TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE

ChemicalBook > CAS DataBase List > TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE

TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE

Product Name: TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
CAS No.: 370-69-4
Chemical Name: TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
Synonyms: TTFP;Phosphite, tris(2,2,2-trifluoroethyl);Tris(2,2,2-trifluoroethyl) phosphite 99%;TTEP;TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE;Ethanol, 2,2,2-trifluoro-, phosphite (3:1);TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE, 99 %
CBNumber: CB7449383
Molecular Formula: C6H6F9O3P
Formula Weight: 328.07
MOL File: 370-69-4.mol

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TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Property

Boiling point:: 130-131 °C743 mm Hg(lit.)
Density: 1.487 g/mL at 25 °C(lit.)
refractive index: n20/D 1.324(lit.)
Flash point:: >230 °F
BRN: 1714041
InChI: InChI=1S/C6H6F9O3P/c7-4(8,9)1-16-19(17-2-5(10,11)12)18-3-6(13,14)15/h1-3H2
InChIKey: CBIQXUBDNNXYJM-UHFFFAOYSA-N
SMILES: P(OCC(F)(F)F)(OCC(F)(F)F)OCC(F)(F)F

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
F: 10-21
HS Code: 2920290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 270954
Product name: Tris(2,2,2-trifluoroethyl) phosphite
Purity: 99%
Packaging: 25g
Price: $172
Updated: 2024/03/01

Sigma-Aldrich

Product number: 270954
Product name: Tris(2,2,2-trifluoroethyl) phosphite
Purity: 99%
Packaging: 100g
Price: $311.4
Updated: 2024/03/01

TRC

Product number: T876718
Product name: Tris(2,2,2-trifluoroethyl) phosphite
Packaging: 1g
Price: $60
Updated: 2021/12/16

Apolloscientific

Product number: PC52710
Product name: Tris(2,2,2-trifluoroethyl) phosphite
Purity: 99%
Packaging: 5g
Price: $182
Updated: 2021/12/16

Apolloscientific

Product number: PC52710
Product name: Tris(2,2,2-trifluoroethyl) phosphite
Purity: 99%
Packaging: 10g
Price: $254
Updated: 2021/12/16

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TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Chemical Properties,Usage,Production

Uses

Tris(2,2,2-trifluoroethyl) phosphite was used in the synthesis of N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide via the Arbuzov reaction with 2-bromo-N-methoxy-N-methylacetamide.

Purification Methods

Fractionate it through a 10inch Helipak column [Krogh et al. J Org Chem 19 1124 1954]. Tris-[(3-trifluoromethylhydroxymethylene)-d-camphorato] europium (III) [Eu(tfc)3] [34830-11-0] M 893.6, m 195-299o (dec), ~220o, [ ] D +152o (c 2, CCl4, and varies markedly with concentration). Purify it by extraction with pentane, filter and the filtrate is evaporated and the residual bright yellow amorphous powder is dried at 100o/0.1mm for 36hours. A sample purified by fractional molecular distillation at 180-200o/0.004mm gave a liquid which solidified and softened at ~130o, and melted at ~180o and was analytically pure. IR (CCl4) 1630-1680cm-1 and NMR (CCl4) broad: -1.3 to 0.5, -0.08 (s), 0.41 max (s), 1.6-2.3 and 3.39 (s). [McCreary et al. J Am Chem Soc 96 1038 1974, Goering et al. J Am Chem Soc 93 5913 1971.]

TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Tris(2,2,2-trifluoroethyl) phosphite 370-69-4
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50 tons
Release date: 2020-01-17

Career Henan Chemical Co

Product: TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE 370-69-4
Price: US $7.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100KG
Release date: 2018-12-17

370-69-4, TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITERelated Search:

Phosphite TRIS(2,2,2-TRIFLUOROETHYL)PHOSPHATE TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Trimethyl phosphite TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE Triethyl phosphite

Phosphite, tris(2,2,2-trifluoroethyl)

TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE

TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE, 99 %

Tris(2,2,2-trifluoroethyl) phosphite 99%

TTFP

Ethanol, 2,2,2-trifluoro-, phosphite (3:1)

TTEP

370-69-4

C6H6F9O3P

CF3CH2O3P

Building Blocks

Phosphorus Compounds

Organic Phosphates/Phosphites

Organic Building Blocks

Organic Phosphates/Phosphites

Phosphorus Compounds