Isobornyl methacrylate

Product Name: Isobornyl methacrylate
CAS No.: 7534-94-3
Chemical Name: Isobornyl methacrylate
Synonyms: IBOMA;IBXMA;Acryester IBX;exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl methacrylate;Photomer 2012;Ageflex IBOMA;Light Ester IB;Isoice methacrylate;Isobornyl Methacrylat;ISOBOMYL METHACRYLATE
CBNumber: CB9196470
Molecular Formula: C14H22O2
Formula Weight: 222.33
MOL File: 7534-94-3.mol

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Isobornyl methacrylate Property

Melting point:: -60 °C
Boiling point:: 127-129 °C15 mm Hg(lit.)
Density: 0.983 g/mL at 25 °C(lit.)
vapor pressure: 7.5Pa at 20℃
refractive index: n20/D 1.477(lit.)
Flash point:: 225 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: Liquid
color: Clear colorless to yellow
Specific Gravity: 0.985
Water Solubility: negligible
InChIKey: HHHKSPVBHWRWNA-QOZQQMKHSA-N
LogP: 5.09
CAS DataBase Reference: 7534-94-3(CAS DataBase Reference)
EPA Substance Registry System: Isobornyl methacrylate (7534-94-3)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 2
HS Code: 29161400
Hazardous Substances Data: 7534-94-3(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H412Harmful to aquatic life with long lasting effects
Precautionary statements: P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 392111
Product name: Isobornyl methacrylate
Purity: technical grade
Packaging: 100ml
Price: $58.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 392111
Product name: Isobornyl methacrylate
Purity: technical grade
Packaging: 1l
Price: $248
Updated: 2024/03/01

TCI Chemical

Product number: I0617
Product name: Isobornyl Methacrylate (stabilized with MEHQ)
Purity: >85.0%(GC)
Packaging: 25g
Price: $31
Updated: 2024/03/01

TCI Chemical

Product number: I0617
Product name: Isobornyl Methacrylate (stabilized with MEHQ)
Purity: >85.0%(GC)
Packaging: 500g
Price: $128
Updated: 2024/03/01

Sigma-Aldrich

Product number: 392111
Product name: Isobornyl methacrylate
Purity: technical grade
Packaging: 500ml
Price: $172
Updated: 2024/03/01

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Isobornyl methacrylate Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLORLESS TO YELLOW LIQUID

Characteristics

Isobornyl methacrylate is a colorless transparent liquid. It is a monomer that unifies hardness and flexibility. Due to its molecular structure, its polymer has excellent high gloss, sharp image, scratch resistance, medium resistance and weather resistance, and Its hygroscopicity is significantly lower than that of MMA (methyl methacrylate). In addition, IBOMA-added acrylic resin has good compatibility with polyester, alkyd and many volatile paint film-forming substances.

Uses

Isobornyl methacrylate is a versatile hydrophobic monomer with a good combination of hardness and flexibility that can improve the chemical and water resistance of polymer systems.

Preparation

Isobornyl methacrylate was synthesized by direct esterification of camphene and methacrylic acid.

General Description

Isobornyl methacrylate is a reactive solvent with low vapor pressure. It facilitates the free radical polymerization by forming a polymer with high glass transition temperature (T_g).

Flammability and Explosibility

Not classified

Synthesis

Isobornyl methacrylate is obtained by reacting (1S,2S,4S)-(+)-isoborneol and 4-methoxyphenol.Dissolve5g (1S,2S,4S)-(+)-isoborneol in 15 mL toluene. Add 4 mg (0.032 mmol) 4-methoxyphenol to the solution. After the addition of 0.4 g (3.24 mmol)4-dimethylamino pyridine, add a solution of 10 g (64.8 mmol) methacrylic anhydride (MAA) in 10 mL toluene dropwise to the mixture. Heat the reaction mixture to 80 °C. Stir the reaction mixture for 16 hours. After cooling down to room temperature, wash the mixture with 50 mL 1M sodium bicarbonate solution four times. Wash the organic phase with 50 mL brine two times. Separate the organic phase. Remove the toluene by rotary evaporation followed by a fractional distillation under reduced pressure.
1H NMR (CDCl3, 300 MHz): δ(ppm) = 6.06 (dq, 1H, 1); 5.51 (dq, 1H, 2); 4.71 (m ,1H, 4); 1.93 (dd, 3H, 3); 1.87-1.5 (m, 5H, 6,7,8); 1.23-1.04 (m, 2H, 5); 1.012 (s, 3H, 9);0.86 (s, 3H, 10); 0.85 (s, 3H, 11). IR (film): ν(cm-1) = 2954 (CH2), 2879 (CH2), 1715 (C=O) 1454 (CH2), 1157 and 1053 (C=O).

