ChemicalBook > CAS DataBase List > (S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE

(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE

Product Name
(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE
CAS No.
64030-44-0
Chemical Name
(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE
Synonyms
(2S)-(Anilinomethyl)pyrrolidine;(2S)-2-(Anilinomethyl)pyrrolidine;(S)-N-(Pyrrolidin-2-ylMethyl)aniline;(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE;(S)-2-(Phenylaminomethyl)pyrrolidine;(2S)-2-(Phenylaminomethyl)pyrrolidine;(S)-(+)-N-(2-PYRROLIDINOMETHYL)ANILINE;(2S)-N-Phenylpyrrolidine-2-methanamine;N-[[(2S)-2-Pyrrolidinyl]methyl]aniline;(2S)-PHENYL-PYRROLIDIN-2-YLMETHYL-AMINE
CBNumber
CB7461398
Molecular Formula
C11H16N2
Formula Weight
176.26
MOL File
64030-44-0.mol
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(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE Property

Melting point:
19°C
Boiling point:
111-112 °C/0.55 mmHg (lit.)
Density 
1.046 g/mL at 25 °C (lit.)
refractive index 
1.5750
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
sol ether, THF.
pka
10.52±0.10(Predicted)
form 
clear liquid
color 
Colorless to Yellow to Green
optical activity
[α]20/D +19°, c = 1 in ethanol
Sensitive 
Air Sensitive
BRN 
472065
CAS DataBase Reference
64030-44-0(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3267 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
A0945
Product name
(S)-(+)-2-(Anilinomethyl)pyrrolidine
Purity
>98.0%(T)
Packaging
1g
Price
$152
Updated
2024/03/01
TCI Chemical
Product number
A0945
Product name
(S)-(+)-2-(Anilinomethyl)pyrrolidine
Purity
>98.0%(T)
Packaging
5g
Price
$483
Updated
2024/03/01
TRC
Product number
A663753
Product name
(S)-(+)-2-(Anilinomethyl)pyrrolidine
Packaging
10mg
Price
$45
Updated
2021/12/16
TRC
Product number
A663753
Product name
(S)-(+)-2-(Anilinomethyl)pyrrolidine
Packaging
100mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA59887
Product name
(S)-(+)-2-(Anilinomethyl)pyrrolidine
Packaging
1g
Price
$89
Updated
2021/12/16
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(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless viscous liquid

Synthesis

(S)-2-(Anilinomethyl)pyrrolidine is prepared by the reaction of (S)-N-(benzyloxycarbonyl)proline with ethyl  chloroformate and N-methylmorpholine, aniline, hydrogenolysis with Pd/C, and reduction with LiAlH4 affords the title compound in 59% overall yield.

(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE Suppliers

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64030-44-0, (S)-(+)-2-(ANILINOMETHYL)PYRROLIDINERelated Search:

(S)-(+)-2-(2,6-XYLIDINOMETHYL)PYRROLIDINE GLY-PRO P-NITROANILIDE P-TOLUENESULFONATE SALT (S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE PYR-PNA (R)-(-)-2-(ANILINOMETHYL)PYRROLIDINE Z-PRO-BETANA H-PRO-PNA HBR GLY-PRO-MCA TOSYLATE Z-GLY-PRO-AMC PYR-HIS-PRO-BETANA GLY-PRO 4-METHOXY-BETA-NAPHTHYLAMIDE HYDROCHLORIDE L-PROLINE BETA-NAPHTHYLAMIDE HYDROCHLORIDE GLY-PRO 4-METHOXY-BETA-NAPHTHYLAMIDE L-PRO-7-AMINO-4-METHYLCOUMARIN Z-GLY-PRO-PNA SUC-GLY-PRO-AMC L-PYROGLUTAMIC ACID BETA-NAPHTHYLAMIDE Z-GLY-PRO-BETANA

  • 2-PyrrolidineMethanaMine,N-phenyl-, (2S)-
  • (S)-N-(Pyrrolidin-2-ylMethyl)aniline
  • (2S)-(Anilinomethyl)pyrrolidine
  • (S)-2-(Phenylaminomethyl)pyrrolidine
  • (S)-(+)-2-(Anilinomethyl)pyrrolidine 96%
  • (S)-2-(Anilinomethyl)pyrrolidine,99%e.e.
  • (S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE
  • (S)-(+)-N-(2-PYRROLIDINOMETHYL)ANILINE
  • (2S)-PHENYL-PYRROLIDIN-2-YLMETHYL-AMINE
  • (S)-(+)-2-(ANILINOMETHYL)PYRROLIDINE, 96 %
  • (2S)-2-(Anilinomethyl)pyrrolidine
  • (2S)-2-(Phenylaminomethyl)pyrrolidine
  • (2S)-N-Phenylpyrrolidine-2-methanamine
  • (2S)-N-Phenyl-pyrrolidine-2α-methanamine
  • (2S)-N-Phenylpyrrolidine-2α-methanamine
  • N-[[(2S)-2-Pyrrolidinyl]methyl]aniline
  • (S)-(+)-2-(Anilinomethyl)pyrrolidine &gt
  • 64030-44-0
  • Asymmetric Synthesis
  • Proline-Based Organocatalysts
  • Chiral Catalysts, Ligands, and Reagents
  • chiral
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Proline-Based Organocatalysts