2-BROMOPHENETHYLALCOHOL
- Product Name
- 2-BROMOPHENETHYLALCOHOL
- CAS No.
- 1074-16-4
- Chemical Name
- 2-BROMOPHENETHYLALCOHOL
- Synonyms
- 2-(2-bromophenyl)ethan-1-ol;2-(2-BROMOPHENYL)ETHANOL;2-bromophenylethyl alcohol;2-BROMOPHENYLETHANOL;O-bromophenylethanol;2-BroMobenzeneethanol;2-BROMOPHENETHYLALCOHOL;Benzeneethanol, 2-bromo-;o-BroMophenethyl Alcohol;o-BroMophenylethyl Alcohol
- CBNumber
- CB7386118
- Molecular Formula
- C8H9BrO
- Formula Weight
- 201.06
- MOL File
- 1074-16-4.mol
2-BROMOPHENETHYLALCOHOL Property
- Boiling point:
- 97 °C/0.7 mmHg (lit.)
- Density
- 1.483 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.577(lit.)
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- DMSO, Ethyl Acetate
- pka
- 14.70±0.10(Predicted)
- form
- Liquid
- Specific Gravity
- 1.483
- color
- Clear slightly yellow
- InChI
- InChI=1S/C8H9BrO/c9-8-4-2-1-3-7(8)5-6-10/h1-4,10H,5-6H2
- InChIKey
- ADLOWZRDUHSVRU-UHFFFAOYSA-N
- SMILES
- C1(CCO)=CC=CC=C1Br
Safety
- Safety Statements
- 24/25
- WGK Germany
- 3
- HS Code
- 29062990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 394548
- Product name
- 2-Bromophenethyl alcohol
- Purity
- 99%
- Packaging
- 5g
- Price
- $30.59
- Updated
- 2025/07/31
- Product number
- B3516
- Product name
- 2-(2-Bromophenyl)ethyl Alcohol
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $74
- Updated
- 2025/07/31
- Product number
- B3516
- Product name
- 2-(2-Bromophenyl)ethyl Alcohol
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $243
- Updated
- 2025/07/31
- Product number
- B686535
- Product name
- 2-(2-Bromophenyl)ethanol
- Packaging
- 10g
- Price
- $140
- Updated
- 2021/12/16
- Product number
- CS-W002365
- Product name
- 2-(2-Bromophenyl)ethanol
- Purity
- >97.0%
- Packaging
- 100g
- Price
- $153
- Updated
- 2021/12/16
2-BROMOPHENETHYLALCOHOL Chemical Properties,Usage,Production
Chemical Properties
clear slightly yellow liquid
Uses
2-Bromophenethyl alcohol is used as an end capping reagent during the synthesis of rod-coil block copolymers and also as a test compound in the study to evaluate the potential Aedes aegypti repellent chemotype.
Uses
2-Bromophenethyl alcohol is a brominated phenethanol derivative used as a building block in the preparation or bicyclic and tricyclic heterocycles.
General Description
2-Bromophenethyl alcohol is a phenethyl alcohol derivative. It participates in the preparation of novel P-chirogenic phosphines with a sulfur-chelating arm (P*,S-hybrid ligand).
Synthesis
57486-69-8
1074-16-4
General method: anhydrous CaCl2 (1.12 g, 10.2 mmol) was dissolved in ethanol (50 mL) in a three-necked round-bottomed flask under argon protection. The solution was cooled to 0 °C, followed by slow addition of NaBH4 (0.19 g, 5.1 mmol) at the same temperature. The resulting suspension was stirred at 0 °C for 30 min, after which an ethanol solution (60 mL) of methyl 2-(2-bromophenyl)acetate (S5a, 1.0 g, 3.4 mmol) was added dropwise at the same temperature. The reaction mixture was continued to be stirred at 0 °C for 30 min, and then raised to room temperature and stirred for 15 h. The reaction was carried out at 0 °C. Upon completion of the reaction, 50 mL of a mixture of water and dichloromethane (1:1, v/v) was added to the mixture and sonicated for 1 hour. The mixture was vacuum filtered through diatomaceous earth and the filtrate was concentrated under reduced pressure. The crude product was dissolved in 50 mL of water and extracted with dichloromethane (3 x 30 mL). The organic phases were combined, dried with anhydrous Na2SO4 and the solvent was evaporated under reduced pressure to give the target product 2-(2-bromophenyl)ethanol (S6a-S6d). The products were characterized as follows: 2-(2-bromo-4,5-dimethoxyphenyl)ethanol (S6a): brown oil in 60% yield (2.56 g); 2-(2-bromo-5-methoxyphenyl)ethanol (S6b): colorless transparent oil in 42% yield (1.29 g); 2-(2-bromo-4-methoxyphenyl)ethanol (S6c): colorless transparent oily substance, yield 55% (1.03 g); 2-(2-bromophenyl)ethanol (S6d): colorless transparent oily substance, yield 55% (2.41 g).
References
[1] Tetrahedron, 2013, vol. 69, # 42, p. 8914 - 8920
2-BROMOPHENETHYLALCOHOL Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-BROMOPHENETHYLALCOHOL manufacturers
- Product
- 2-BROMOPHENETHYLALCOHOL 1074-16-4
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10
- Release date
- 2024-07-07
- Product
- 2-BROMOPHENETHYLALCOHOL 1074-16-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- 2-BROMOPHENETHYLALCOHOL 1074-16-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09