ChemicalBook > CAS DataBase List > Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane

Product Name
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane
CAS No.
68478-92-2
Chemical Name
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane
Synonyms
KARSTEDT CATALYST;Karstedt;Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution;PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX;PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE COMPLEX;Pt catalyst;disiL;ex soL;oxane compL;Karstedt cat
CBNumber
CB7448548
Molecular Formula
C8H18OPtSi2
Formula Weight
381.48
MOL File
68478-92-2.mol
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Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Property

Melting point:
12-13 °C
Boiling point:
138 °C
Density 
0.984 g/mL at 25 °C
vapor pressure 
7 mm Hg ( 21 °C)
refractive index 
1.4954
Flash point:
86 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Light yellow to Yellow to Green
Specific Gravity
0.984
Water Solubility 
Miscible with toluene, xylene, isopropyl alcohol, double-vinyl silicone oil and vinyl terminated poly(dimethylsiloxane). Immiscible with water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Stability:
Flammable. Incompatible with reducing agents, oxidizing agents. Contact with water yields hydrogen gas.
EPA Substance Registry System
Platinum, 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes (68478-92-2)
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Safety

Hazard Codes 
T,Xi,Xn
Risk Statements 
61-10-20/21-37/38-41-62-36/37/38-38
Safety Statements 
53-16-26-36/37/39-45-36-36/37
RIDADR 
UN 1307 3/PG 3
WGK Germany 
3
TSCA 
Yes
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
479519
Product name
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution
Purity
in xylene, Pt ~2 %
Packaging
5g
Price
$179
Updated
2024/03/01
Sigma-Aldrich
Product number
479519
Product name
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution
Purity
in xylene, Pt ~2 %
Packaging
25g
Price
$694
Updated
2024/03/01
Alfa Aesar
Product number
041508
Product name
Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimethylsiloxane
Packaging
1g
Price
$55.6
Updated
2024/03/01
Alfa Aesar
Product number
041508
Product name
Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimethylsiloxane
Packaging
5g
Price
$278
Updated
2024/03/01
Sigma-Aldrich
Product number
479535
Product name
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution
Purity
0.05 M in poly(dimethylsiloxane), vinyl terminated
Packaging
5g
Price
$90.5
Updated
2024/03/01
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Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Chemical Properties,Usage,Production

Description

Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a kind of yellow liquid with a chemical formula of O[Si(CH3)2CH=CH2]2Pt and a molecular weight of 381.48. Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution (Pt-DVTMDS) has emerged as a novel organometallic compound with diverse applications in recent scientific research. This compound represents a coordination complex of platinum(0) and divinyl-1,1,3,3-tetramethyldisiloxane complex solution (DVTMDS). It has proven valuable in synthesizing diverse organometallic compounds, including gold(I)-DVTMDS and palladium(II)-DVTMDS. Furthermore, it has played a significant role in investigating chemical reactions, such as the catalytic hydrogenation of aldehydes and ketones theand oxidation of organic compounds. It was used as a precursor of the metallic phase to obtain a highly active electrochemical system Pt/SnO2 catalyst with a low metal load[1].

Chemical Properties

pale yellow solution

Uses

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a catalyst in the preparation of phenol functional silanes which are used as adhesion promoters.

Uses

Hydrosilylation Catalysts

General Description

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex is a platinum complex, commonly known as a Karstedt′s catalyst. It is generally employed as a catalyst in hydrosilylation reactions.

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Preparation Products And Raw materials

Raw materials

Preparation Products

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Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Suppliers

Australia 1 Belgium 1 China 201 Germany 6 India 5 Japan 3 Singapore 1 South Korea 2 Switzerland 1 The Netherlands 1 United Kingdom 3 United States 21 Global 246
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
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Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
Alfa Aesar
Tel
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Fax
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Email
tech@alfa.com
Country
India
ProdList
6905
Advantage
58
Hindustan Platinum Pvt., Ltd.
Tel
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Fax
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Email
dilip.chhugani@hp.co.in
Country
India
ProdList
53
Advantage
58
Johnson Matthey Chemicals India Pvt., Ltd.
Tel
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Fax
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Email
cctindia@matthey.com
Country
India
ProdList
47
Advantage
58
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View Lastest Price from Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane 68478-92-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-24
Shanghai UCHEM Inc.
Product
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane 68478-92-2
Price
US $54.00-184.00/g
Min. Order
5g
Purity
0.98
Supply Ability
25kg
Release date
2023-12-07
Wuhan KEMI-WORKS Chemical Co., Ltd.
Product
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane;Pt catalyst 68478-92-2
Price
US $1.00/Kg/Drum
Min. Order
0.1KG
Purity
Pt content: 0.1-10%
Supply Ability
1mt per month
Release date
2021-09-18

