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TITANIUM OXIDE

Product Name
TITANIUM OXIDE
CAS No.
12065-65-5
Chemical Name
TITANIUM OXIDE
Synonyms
TIO2 ANATASE;TIO2 ANATASE B101;TITANIUM OXIDE BLACK;trititanium pentoxide;TITANIUM DIOXIDE RUTIL;TITANIUM DI OXIDE B101;TIO2-ENAMEL GRADE-5FCL;Trititanium pentaoxide;Titanium(III,IV) oxide;Titanium oxide (Ti3O5)
CBNumber
CB7401224
Molecular Formula
H2OTi
Formula Weight
65.88
MOL File
12065-65-5.mol
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TITANIUM OXIDE Property

Melting point:
1800°C
Density 
4.20
solubility 
Soluble in hot concentrated sulfuric acid, hydrofluoric acid and alkali.
form 
Pellet
Specific Gravity
4.2
color 
Black
Crystal Structure
Dimorphic (120°C): Low temperature: anasovite type monoclinic; High temperature: pseudobrookite orthorhombic
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H341Suspected of causing genetic defects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Alfa Aesar
Product number
039000
Product name
Titanium oxide
Purity
99.9% (metals basis)
Packaging
25g
Price
$100.65
Updated
2024/03/01
Alfa Aesar
Product number
039000
Product name
Titanium oxide
Purity
99.9% (metals basis)
Packaging
100g
Price
$308.65
Updated
2024/03/01
Alfa Aesar
Product number
041635
Product name
Titanium oxide
Purity
99.9% (metals basis)
Packaging
10g
Price
$75.7
Updated
2022/04/27
Alfa Aesar
Product number
041635
Product name
Titanium oxide
Purity
99.9% (metals basis)
Packaging
50g
Price
$277
Updated
2021/12/16
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TITANIUM OXIDE Chemical Properties,Usage,Production

Chemical Properties

Ti3O5: (1) Rel.molar mass (Mr ): 223.0070; (2) wt.% Ti: 64.1; (3) Color: Dark blue; (4) crystal lattice structure: dimorphic (120°C) Low T: Anasovite-type I Monoclinic, C2/m, Z = 4 a = 975.2 pm; b = 380.2 pm; c = 944.2 pm; β = 91.55° High T: Pseudobrookite (orthorhombic); (5) ρcalc. = 4900 kg.m–3, m.p. = 1777°C

Physical properties

Dark blue crystals. Anasovite Type II is similar to that identified in titania slags. Can be stabilized at room temperature with a small amount of iron.

Uses

Nanocrystalline titanium oxide electrodes is useful for photo voltaic applications. It plays an important role as photocatalyst under visible light radiation. Treated titanium oxide nanotubes play a significant part in the development of nano-scale hydroxy apatite. It is too utilized as catalysts.

Preparation

Anosovite can be prepared in the following ways:
(i) By the hydrogen reduction of solid TiO2 at temperature around 1300°C16 according to the following reaction scheme: 3TiO2(s) + H2(g) —> T3O5(s) + H2O(g) (1300°C).
(ii) By mixing intimately stoichiometric quantities of titanium metal and titanium dioxide in an electric-arc furnace under an argon atmosphere according to the following reaction scheme:
5TiO2(s) + Ti(s) —> 2Ti3O5(s) (1150°C)
followed by annealing in a vacuum of the crushed material for 2 weeks at 1150°C in a sealed silica tube. This oxide is dimorphic with a rapid phase transition from semiconductor to metal occurring at roughly 120°C. α-Ti3O5—> β-Ti3O5 (120°C).
The low-temperature form (α-Ti3O5), also called anosovite type I, crystallizes with a monoclinic unit cell with the Ti-O bond distances ranging from 178 to 221 pm. The structure can be described in terms of TiO6 8– octahedra joined by sharing the edge and corners to form an infinite three-dimensional network. Anosovite I is obtained by the hydrogen reduction of pure rutile at 1300°C. The high-temperature form (β-Ti3O5), also called anosovite type II, is a slightly deformed pseudobrookite structure (AB2O5) with the Ti-O bond distances ranging from 191 to 210 pm. The type II is obtained by hydrogen reduction at 1500°C with magnesia as a catalyst. The anasovite type II is similar to that identified in titanium slags. It can be stabilized at room temperature with a small amount of iron.

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TITANIUM OXIDE Suppliers

Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9978
Advantage
55
Suzhou yacoo science co.,Ltd
Tel
0512-87182056 18013166090
Fax
0512-87182056
Email
lingling.qi@yacoo.com.cn
Country
China
ProdList
7295
Advantage
60
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Forsman Scientific ( Beijing ) Co., Ltd.
Tel
13811783941 18611317957
Fax
+86-10-64646568
Email
linwp@forsman.com.cn
Country
China
ProdList
851
Advantage
58
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
17687
Advantage
55
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View Lastest Price from TITANIUM OXIDE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
TITANIUM OXIDE 12065-65-5
Price
US $10.00-8.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2022-09-19
Hebei Mojin Biotechnology Co., Ltd
Product
TITANIUM OXIDE 12065-65-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-11
Career Henan Chemical Co
Product
TITANIUM OXIDE 12065-65-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%HPLC
Supply Ability
100KG
Release date
2020-02-01

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