-2-amine
  • 2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
  • 2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DI- METHYLPERHYDRODIAZAPHOSPHORINE, 98%
  • 2-T-BU-IMINO-2-DIETHAMINO-1,3,DIME-PER-H YDRO-DIAZAPHOSPHOR.
  • 2-tert-Butylimino-2-diethylamino-1,3-diethyl-perhydro-1,3,2-diazaphosphorine
  • 2-(Di-n-propylamino)ethylamine &ge
  • 5-Chloro-2-methoxyacetophenone &ge
  • 2-Amino-4-pyridinecarboxylic acid methyl ester &ge
  • 2-Amino-4,5-diethoxybenzoic acid &ge
  • 3-Bromo-4-nitroaniline &ge
  • Cyclohexanecarboxylic acid &ge
  • 2-Fluoro-5-iodopyridine &ge
  • 3,5-Dibromo-2,4,6-trimethylpyridine &ge
  • 5-Iodo-2-methoxypyridine &ge
  • 1-Bromo-3-hydroxypropane &ge
  • 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution 1 M in hexane, >=97% (GC), 97% (GC)
  • 2-tert-Butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2
  • 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine purum, >=98.0% (GC)
  • >=97% (GC)
  • 2-|tert|-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution
  • 4-Chlorobutyl acetate &ge
  • 3,4-Dihydro-2H-benzo[b]oxepin-5-one &ge
  • Thiazole-5-carbaldehyde &ge
  • 4-Cyanodiphenyl ether &ge
  • 6-Quinolinecarboxylic acid methyl ester &ge
  • DL-Nornicotine &ge
  • 5-Aminomethyl-pyrrolidin-2-one &ge
  • 1,2,3,4,6-Penta-O-acetyl-a-D-galactopyranose &ge
  • n-Octylpentaoxyethylene &ge
  • a-Methyl-(3-benzyloxy)benzyl alcohol &ge
  • 3-Bromo-2,4,6-trimethylpyridine &ge
  • trans-1-(Boc-amino)-4-(2-hydroxyethyl)cyclohexane &ge
  • (S)-2-Formyl-piperidine-1-carboxylic acid tert-butyl ester &ge
  • 3-Bromo-4-hydroxy-5-methoxybenzonitrile &ge
  • 6-Methylchromanone &ge
  • 3-Bromo-4-methoxybenzaldehyde &ge
  • 1-Cyano-2-bromo-5-nitrobenzene &ge
  • 4-Bromo-3-nitrobenzoic acid methyl ester &ge
  • 4-Methyl-2H-1,4-benzoxazin-3(4H)-one &ge
  • Di-tert-Butylmethylsilane &ge
  • 1-Cyano-4-(dimethylamino)benzene &ge
  • 4-Acetylbenzoic acid methyl ester &ge
  • 2-Bromo-3-nitrotoluene &ge
  • 3-Phenyl-cyclohexanone &ge
  • 6-Amino-2,3-dimethylpyridine &ge
  • 2-Bromo-4-methyl-5-nitropyridine &ge
  • 5-Amino-2-methoxy-benzoic acid methyl ester &ge
  • 4-Cyano-3-methylnitrobenzene &ge
  • 6-Bromo-1,4-benzodioxane &ge
  • 2-Bromo-5-chloro-3-methylpyridine &ge
  • 3-Methoxybenzyl cyanide &ge
  • 4-(2-Hydroxyethyl)benzoic acid &ge