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2,4-DIBROMOTOLUENE

Product Name
2,4-DIBROMOTOLUENE
CAS No.
31543-75-6
Chemical Name
2,4-DIBROMOTOLUENE
Synonyms
NSC 139877;2,4-DIBROMOTOLUENE;o,p-Dibromotoluene;Pramexol Impurity 59;2,4-Dibromotoluene>2,4-Second Bromotoluene;1-Methyl-2,4-dibromobenzene;2,4-Dibromo-1-methylbenzene;2,4-dibromo-1-methyl-benzen;1,3-Dibromo-4-methylbenzene
CBNumber
CB7423310
Molecular Formula
C7H6Br2
Formula Weight
249.93
MOL File
31543-75-6.mol
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2,4-DIBROMOTOLUENE Property

Melting point:
-10 °C
Boiling point:
243 °C
Density 
1.85
Flash point:
109℃
refractive index 
1.601
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Light orange to Yellow to Green
InChI
InChI=1S/C7H6Br2/c1-5-2-3-6(8)4-7(5)9/h2-4H,1H3
InChIKey
GHWYNNFPUGEYEM-UHFFFAOYSA-N
SMILES
C1(C)=CC=C(Br)C=C1Br
CAS DataBase Reference
31543-75-6(CAS DataBase Reference)
EPA Substance Registry System
2,4-Dibromotoluene (31543-75-6)
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Safety

Hazard Codes 
Xi
TSCA 
Yes
HS Code 
2903998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D3591
Product name
2,4-Dibromotoluene
Packaging
1G
Price
$17
Updated
2025/07/31
TCI Chemical
Product number
D3591
Product name
2,4-Dibromotoluene
Packaging
5G
Price
$47
Updated
2025/07/31
Matrix Scientific
Product number
075899
Product name
2,4-Dibromo-1-methylbenzene
Purity
95+%
Packaging
100g
Price
$245
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-9-V2
Product name
2,4-Dibromotoluene
Purity
98%
Packaging
100g
Price
$285
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0010757
Product name
2,4-DIBROMOTOLUENE
Purity
95.00%
Packaging
1G
Price
$618.25
Updated
2021/12/16
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2,4-DIBROMOTOLUENE Chemical Properties,Usage,Production

Chemical Properties

light yellow liquid

Synthesis Reference(s)

The Journal of Organic Chemistry, 53, p. 5545, 1988 DOI: 10.1021/jo00258a030

Synthesis

108-88-3

612-75-9

452-63-1

95-46-5

31543-75-6

General procedure: 3,3'-dimethylbiphenyl, 2-bromo-5-fluorotoluene, 2-bromotoluene and 2,4-dibromotoluene were synthesized using the following general procedure: boron trifluoride (TFB) was pre-synthesized prior to use according to the literature methods [7-9]. The corresponding aromatics (4 mmol) were dissolved in Freon R 113 (4.1 mL) and the solution was cooled to -25 °C. The corresponding TFB (2 mmol) was slowly added to the aromatic solution under vigorous stirring, followed by removal of the cooling bath. The reaction mixture was stirred at 45 °C for 5 hours. Upon completion of the reaction, the reaction mixture was treated with H2O and filtered to remove the metal fluoride precipitate. Subsequently, the liquid phase was treated with 10% NaNO2 aqueous solution to remove traces of bromine and 30% CaCl2 aqueous solution to remove F- anions. Finally, Freon R 113 was removed from the organic phase by evaporation and the resulting product was purified by rapid chromatography on silica gel, the eluent being a hexane:EtOAc solvent mixture.

References

[1] Journal of Fluorine Chemistry, 2016, vol. 192, p. 120 - 123

2,4-DIBROMOTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4-DIBROMOTOLUENE Suppliers

Americas 1 Belgium 1 China 178 Europe 1 Germany 4 India 7 Japan 3 Switzerland 1 United Kingdom 8 United States 26 Global 230
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
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View Lastest Price from 2,4-DIBROMOTOLUENE manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
2,4-DIBROMOTOLUENE 31543-75-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-13
Shaanxi Dideu Medichem Co. Ltd
Product
2,4-DIBROMOTOLUENE 31543-75-6
Price
US $1.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20T
Release date
2024-07-20
Career Henan Chemical Co
Product
2,4-DIBROMOTOLUENE 31543-75-6
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-09

31543-75-6, 2,4-DIBROMOTOLUENERelated Search:

Tetrabromo-2-sulfobenzoic acid cyclic anhydride 3-HYDROXY-2,4,6-TRIBROMOBENZALDEHYDE 2,4-DIBROMO-5-METHOXYTOLUENE 3-METHYL-2,4,6-TRIBROMOANILINE 3,4,5,6-Tetrabromophenolsulfonephthalein 2,4-DIBROMOMESITYLENE 2,3,4,5,6-Pentabromoethylbenzene 3,4,5,6-TETRABROMO-O-CRESOL 3,4,5,6-TETRABROMOPHTHALIMIDE Sulfobromophthalein sodium Tetrabromophthalic anhydride 1-Amino-2,4-dibromoanthraquinone Bromocresol green 2,4,6-TRIBROMOTOLUENE 3,5-Dibromobenzoic acid 3,5-Dibromotoluene, 98+%,3,5-DIBROMOTOLUENE 2,5-DIBROMOTOLUENE,2,5-Dibromotoluene,97%,f,5-DIBROMOTOLUENE, 98%,2,5-Dibromotoluene 97% α,3-dibromotoluene,à,3-dibromotoluene,ALPHA,3-DIBROMOTOLUENE,ALPHA,M-DIBROMOTOLUENE

  • 1,3-Dibromo-4-methylbenzene
  • 2,4-dibromo-1-methyl-benzen
  • Benzene, 2,4-dibromo-1-methyl-
  • Benzene,2,4-dibromo-1-methyl-
  • 2,4-DIBROMOTOLUENE
  • 2,4-Dibromo-1-methylbenzene
  • 1-Methyl-2,4-dibromobenzene
  • NSC 139877
  • 2,4-Second Bromotoluene
  • o,p-Dibromotoluene
  • 2,4-DibroMo-1-Methylbenzene, 95+%
  • 2,4-Dibromotoluene&gt
  • Pramexol Impurity 59
  • 31543-75-6
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • Halogen toluene
  • Bromine Compounds
  • bc0001