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BIS(CYCLOPENTADIENYL)COBALT

Product Name
BIS(CYCLOPENTADIENYL)COBALT
CAS No.
1277-43-6
Chemical Name
BIS(CYCLOPENTADIENYL)COBALT
Synonyms
tocene;Kobaltocen;COBALTOCENE;Cobaltocene,98%;Ferrocene cobalt;cobaltocene(1277-43-6);Dicyclopentadienylcobalt;BIS(CYCLOPENTADIENYL)COBALT;di-pi-cyclopentadienyl-cobal;Bis (cyclopentadiene) cobalt
CBNumber
CB7358719
Molecular Formula
C10H10Co10*
Formula Weight
189.12
MOL File
1277-43-6.mol
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BIS(CYCLOPENTADIENYL)COBALT Property

Melting point:
176-180 °C (dec.)(lit.)
Boiling point:
173℃ [CRC10]
storage temp. 
2-8°C
form 
crystal
color 
purplish-black
Water Solubility 
Insoluble in water.
Sensitive 
Air & Moisture Sensitive
Stability:
Stable, but very reactive and air and moisture sensitive - store under inert gas. Incompatible with strong oxidizing agents. Highly flammable.
CAS DataBase Reference
1277-43-6(CAS DataBase Reference)
EPA Substance Registry System
Cobaltocene (1277-43-6)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-68-42/43-40
Safety Statements 
16-33-7/9-36/37-22
RIDADR 
UN 1325 4.1/PG 3
WGK Germany 
3
RTECS 
GG0350000
TSCA 
Yes
HazardClass 
4.1
PackingGroup 
II
HS Code 
29319090
Toxicity
mmo-sat 3333 mg/plate EMMUEG 19(Suppl 21),2,92
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H341Suspected of causing genetic defects

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
339164
Product name
Bis(cyclopentadienyl)cobalt(II)
Packaging
2g
Price
$125
Updated
2024/03/01
Sigma-Aldrich
Product number
339164
Product name
Bis(cyclopentadienyl)cobalt(II)
Packaging
10g
Price
$490
Updated
2024/03/01
Alfa Aesar
Product number
016857
Product name
Bis(cyclopentadienyl)cobalt
Packaging
5g
Price
$199
Updated
2024/03/01
Alfa Aesar
Product number
016857
Product name
Bis(cyclopentadienyl)cobalt
Packaging
1g
Price
$57
Updated
2023/06/20
Strem Chemicals
Product number
27-0475
Product name
Bis(cyclopentadienyl)cobalt(II), min. 98% (Cobaltocene)
Packaging
1g
Price
$40
Updated
2024/03/01
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BIS(CYCLOPENTADIENYL)COBALT Chemical Properties,Usage,Production

Chemical Properties

dark violet crystals

Uses

Polymerization inhibitor of olefins up to 200C, Diels–Alder reaction, catalyst, paint drier, oxygen stripping agent.

Uses

Bis(cyclopentadienyl)cobalt is used to catalyze the preparation of pyridines from alkynes and nitriles. It acts as a polymerization inhibitor of olefins. It is a common one-electron reducing agent in the laboratory. It reacts with carbon monoxide to prepare cobalt(I) derivative, cyclopentadienylcobalt dicarbonyl. It also serves as an internal standard in cyclic voltametry. Further, it finds use in Diels-Alder reactions. In addition to this, it is used as a paint drier and as an oxygen stripping agent.

Definition

A metallocene.

General Description

Black-purple crystals or black solid. Sublimes at 104°F and 0.1 mm Hg.

Air & Water Reactions

Air-sensitive. Highly flammable. Insoluble in water.

Reactivity Profile

BIS(CYCLOPENTADIENYL)COBALT is very sensitive to air and is readily oxidized. BIS(CYCLOPENTADIENYL)COBALT is also sensitive to exposure to light. Readily oxidized by water and dilute acids .

Hazard

Toxic by ingestion.

Health Hazard

ACUTE/CHRONIC HAZARDS: BIS(CYCLOPENTADIENYL)COBALT is toxic by ingestion.

Fire Hazard

Vendor information indicates that BIS(CYCLOPENTADIENYL)COBALT is flammable.

Safety Profile

Poison by intraperitoneal route.Questionable carcinogen with experimental tumorigenicdata. Mutation data reported. When heated todecomposition it emits acrid smoke and fumes.

BIS(CYCLOPENTADIENYL)COBALT Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(CYCLOPENTADIENYL)COBALT Suppliers

Belgium 2 China 60 Finland 1 Germany 6 India 1 Japan 4 Russia 1 South Korea 1 Switzerland 3 United Kingdom 7 United States 19 Global 105
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View Lastest Price from BIS(CYCLOPENTADIENYL)COBALT manufacturers

Career Henan Chemical Co
Product
BIS(CYCLOPENTADIENYL)COBALT 1277-43-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

1277-43-6, BIS(CYCLOPENTADIENYL)COBALTRelated Search:

SODIUM CYCLOPENTADIENIDE CYCLOPENTYLMAGNESIUM CHLORIDE (TRIMETHYL)CYCLOPENTADIENYLPLATINUM (IV) CYCLOPENTADIENYLHAFNIUM TRICHLORIDE CYCLOPENTADIENYLTITANIUM TRICHLORIDE LITHIUM CYCLOPENTADIENIDE COBALTOCENE HEXAFLUOROPHOSPHATE BIS(PENTAMETHYLCYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE [1,1'-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II) BIS(CYCLOPENTADIENYL)COBALT BIS(PENTAMETHYLCYCLOPENTADIENYL)COBALT BIS(ETHYLCYCLOPENTADIENYL)COBALT(II) (S)-(+)-COP-OAC CATALYST, 95% BIS(METHYLCYCLOPENTADIENYL)COBALT (II) (R)-(-)-COP-CL CATALYST (R)-(-)-COP-OAC CATALYST COP-CL CATALYST BIS(ETHYLCYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE

  • Bis(cyclopentadienyl)cobalt (II), (Cobaltocene)
  • Bis(cyclopentadienyl)cobalt(II),min.98%(Cobaltocene)
  • Cobaltocene,98%
  • CobaltoceneBis(cyclopentadienyl)cobalt
  • Bis(cyclopentadienyl)cobalt (II), 98+% (Cobaltocene)
  • di(cyclopenta-1,3-dien-1-yl)cobalt
  • Bis(cyclopentadienyl)cobalt(Ⅱ)
  • Cobaltocene SynonyMs Bis(cyclopentadienyl)cobalt
  • Ferrocene cobalt
  • BIS(CYCLOPENTADIENYL)COBALT
  • BIS(CYCLOPENTADIENYL)COBALT(II)
  • COBALTOCENE
  • bis-(eta<sup>5</sup>-Cyclopentadienyl) cobalt
  • Cobalt, bis(eta<sup>5</sup>-cyclopentadienyl)-
  • Cobalt, bis(eta5-2,4-cyclopentadien-1-yl)-
  • Cobalt, di-pi-cyclopentadienyl-
  • cobalt,bis(η5-2,4-cyclopentadien-1-yl)-
  • Dicyclopentadienylcobalt
  • di-pi-cyclopentadienyl-cobal
  • Kobaltocen
  • tocene
  • BIS(CYCLOPENTADIENYL)COBALT ISO 9001：2015 REACH
  • cobaltocene(1277-43-6)
  • Bis (cyclopentadiene) cobalt
  • 1277-43-6
  • CoC5H52
  • C5H52Co
  • C10H10Co
  • 2C5H5Co
  • metallocene
  • Cobalt
  • Precursors by Metal
  • Vapor Deposition Precursors