4-Methylmorpholine N-oxide
- Product Name
- 4-Methylmorpholine N-oxide
- CAS No.
- 7529-22-8
- Chemical Name
- 4-Methylmorpholine N-oxide
- Synonyms
- NMO;4-METHYLMORPHOLINE 4-OXIDE;N-Methylmorpholine oxide;Morpholine, 4-methyl-, 4-oxide;4-methyl-morpholin4-oxide;MMNO;NSC 73198;NSC 82153;ine N-oxide;nmo solution
- CBNumber
- CB7305470
- Molecular Formula
- C5H11NO2
- Formula Weight
- 117.15
- MOL File
- 7529-22-8.mol
4-Methylmorpholine N-oxide Property
- Melting point:
- 180-184 °C(lit.)
- Boiling point:
- 118-119°C
- Density
- 1,14 g/cm3
- vapor pressure
- 1.41hPa at 20℃
- refractive index
- n20/D 1.43
- Flash point:
- 118-119°C
- storage temp.
- 2-8°C
- solubility
- DMSO (Soluble), Methanol (Slightly)
- form
- Liquid
- pka
- 4.93±0.20(Predicted)
- color
- Clear colorless to yellow
- PH
- 9.00 ( in neat)
- Water Solubility
- Soluble in water, methanol, ethanol, acetone, ethers and dimethylsulfoxide.
- BRN
- 507437
- Stability:
- Hygroscopic
- LogP
- -1.2 at 25℃
- CAS DataBase Reference
- 7529-22-8(CAS DataBase Reference)
- NIST Chemistry Reference
- N-Methylmorpholine-N-oxide(7529-22-8)
- EPA Substance Registry System
- Morpholine, 4-methyl-, 4-oxide (7529-22-8)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H272May intensify fire; oxidizer
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220Keep/Store away from clothing/…/combustible materials.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 8.14779
- Product name
- 4-Methylmorpholine 4-oxide
- Purity
- (50% solution in water) for synthesis
- Packaging
- 250ML
- Price
- $53.7
- Updated
- 2024/03/01
- Product number
- 8.14779
- Product name
- 4-Methylmorpholine 4-oxide
- Purity
- (50% solution in water) for synthesis
- Packaging
- 1L
- Price
- $168
- Updated
- 2024/03/01
- Product number
- 224286
- Product name
- 4-Methylmorpholine N-oxide
- Purity
- 97%
- Packaging
- 5g
- Price
- $55.3
- Updated
- 2024/03/01
- Product number
- 224286
- Product name
- 4-Methylmorpholine N-oxide
- Purity
- 97%
- Packaging
- 25g
- Price
- $149
- Updated
- 2024/03/01
- Product number
- M0981
- Product name
- 4-Methylmorpholine N-Oxide (50% in Water, ca. 4.8mol/L)
- Packaging
- 25mL
- Price
- $18
- Updated
- 2024/03/01
4-Methylmorpholine N-oxide Chemical Properties,Usage,Production
Chemical Properties
Clear colorless to yellow solution
Uses
4-Methylmorpholine N-Oxide is a metabolite of Morpholine (M723725). N-Methylmorpholine N-Oxide is commonly used to dissolve cellulose as well as in the dissolution of of scleroproteins.
Uses
4-Methylmorpholine N-oxide acts as a non-metallic catalyst for the cyanosilylation of ketones. It is also employed as a co-oxidant for Sharpless asymmetric dihydroxylation in ionic liquids. It serves as a solvent in the Lyocell process to produce tencel fiber. Further, it is used in the preparation of aldehydes from primary alcohols in the presence of tetrapropylammonium perruthenate.
Uses
Non-metallic catalyst for the cyanosilylation of ketones. Co-oxidant for Sharpless asymmetric dihydroxylation in ionic liquids.
Definition
ChEBI: N-methylmorpholine N-oxide is a morpholine N-oxide resulting from the oxidation of the amino group of N-methylmorpholine.
General Description
4-Methylmorpholine?N-oxide is an organic compound used as a co-oxidant along with OsO4 and ruthenates in organic synthesis. In recent studies, it has been used as a catalyst in silylcyanation of aldehydes and ketones. Lyocell, a regenerated cellulose fiber, can be prepared using 4-methylmorpholine?N-oxide in an eco-friendly manner.
Flammability and Explosibility
Flammable
Purification Methods
When the oxide is dried for 2-3hours at high vacuum, it dehydrates. Add MeOH to the oxide and distil off the solvent under vacuum until the temperature is ca 95o. Then add Me2CO at reflux and cool to 20o. The crystals are filtered off, washed with Me2CO and dried. The degree of hydration may vary and may be important for the desired reactions. [van Rheenan et al. Tetrahedron Lett 1973 1076, Schneider & Hanze US Pat 2 769 823; see also Sharpless et al. Tetrahedron Lett 2503 1976.]
4-Methylmorpholine N-oxide Preparation Products And Raw materials
Raw materials
Preparation Products
4-Methylmorpholine N-oxide Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23662
- Advantage
- 75
View Lastest Price from 4-Methylmorpholine N-oxide manufacturers
- Product
- 4-Methylmorpholine-N-oxide 7529-22-8
- Price
- US $60.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-05-06
- Product
- 4-Methylmorpholine N-oxide 7529-22-8
- Price
- US $20.00/kg
- Min. Order
- 1kg
- Purity
- 99.9%
- Supply Ability
- 200000kg
- Release date
- 2024-04-26
- Product
- 4-Methylmorpholine N-oxide 7529-22-8
- Price
- US $8.00-0.80/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-09