CERIUM (III) IODIDE

ChemicalBook > CAS DataBase List > CERIUM (III) IODIDE

CERIUM (III) IODIDE

Product Name: CERIUM (III) IODIDE
CAS No.: 7790-87-6
Chemical Name: CERIUM (III) IODIDE
Synonyms: CeI3;CEROUS IODIDE;CERIUM IODIDE;Cerium(Ⅲ)iodide;cerium triiodide;CEROUS TRIIODIDE;Cerium(lll) iodide;CERIUM (III) IODIDE;Cerium(III) triiodide;SRM Cerium(III ) Iodide
CBNumber: CB7420788
Molecular Formula: CeI3
Formula Weight: 520.83
MOL File: 7790-87-6.mol

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CERIUM (III) IODIDE Property

Melting point:: 750 °C(lit.)
Boiling point:: 1400℃ [CRC10]
solubility: soluble in H2O
form: crystal
color: yellow
Water Solubility: Soluble in water
Sensitive: Hygroscopic
Merck: 14,1999
CAS DataBase Reference: 7790-87-6(CAS DataBase Reference)

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Safety

Hazard Codes: T,Xi
Risk Statements: 61-42/43-36/38
Safety Statements: 53-26-36/37/39-45
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 466085
Product name: Cerium(III) iodide
Purity: anhydrous, beads, 10mesh, 99.99% trace metals basis
Packaging: 1g
Price: $123
Updated: 2024/03/01

Alfa Aesar

Product number: 013641
Product name: Cerium(III) iodide, ultra dry, 99.9% (REO)
Packaging: 5g
Price: $255
Updated: 2024/03/01

Alfa Aesar

Product number: 013641
Product name: Cerium(III) iodide, ultra dry, 99.9% (REO)
Packaging: 1g
Price: $85.1
Updated: 2023/06/20

Alfa Aesar

Product number: 043373
Product name: Cerium(III) iodide, ultra dry
Purity: 99.9% (REO)
Packaging: 100g
Price: $1259
Updated: 2021/12/16

Strem Chemicals

Product number: 58-5820
Product name: Cerium(III) iodide, anhydrous (99.99%-Ce) (REO) PURATREM
Purity: anhydrous (99.99%-Ce) (REO) PURATREM
Packaging: 5g
Price: $149
Updated: 2023/06/20

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CERIUM (III) IODIDE Chemical Properties,Usage,Production

Chemical Properties

white or reddish white crystal(s) [MER06]

Uses

Cerium(III) iodide is used as a pharmaceutical intermediate.

Reactivity Profile

Organocerium reagents prepared from cerium triiodide and organolithiums have reduced basicity and possess enhanced nucleophilicity toward the carbonyl group; promotes aldol reaction between α-halo ketones and aldehydes; in combination with LiAlH4 is a selective 1,2-reducing agent.

reaction suitability

reagent type: catalyst
core: cerium

Synthesis

Pure CeI3 (Cerium (III) iodide) is prepared by reacting metallic cerium with iodine or mercury(II) iodide at high temperature.Another method is to dissolve CeO2 in an aqueous HI solution, adding 12 moles of NH4I per mole of CeO2 and evaporating the mixture to dryness. The mixture is heated in vacuo at 300- 350 °C to leave pure CeI3. CeI3 is prepared in situ by reacting powdered cerium with iodine in THF[1-4].

Precautions

Cerium (III) iodide is extremely hygroscopic and turns brown when exposed to air owing to the liberation of iodine. This reagent should be stored under nitrogen and handled in a glove bag.

References

1. Jantsch, G.; Grubitsch, H.; Hoffmann, F.; Alber, H. ZC 1929, 185, 49.
2. Asprey, L. B.; Keenan, T. K.; Kruse, F. H. IC 1964, 3, 1137.
3. Taylor, M. D. CRV 1962, 62, 503.
4. Imamoto, T.; Kusumoto, T.; Tawarayama, Y.; Sugiura, Y.; Mita, T.; Hatanaka, Y.; Yokoyama, M. JOC 1984, 49, 3904.

CERIUM (III) IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from CERIUM (III) IODIDE manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: Cerium(Iii) Iodide 7790-87-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.2%
Supply Ability: 50000KG/month
Release date: 2024-10-22

7790-87-6, CERIUM (III) IODIDERelated Search:

LUTETIUM(III) IODIDE YTTRIUM IODIDE SAMARIUM(II) IODIDE BISMUTH ACETATE LANTHANUM IODIDE SCANDIUM IODIDE Cerium fluoride Cerium(III) bromide hydrate CERIUM (III) IODIDE HYDRATE CERIUM CERIUM (III) HYDRIDE CERIUM (III) IODIDE Cerium Iodide

Ceriumiodidehydrateyellowxtl

cerium triiodide

CERIUM(III) IODIDE, ANHYDROUS, POWDER,99 .99%

CERIUM(III) IODIDE, ANHYDROUS, 99.999%

CERIUM(III) IODIDE, ANHYDROUS, BEADS, -10 MESH, 99.99%

Cerium(III)iodide,ultradry,99.9%(REO)

Cerium(Ⅲ)iodide

cerium(iii) iodide, ultra dry

Cerium(III) iodide anhydrous

Cerium(III) triiodide

SRM Cerium(III ) Iodide

CeriuM Iodide, 99.9% (RE EleMent base)

CEROUS TRIIODIDE

CEROUS IODIDE

CERIUM IODIDE

CERIUM (III) IODIDE

CeI3

Cerium(III) iodide, anhydrous (99.99%-Ce) (REO) PURATREM

CERIUM (III) IODIDE ISO 9001：2015 REACH

Cerium(III) iodide anhydrous, beads, 10 mesh

Cerium(lll) iodide

7790-87-6

CeI3XH2O

CeI3稾H2O

Cerium

Catalysis and Inorganic Chemistry

Rare-Earth Metals

metal halide