Uses in Perfume
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Benzyl methacrylate

Uses in Perfume
Product Name
Benzyl methacrylate
CAS No.
2495-37-6
Chemical Name
Benzyl methacrylate
Synonyms
BZMA;Benzylmethacrylat;BENZYL METHACRYLATE;BENZYLMETHACRAYLATE;Benzyl 2-methylacrylate;Methacrylic acid benzyl;Benzyl methacrylate ,98%;benzyl 2-methylprop-2-enoate;METHACRYLIC ACID BENZYL ESTER;Benzyl Methacrylate, stabilized
CBNumber
CB7306028
Molecular Formula
C11H12O2
Formula Weight
176.21
MOL File
2495-37-6.mol
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Benzyl methacrylate Property

Melting point:
<25 °C
Boiling point:
95-98 °C/4 mmHg (lit.)
Density 
1.04 g/mL at 25 °C (lit.)
vapor pressure 
3Pa at 20℃
refractive index 
n20/D 1.512(lit.)
Flash point:
225 °F
storage temp. 
2-8°C(protect from light)
form 
clear liquid
color 
Colorless
Water Solubility 
Insoluble in water.
Sensitive 
Light Sensitive
BRN 
2045924
Stability:
Stable. Flammable. Incompatible with free-radical initiators, oxidizing agents, reducing agents. Avoid heat. Light-sensitive.
LogP
3.1 at 20℃
CAS DataBase Reference
2495-37-6(CAS DataBase Reference)
NIST Chemistry Reference
Benzyl methacrylate(2495-37-6)
EPA Substance Registry System
2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
1
TSCA 
Yes
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
409448
Product name
Benzyl methacrylate
Purity
96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor
Packaging
250ml
Price
$82.3
Updated
2024/03/01
Sigma-Aldrich
Product number
409448
Product name
Benzyl methacrylate
Purity
96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor
Packaging
1l
Price
$264
Updated
2024/03/01
TCI Chemical
Product number
M0279
Product name
Benzyl Methacrylate (stabilized with MEHQ)
Purity
>98.0%(GC)
Packaging
25mL
Price
$20
Updated
2024/03/01
TCI Chemical
Product number
M0279
Product name
Benzyl Methacrylate (stabilized with MEHQ)
Purity
>98.0%(GC)
Packaging
500mL
Price
$76
Updated
2024/03/01
Alfa Aesar
Product number
L10840
Product name
Benzyl methacrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol
Packaging
50g
Price
$23.65
Updated
2024/03/01
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Benzyl methacrylate Chemical Properties,Usage,Production

Uses in Perfume

Benzyl methacrylate has found some use in perfume compositions where it may introduce very desirable notes in Rose and other floral fragrances, in Chypre, Oriental and heavy woody fragrance types, etc. It blends excellently with Oakmoss, Vetiver, Phenylacetaldehyde dimethylacetal, Citrcnel101,as well as with Lavender, Lavandin, Spike Lavender, etc. The ester is also used in soap and detergent perfumes, where its low cost allows for a more liberal application.

Description

The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].

Chemical Properties

Colorless oily liquid. Very slightly soluble in water, soluble in alcohol and oils. Soft, warm, herbaceous-rosy odor of moderate tenacity.

Uses

Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Flammability and Explosibility

Not classified

Advantages

The Tg of the copolymer was elevated, while thermal stability was first increased and then decreased with the introduction of Benzyl methacrylate. Besides, the water resistance of the latex PSA was improved by the presence of BzMA, which was confirmed by water contact angle measurements. Furthermore, as the BzMA content increased, the gel content slightly decreased, while sol molecular weight (Mw, Mn) of the polymer increased. Finally, with respect to the adhesive properties of the PSA, it was observed that loop tack decreased, while shear strength increased with the incorporation of BzMA. 180° peel strength initially increased and then decreased with the addition of Benzyl methacrylate from 0 to 30 wt%, with a maximum value at 5 wt%.

References

[1] Cheng Fang , Xiaolong Zhu, Fuxiang Zhou . “The application research of benzyl methacrylate (BzMA) in acrylate latex pressure sensitive adhesives.” International Journal of Adhesion and Adhesives 107 (2021): Article 102861.

Benzyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl methacrylate Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Fine Corporation
Tel
--
Fax
--
Email
info@fine-c.jp
Country
Japan
ProdList
1427
Advantage
58
Mitsubishi Gas Chemical (MGC)
Tel
--
Fax
--
Country
Japan
ProdList
45
Advantage
58
Kyoeisha Chemical Co., Ltd.
Tel
--
Fax
--
Email
h_sakurai@kyoeisha.co.jp
Country
Japan
ProdList
36
Advantage
58
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
FUJIFILM Wako Pure Chemical Corporation
Tel
--
Fax
--
Email
ffwk-cservice@fujifilm.com
Country
Japan
ProdList
6222
Advantage
58
Hitachi Chemical Co.,Ltd.
Tel
--
Fax
--
Email
kojinjyoho@hitachi-chem.co.jp
Country
Japan
ProdList
21
Advantage
77
Junsei Chemical Co., Ltd.
Tel
--
Fax
--
Email
shiyaku@junsei.co.jp
Country
Japan
ProdList
3096
Advantage
46
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
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View Lastest Price from Benzyl methacrylate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Benzyl methacrylate 2495-37-6
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-08
Qingdao RENAS Polymer Material Co., Ltd.
Product
Benzyl methacrylate 2495-37-6
Price
US $0.00/kg
Min. Order
20kg
Purity
99.5%
Supply Ability
10 toms
Release date
2024-04-26
Hebei Yanxi Chemical Co., Ltd.
Product
Benzyl methacrylate 2495-37-6
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
20tons
Release date
2023-09-14

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