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Sodium glucoheptonate

Background
Product Name
Sodium glucoheptonate
CAS No.
31138-65-5
Chemical Name
Sodium glucoheptonate
Synonyms
SODIUM HEPTAGLUCONATE;Sodium Glucoheptonate Dihydrate;GAL[2346AC]Β(1-3)GLCN3[46BZD]-Β-MP;Squalane 111-01-3;LacMP 4'-OH, per OBn;LacMP 3'-OH, per OBn;Natriumglucoheptonat;SODIUM GLUCOHEPTONATE;SODIUM GLUCO HEPTANATE;SODIUM A-GLUCOHEPTONATE
CBNumber
CB7430675
Molecular Formula
C7H15NaO8
Formula Weight
250.18
MOL File
31138-65-5.mol
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Sodium glucoheptonate Property

Melting point:
177 °C
Boiling point:
117℃[at 101 325 Pa]
Density 
1.45[at 20℃]
refractive index 
132.5 ° (C=1, H2O)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
DMSO: 50 mg/mL (175.94 mM);Ethanol: Insoluble
form 
Powder
color 
White
Water Solubility 
Freely soluble in water
LogP
-6.44 at 20℃
CAS DataBase Reference
31138-65-5(CAS DataBase Reference)
EPA Substance Registry System
D-gluco-Heptonic acid, monosodium salt, (2.xi.)- (31138-65-5)
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Safety

Safety Statements 
24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
2918.19.9000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

Precautionary statements

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

TCI Chemical
Product number
G0330
Product name
Gal[2346Ac]β(1-3)GalN3[46Bzd]-β-MP
Packaging
1G
Price
$417
Updated
2024/03/01
TCI Chemical
Product number
M1763
Product name
Neu5GcAc[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP
Packaging
200MG
Price
$859
Updated
2024/03/01
TCI Chemical
Product number
G0330
Product name
Gal[2346Ac]β(1-3)GalN3[46Bzd]-β-MP
Packaging
5G
Price
$1365
Updated
2024/03/01
TCI Chemical
Product number
G0311
Product name
Gal[2346Ac]β(1-3)GlcNPhth[46Bzd]-β-MP
Packaging
1G
Price
$206
Updated
2024/03/01
TCI Chemical
Product number
G0311
Product name
Gal[2346Ac]β(1-3)GlcNPhth[46Bzd]-β-MP
Packaging
5G
Price
$617
Updated
2024/03/01
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Sodium glucoheptonate Chemical Properties,Usage,Production

Background

The value of the sugar acids and their soluble salts and lactones as sequestering or chelating agents for metal ions, particularly in alkaline solutions, has been recognized for many years. These materials have been used industrially in alkaline de-rusting processes, bottle washing, descaling, for the prevention of iron-staining in paper making, and in the processing of cotton and other textiles, among numerous other applications which could be mentioned. Soil gluconates, particularly sodium gluconate, have become the most widespread use for these purposes, primarily because of their availability and relatively low cost. Kiliani prepared sodium glucoheptonate as early as 1886 by the reaction of hydrocyanic acid with glucose in an aqueous solution, and many modified methods for the preparation of the valuable salt have been suggested. However, it is available only in highly coloured amber to red or red-brown solutions. Such highly colored sequestering agents are unsuitable in many applications in the paper, textile and pharmaceutical industries.

Uses

Sodium glucoheptonate is used for cleaning metal, mercerizing, paint stripping, and aluminum etching. It is also used to mercerize cotton, linen, hemp, and other plant-based fibers to increase strength and add luster to their overall appearance of threads and fabrics.

Synthesis

98 g (2 mol) of sodium cyanide and 300 g of water were charged into a flask fitted with a stirrer, thermometer and a connection to a water jet aspirator. The contents of the flask were cooled to 2 ℃. using an ice bath. 396 g (2 mol) of dextrose hydrate were charged into the flask over about 30 minutes. When the sugar had all been charged, the temperature rose to 8 ℃., when the vacuum jet was turned on to provide a vacuum of about 40 mm of Hg. Within about 30 minutes, the temperature rose to 27 ℃., when the ammonia began to boil off vigorously. Within approximately 1 hour, the alpha sodium glucoheptonate dihydrate began to crystallize. The removal of the ammonia was continued at 27 ℃ and a vacuum of 33-40 mm of Hg for 6 hours. The crystals were filtered, water washed, and air dried. The first crop yield of alpha sodium glucoheptonate was -328 grams or 57.7% of the theoretical.

Sodium glucoheptonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Sodium glucoheptonate Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
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Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9809
Advantage
59
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Hunan Hui Bai Shi Biotechnology Co., Ltd.
Tel
0731-85526065 13308475853
Email
ivy@hnhbsj.com
Country
China
ProdList
4554
Advantage
62
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
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View Lastest Price from Sodium glucoheptonate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
SODIUM GLUCOHEPTONATE 31138-65-5
Price
US $40.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/Week
Release date
2024-05-08
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Monosodium D-glycero-D-gulo-heptonate 31138-65-5
Price
US $70.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-05-31
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Sodium glucoheptonate 31138-65-5
Price
US $0.00/G
Min. Order
10G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-13

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