Reaction
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Josiphos SL-J009-1 Pd G3

Reaction
Product Name
Josiphos SL-J009-1 Pd G3
CAS No.
1702311-34-9
Chemical Name
Josiphos SL-J009-1 Pd G3
Synonyms
Josiphos Pd G3;JOSIPHOS Palladacycle Gen. 3;BRUNO PALLADACYCLE;Josiphos SL-J009-1 Pd G3;cyclopenta-2,4-dien-1-yl-[(1R)-2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron;Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3;Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3];METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3]
CBNumber
CB73159041
Molecular Formula
C45H66FeNO3P2PdS10*-
Formula Weight
925.287962
MOL File
1702311-34-9.mol
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Josiphos SL-J009-1 Pd G3 Property

Melting point:
180-186 °C
form 
solid
color 
red-orange
InChIKey
VXSQFQJKYCLYAK-DHOIFHORSA-N
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
747130
Product name
Josiphos SL-J009-1 Pd G3
Packaging
100MG
Price
$111
Updated
2023/06/20
Sigma-Aldrich
Product number
747130
Product name
Josiphos SL-J009-1 Pd G3
Packaging
250MG
Price
$272
Updated
2023/06/20
Sigma-Aldrich
Product number
747130
Product name
Josiphos SL-J009-1 Pd G3
Packaging
1G
Price
$944
Updated
2023/06/20
Sigma-Aldrich
Product number
747130
Product name
Josiphos SL-J009-1 Pd G3
Packaging
5G
Price
$4110
Updated
2023/06/20
Strem Chemicals
Product number
46-0353
Product name
Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Josiphos Palladacycle Gen. 3]
Packaging
100mg
Price
$104
Updated
2024/03/01
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Josiphos SL-J009-1 Pd G3 Chemical Properties,Usage,Production

Reaction

Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides.

Uses

Josiphos SL-J009-1 Pd G3 is a good catalyst, widely used in various cross-coupling reactions, including: Buchwald-Hartwig cross-coupling reaction, Hiyama Coupling, Negishi Coupling, Heck Reaction, Sonogashira Coupling and Suzuki-Miyaura Coupling, etc.

General Description

Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Josiphos SL-J009-1 Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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Josiphos SL-J009-1 Pd G3 Suppliers

Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
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9171
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Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
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Strem Chemicals, Inc.
Tel
--
Fax
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Email
info@strem.com
Country
United States
ProdList
4910
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86

1702311-34-9, Josiphos SL-J009-1 Pd G3Related Search:


  • Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • JOSIPHOS Palladacycle Gen. 3
  • Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3]
  • Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3]
  • BRUNO PALLADACYCLE
  • Josiphos Pd G3
  • Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3
  • cyclopenta-2,4-dien-1-yl-[(1R)-2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron
  • (SP-4-3)-[2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][(2R)-1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino-κP]ethyl]-2-(dicyclohexylphosphino)ferrocene](methanesulfonato-κO)palladium (ACI)
  • Josiphos SL-J009-1 Pd G3
  • 1702311-34-9
  • C45H65FeNO3P2PdS