68478-92-2, Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxaneRelated Search:

Silicone oil (high temperature) Hexamethylcyclotrisiloxane Octamethylcyclotetrasiloxane 1,1,3,3,5,5-hexamethyl-1,3,5-trisilacyclohexane 1,1,3,3-Tetramethyldisiloxane Poly(dimethylsiloxane) POLYDIMETHYLSILOXANE Hexamethyldisiloxane POLY(DIMETHYLSILOXANE), HYDROXY TERMINATED Diethyl 1,3-acetonedicarboxylate Divinyltetramethyldisiloxane VINYL TERMINATED POLYDIMETHYLSILOXANE Vinyl terminated polydimethylsiloxane Platinum VINYLPENTAMETHYLDISILOXANE VINYLTETRAMETHYLDISILOXANE Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane

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  • PlatinuM(o) 1,3 divinyl-1,1,3,3 tetraMethyldisiloxane
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, 20% Pt, Product of UMicore
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution in xylene, Pt ~2 %
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, Pt 2000 ppM
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  • PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE COMPLEX
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  • pt(0)-1,3-divinyl-tetrame-disiloxane compl 0.100
  • KARSTEDT CATALYST
  • 2% Pt in xylene
  • 3.0% Pt in VINYL TERMINATED PDMS
  • 5% Pt in xylene
  • 2.0% Pt in VINYL TERMINATED PDMS
  • -1,1,3,3-tetramethyL
  • atinum(0)-1,3-divinyL
  • disiL
  • ex soL
  • oxane compL
  • 1,1,3,3-Tetramethyl-1,3-divinyldisiloxane, platinum salt
  • Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimeth
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  • Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution [in dimethylsiloxane]
  • Platinum-divinyltetramethyldisiloxane complex inxylene
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisilox
  • PlatinuM (0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, soln. in Isopropanol
  • PT(0)-1,3-DIVINYL-TETRAME-DISILOXANE COM PL 0.100M IN POLY(DIME-SILOXANE),VINYL
  • PLATINUM(0)-1,3-DIVINYL-TETRAME-DISILOXA NE IN POLY(DI-ME-SILOXANE),VINYLTERMINA
  • PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMEDI-SILOXANE COMPLEX, SOLUTION IN XYLENES (PT~2%)
  • Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane
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  • platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimethylsiloxane
  • Platinum, 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes platinum-divinyltetramethyldisiloxane complex karstedt catalyst platinum vinylsiloxane platinumvinylsiloxane Platinum,1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes
  • PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX IN XYLENE: (2.1-2.4%PT)
  • PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX IN XYLENE LOW COLOR
  • Karstedt Catalyst Solution Hydrosilylation. Usually supplied in propan-2-ol/ divinyltetramethyldisiloxane
  • 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane platinum
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution 0.05 M in poly(diMethylsiloxane), vinyl terMinated
  • PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution 0.1 M in poly(diMethylsiloxane), vinyl terMinated
  • Platinum(0) - 1,3-Divinyltetramethyldisiloxane Complex (19.0-21.5% as Pt) (contains 1,3-Divinyltetramethyldisiloxane)
  • Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, solution in vinyl terminated polydimethylsiloxane
  • Karstedt
  • Karstedt Catalys
  • Karstedt cat
  • Platinum(0)-1,3-divinyltetramethyldisiloxane complex
  • Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane (2% xylene)
  • Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Platinum
  • Platinum(0)- 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex solution
  • Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, solution in xylene, 2% Pt
  • Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane ISO 9001：2015 REACH
  • Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane(c,2% in xylene)