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2-Bromomalonaldehyde

Product Name
2-Bromomalonaldehyde
CAS No.
2065-75-0
Chemical Name
2-Bromomalonaldehyde
Synonyms
BROMOMALONALDEHYDE;Bromomalonaldehyde 97%;onaL;BromomaL;2-Bromomaloldehyde;2-BROMOMALONALDEHYDE;Propanedial, 2-broMo-;2-bromomalondialdehyde;2-broMo-1,3-propanedial;2-Bromomalonaldehyde ,99%
CBNumber
CB7453102
Molecular Formula
C3H3BrO2
Formula Weight
150.96
MOL File
2065-75-0.mol
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2-Bromomalonaldehyde Property

Melting point:
132-136 °C(lit.)
Boiling point:
134.8±25.0 °C(Predicted)
Density 
1.750±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Acetonitrile (Slightly), DMSO (Slightly)
form 
Solid
pka
1.70±0.10(Predicted)
color 
Pale Beige to Pale Yellow
Sensitive 
Air Sensitive
InChI
InChI=1S/C3H3BrO2/c4-3(1-5)2-6/h1-3H
InChIKey
SURMYNZXHKLDFO-UHFFFAOYSA-N
SMILES
C(=O)C(Br)C=O
CAS DataBase Reference
2065-75-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant/Keep Cold
HS Code 
29130000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
535079
Product name
Bromomalonaldehyde
Purity
97%
Packaging
5g
Price
$124
Updated
2025/07/31
Sigma-Aldrich
Product number
535079
Product name
Bromomalonaldehyde
Purity
97%
Packaging
25g
Price
$268
Updated
2025/07/31
TCI Chemical
Product number
B3699
Product name
Bromomalonaldehyde
Purity
min. 95.0 %
Packaging
25G
Price
$54
Updated
2025/07/31
TRC
Product number
B684490
Product name
Bromomalonaldehyde
Packaging
50g
Price
$120
Updated
2021/12/16
AK Scientific
Product number
J94394
Product name
2-Bromomalonaldehyde,tech.
Packaging
5g
Price
$10
Updated
2021/12/16
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2-Bromomalonaldehyde Chemical Properties,Usage,Production

Chemical Properties

Light Yellow Solid

Uses

Used in the formation of glyoxal-derived adducts from substituted guanines

Synthesis

102-52-3

2065-75-0

1,1,3,3-tetramethoxypropane (23) (10 g) was used as a raw material, and a solution of water (H2O, 11 mL) with concentrated HCl (0.43 mL) was stirred at room temperature for 10 minutes. Subsequently, Br2 (3.1 mL) was slowly added dropwise to the above solution at room temperature for a controlled time of 50 minutes or more. After the dropwise addition was completed, the reaction mixture was continued to be stirred at room temperature for 20 minutes. After completion of the reaction, the mixture was concentrated under vacuum. The resulting residual solid was washed with water (H2O) to give the final target product 2-bromomalonaldehyde (24) (3.6 g, 39%) as a yellow solid. The melting point of the product was 147-148 °C; 1H NMR (CDCl3) δ 4.73-4.80 (1H,m),8.47 (2H,br s); FAB MS m/e (M-H)-149.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2004, vol. 14, # 1, p. 235 - 238
[2] Patent: US2005/85492, 2005, A1. Location in patent: Page/Page column 25
[3] Bioorganic and Medicinal Chemistry, 2013, vol. 21, # 5, p. 1219 - 1233
[4] Organic and Biomolecular Chemistry, 2005, vol. 3, # 18, p. 3388 - 3398
[5] Patent: WO2004/67521, 2004, A1. Location in patent: Page 68

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2-Bromomalonaldehyde Suppliers

Suzhou Guide Fine Material Co.Ltd.
Tel
0512-66627360 13914021065
Fax
0512-66627360
Email
706938434@qq.com
Country
China
ProdList
237
Advantage
60
Hangzhou Junjieriheng New Materials Co., Ltd
Tel
19816896903 19816896903
Email
3842157198@qq.com
Country
China
ProdList
17
Advantage
58
Hubei long Kang Sheng Fine Chemical Co., Ltd.
Tel
027-027-83850368 18140587623
Email
3052398675@qq.com
Country
China
ProdList
993
Advantage
58
Cangzhou Enke Pharma Tech Co.,ltd.
Tel
0317-5106596 15533709196
Email
1154424302@qq.com
Country
China
ProdList
2262
Advantage
58
nantong honglong
Tel
13078814179
Email
2771867773@qq.com
Country
China
ProdList
526
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15838
Advantage
69
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
New Energy Chemicals
Tel
0515-82159099 13770142076
Fax
86-0515-8215909
Email
info@njuchem.com
Country
China
ProdList
242
Advantage
65
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View Lastest Price from 2-Bromomalonaldehyde manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2-Bromomalonaldehyde 2065-75-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-11-14
Zibo Hangyu Biotechnology Development Co., Ltd
Product
2-Bromomalonaldehyde 2065-75-0
Price
US $70.00-700.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-11-08
R&D Scientific Inc.
Product
2-bromomalonaldehyde 2065-75-0
Price
US $350.00/Kg
Min. Order
1Kg
Purity
96
Supply Ability
500 Kg
Release date
2024-07-26

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