1,1'-Diacetylferrocene

Product Name: 1,1'-Diacetylferrocene
CAS No.: 1273-94-5
Chemical Name: 1,1'-Diacetylferrocene
Synonyms: 1,1'-DiacetyL;Diacetylferrocene;1,1-Diacetylferrocne;1,1'-Diacetylferrocene;1,1'-Diacetylferrocene;Ferrocene, 1,1'-diacetyl-;1,1'-Diacetylferrocene >1,1′-Diacetylferrocene 97%;1,1'-Diacetylferrocene,98%;1,1'-Diacetylferrocene ,97%
CBNumber: CB7326938
Molecular Formula: C14H14FeO210*
Formula Weight: 270.1
MOL File: 1273-94-5.mol

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1,1'-Diacetylferrocene Property

Melting point:: 125-127 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
form: solid
Appearance: Brown to reddish brown Solid
Water Solubility: Insoluble
InChI: InChI=1S/2C7H7O.Fe/c2*1-6(8)7-4-2-3-5-7;/h2*2-5H,1H3;
InChIKey: JNBIZDIDVCJECQ-UHFFFAOYSA-N
SMILES: [C]1([CH][CH][CH][CH]1)C(=O)C.[C]1([CH][CH][CH][CH]1)C(=O)C.[Fe] |^1:0,1,2,3,4,8,9,10,11,12|
CAS DataBase Reference: 1273-94-5(CAS DataBase Reference)
NIST Chemistry Reference: 1,1'-Diacetylferrocene(1273-94-5)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 36
WGK Germany: 3
RTECS: LK0725666
HS Code: 29319090
Toxicity: mammal (species unspecified),LDLo,intratracheal,50mg/kg (50mg/kg),BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLDBEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)KIDNEY, URETER, AND BLADDER: INCONTINENCE,"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 62, 1999.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 106879
Product name: 1,1′-Diacetylferrocene
Purity: 97%
Packaging: 5g
Price: $110
Updated: 2025/07/31

TRC

Product number: D353248
Product name: 1,1-Diacetylferrocene,97%
Packaging: 10g
Price: $330
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD35258
Product name: 1,1'-Diacetylferrocene
Packaging: 5G
Price: $120
Updated: 2021/12/16

AK Scientific

Product number: Z2232
Product name: 1,1'-Diacetylferrocene
Packaging: 25g
Price: $154
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD35258
Product name: 1,1'-Diacetylferrocene
Packaging: 10g
Price: $220
Updated: 2021/12/16

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1,1'-Diacetylferrocene Chemical Properties,Usage,Production

Chemical Properties

dark orange to dark red powder

reaction suitability

core: iron
reagent type: catalyst

Synthesis

102-54-5

75-36-5

1273-94-5

1) In a dry reaction vessel, anhydrous aluminum trichloride (0.1-0.18 moles) and methylene chloride (30-60 ml) were added and stirred until homogeneous. Subsequently, a mixed solution consisting of ferrocene (0.03-0.06 moles), methylene chloride (80-100 ml) and acetyl chloride (0.1-0.16 moles) was added slowly and dropwise. The reaction was first stirred at room temperature for 3-5 hours and then heated to reflux for 3-4 hours. Upon completion of the reaction, 70-100 ml of distilled water was slowly added to hydrolyze the aluminum trichloride, taking care to prevent splashing. After completion of hydrolysis, the reaction mixture was extracted with dichloromethane and the lower organic phase was separated in a separatory funnel. The upper aqueous phase was extracted three times with a small amount of dichloromethane and the organic phases were combined. The organic phase was dried with anhydrous magnesium sulfate, filtered to remove the desiccant and concentrated to give the crude product. The crude product was purified by aqueous recrystallization to give red needle-like crystals of 1,1'-diacetylferrocene in about 80% yield.

References

[1] Journal of the Chemical Society, Perkin Transactions 1, 2000, # 10, p. 1551 - 1557
[2] Patent: CN108530493, 2018, A. Location in patent: Paragraph 0032; 0038; 0044; 0049
[3] Patent: CN107226829, 2017, A. Location in patent: Paragraph 0022; 0026; 0030
[4] Journal of Organic Chemistry, 2015, vol. 80, # 19, p. 9563 - 9569
[5] Patent: CN104292274, 2017, B. Location in patent: Paragraph 0057

1,1'-Diacetylferrocene Preparation Products And Raw materials

Raw materials

Ferrocene Acetyl chloride Aluminum chloride

Preparation Products

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1,1'-Diacetylferrocene Suppliers

Belgium 1 China 113 Europe 2 Germany 4 India 1 Japan 2 Switzerland 1 Ukraine 1 United Kingdom 6 United States 17 Global 148

Sichuan Zhongcheng Pharmaceutical & Chemical Co., Ltd

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View Lastest Price from 1,1'-Diacetylferrocene manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 1,1'-Diacetylferrocene 1273-94-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KG
Release date: 2024-09-04

Shaanxi Dideu Medichem Co. Ltd

Product: Dimethyl 1,1'-ferrocenedicarboxylate 1273-94-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KG
Release date: 2024-09-04

Career Henan Chemical Co

Product: 1,1'-Diacetylferrocene 1273-94-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

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1273-94-5

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