Fig The synthetic method of Isobornyl methacrylate

Isobornyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Isobornyl methacrylate Suppliers

Americas 1 Belgium 2 China 282 Europe 2 France 1 Germany 5 India 8 Japan 8 Russia 1 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 2 United Kingdom 3 United States 33 Global 352

Yancheng Green Chemicals Co.,Ltd.

Tel: 25-25-86655873 02586655873
Email: marketing@royal-chem.com
Country: China
ProdList: 75
Advantage: 58

Qingdao RENAS Polymer Material Co.,Ltd.

Tel: 0532-0532-86867058 18562606086
Fax: 0532-86867058
Email: sales@qdrenas.com
Country: China
ProdList: 88
Advantage: 50

Anhui Royal Chemical Co., Ltd.

Tel: 25-86655873 13962173137
Fax: +86-25-52279193
Email: marketing@royal-chem.com
Country: China
ProdList: 476
Advantage: 60

Suzhou Senfeida Chemical Material Co., Ltd.

Tel: 512-83500002 13862111431
Fax: 0512-66387035
Email: sales2@senfeida.com
Country: China
ProdList: 288
Advantage: 58

SUMMIT CHEMICAL

Tel: 020-82567763 13609796592
Email: summitchem@163.com
Country: China
ProdList: 19
Advantage: 58

IGM RESINS

Tel: 021-52080993 13917193189
Fax: 021-5208 0930，010-62620366，020-32008365
Email: selene.wu@igmresins.com
Country: China
ProdList: 89
Advantage: 57

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

MedicalChem(Yancheng)Manuf.Co.,Ltd

Tel: +86-515-84383180
Fax: +86-515-84383182
Email: sales@medicalchem.com
Country: China
ProdList: 80
Advantage: 69

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

future industrial shanghai co., ltd

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: sales@jonln.com
Country: China
ProdList: 1998
Advantage: 65

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View Lastest Price from Isobornyl methacrylate manufacturers

Jinan Finer Chemical Co., Ltd

Product: Isobornyl methacrylate 7534-94-3
Price: US $0.00/Kg/Drum
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000mt
Release date: 2021-12-07

Henan Fengda Chemical Co., Ltd

Product: Isobornyl methacrylate 7534-94-3
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-24

Hebei Yanxi Chemical Co., Ltd.

Product: Isobornyl methacrylate 7534-94-3
Price: US $25.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-21

7534-94-3, Isobornyl methacrylateRelated Search:

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(1,7,7-Trimethyl-6-bicyclo[2.2.1]heptanyl) 2-methylprop-2-enoate

Isobornyl methacrylate, stabilized

Acryester IBX

Ageflex IBOMA

IBXMA

Isoborneol methacrylate

Light Ester IB

Isobornyl methacrylate,85-90%,stabilized

exo-2-Bornyl methacrylate

IsobornylMethacrylate(stabilizedwithMEHQ)&gt

Methacrylate ice tablet ester

Isoice methacrylate

rel-(1R,2R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-yl methacrylate

lsobornyl methacrylate IBOMA

Sinomer? IBOMA / Isobornyl methacrylate

7534-94-3

Esters

Organic Building Blocks

Building Blocks

Carbonyl Compounds

C12 to C63

Bicyclic Monoterpenes

Biochemistry

Terpenes

7534-94-3