ChemicalBook > CAS DataBase List > 2-Bromopyrimidine

2-Bromopyrimidine

Product Name
2-Bromopyrimidine
CAS No.
4595-60-2
Chemical Name
2-Bromopyrimidine
Synonyms
2-Bromopyrimide;2-BroMpyriMidine;2-bromo-pyrimidin;2-BROMOPYRIMIDINE;2 Bromo pydrimine;2-Bromo-1,3-diazine;PYRIMIDINE, 2-BROMO-;2-Bromopyrimidine >2 - broMine pyriMidine;2-Bromopyrimidine,97+%
CBNumber
CB7386976
Molecular Formula
C4H3BrN2
Formula Weight
158.98
MOL File
4595-60-2.mol
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2-Bromopyrimidine Property

Melting point:
55-57 °C (lit.)
Boiling point:
62-64°C (1.5 mmHg)
Density 
1.6448 (rough estimate)
refractive index 
1.5260 (estimate)
Flash point:
62-64°C/1.5mm
storage temp. 
-20°C
solubility 
DMSO (Sparingly), Methanol (Slightly)
pka
-1.59±0.13(Predicted)
form 
Crystalline Powder
color 
Off-white
Water Solubility 
Miscible with water.
BRN 
605945
CAS DataBase Reference
4595-60-2(CAS DataBase Reference)
NIST Chemistry Reference
Pyrimidine, 2-bromo-(4595-60-2)
EPA Substance Registry System
Pyrimidine, 2-bromo- (4595-60-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29335990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
245844
Product name
2-Bromopyrimidine
Purity
95%
Packaging
1g
Price
$27.7
Updated
2024/03/01
Sigma-Aldrich
Product number
245844
Product name
2-Bromopyrimidine
Purity
95%
Packaging
5g
Price
$98.2
Updated
2024/03/01
TCI Chemical
Product number
B2832
Product name
2-Bromopyrimidine
Purity
>98.0%(GC)
Packaging
5g
Price
$95
Updated
2024/03/01
TCI Chemical
Product number
B2832
Product name
2-Bromopyrimidine
Purity
>98.0%(GC)
Packaging
25g
Price
$267
Updated
2024/03/01
Alfa Aesar
Product number
A13791
Product name
2-Bromopyrimidine, 98+%
Packaging
5g
Price
$78.65
Updated
2024/03/01
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2-Bromopyrimidine Chemical Properties,Usage,Production

Chemical Properties

Off-white crystalline powder

Uses

2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.

Preparation

The recent synthesis of 2-bromopyrimidine by diazotization of 2-aminopyrimidine in hydrobromic acid has furnished a convenient starting material for other 2-substituted pyrimidines.

General Description

2-Bromopyrimidine undergoes microwave-assisited aminocarbonylation at C-2 with palladium and Mo(CO)6.

2-Bromopyrimidine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromopyrimidine Suppliers

Carbosynth
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NiCHe Materials Ltd.
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View Lastest Price from 2-Bromopyrimidine manufacturers

Shanghai UCHEM Inc.
Product
2-Bromopyrimidine 4595-60-2
Price
US $7.00-214.00/g
Min. Order
5g
Purity
0.98
Supply Ability
25kg
Release date
2023-12-25
Henan Fengda Chemical Co., Ltd
Product
2-Bromopyrimidine 4595-60-2
Price
US $122.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-11
Hebei Zhanyao Biotechnology Co. Ltd
Product
2-Bromopyrimidine 4595-60-2
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2021-10-12

4595-60-2, 2-BromopyrimidineRelated Search:


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