Description
ChemicalBook > CAS DataBase List > Styrene Butadiene Rubber

Styrene Butadiene Rubber

Description
Product Name
Styrene Butadiene Rubber
CAS No.
9003-55-8
Chemical Name
Styrene Butadiene Rubber
Synonyms
sbs;SBR;STYRENE-BUTADIENE RUBBER;STYRENE/BUTADIENE COPOLYMER;dienols;ricon100;styrene-butadienepolymer;styrene-1,3-butadienecopolymer;Polymerized Styrene Butadiene Rubber;Styrene-butadiene rubber,oil-extended
CBNumber
CB7476376
Molecular Formula
(C8H8.C4H6)x
Formula Weight
158.24
MOL File
9003-55-8.mol
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Styrene Butadiene Rubber Property

Melting point:
253 °C
Density 
1.04 g/mL at 25 °C
refractive index 
1.57
solubility 
solvents with solubility parameters between 7.7 and 9.4: soluble
form 
slab/chunk
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
LogP
2.700 (est)
IARC
3 (Vol. 19, Sup 7) 1987
EPA Substance Registry System
Styrene 1,3-butadiene polymer (9003-55-8)
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Safety

WGK Germany 
3
RTECS 
WL6478000
TSCA 
TSCA listed
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
430072
Product name
Poly(styrene-co-butadiene)
Purity
butadiene 4 wt. %, melt index 6 g/10 min (200°C/5kg)
Packaging
1kg
Price
$77.7
Updated
2024/03/01
Sigma-Aldrich
Product number
182877
Product name
Polystyrene-block-polybutadiene-block-polystyrene
Purity
styrene 30 wt. %, average Mw ~140,000 by GPC, contains <0.5 wt. % antioxidant
Packaging
250g
Price
$104
Updated
2024/03/01
scipoly
Product number
057
Product name
Styrene/butadiene, ABA block copolymer
Packaging
250g
Price
$30
Updated
2024/07/03
scipoly
Product number
057
Product name
Styrene/butadiene, ABA block copolymer
Packaging
500g
Price
$48
Updated
2024/07/03
Sigma-Aldrich
Product number
432490
Product name
Polystyrene-block-polybutadiene-block-polystyrene
Purity
styrene 30 wt. %
Packaging
250g
Price
$64
Updated
2024/03/01
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Styrene Butadiene Rubber Chemical Properties,Usage,Production

Description

By far the most widely used type of synthetic rubber, its consumption for all applications is four times that of polybutadiene, its nearest competitor, and 1.5 times that of all other elastomers combined. Its manufacture involves copolymerization of three parts butadiene with one part styrene. These materials are suspended in finely divided emulsion form in a large proportion of water, in the presence of a soap or detergent. Also present in small amounts are an initiator or catalyst which is usually a peroxide, and a chain-modifying agent such as dodecyl mercaptan.

Chemical Properties

solid or viscous liquid, depending upon the degree of polymerisation

Uses

Molded or extruded into toys, packaging, appliances, communication cassettes, dinnerware and serviceware.

Uses

Component of hot melt adhesives, sealants, asphalt and oil gels. Modifier for polymers, thermosets and general rubber compounding. Direct molded or extruded auto parts, sporting goods, footware and film.

Definition

ChEBI: Styrene-butadiene copolymer is a polymer.

Production Methods

SBR is prepared mainly by emulsion and solution polymerization in a free-radical process with a mercaptan, such as dodecylmercaptan, which is used as a chain-transfer agent to control molecular weight. In the emulsion process, a soapstabilized water emulsion of styrene and butadiene is polymerized in continuous reactors to form SBR elastomer. “Cold” SBR is produced at a temperature of 5–10°C, and “hot” SBR at about 50°C . Solution SBR is typically made in hydrocarbon solution with an n-butyllithium initiator. The major differences between emulsion and solution styrene–butadiene are in the linearity and molecular-weight distribution of the polymer chains. In nonpolar solvents, the tendency is to produce block copolymer, but random copolymers are formed in polar solvents. SBR can be vulcanized similar to natural rubber but generally requires less sulfur and is more accelerated because of its lowunsaturation.

Hazard

Questionable carcinogen.

Health Hazard

Styrene Butadiene Rubber is prepared in large quantities for tire treads and other, similar uses. The properties, molecular weight, and percentage of monomer can all be controlled in the polymerization process. Hazards of the SBR industry have been identified and related mostly to the monomers and additives. Contact dermatitis and leukemia have been associated with solvent and additive use but not with the actual polymer itself (Checkoway et al., 1984; Kilpikari, 1982). Epidemiological studies in the industry have not revealed a significant increase in disease or causes of death (Matanoski and Schwartz, 1987; Meinhardt et al., 1982). The hazards of the butadiene and styrene monomers were discussed previously.

Safety Profile

An eye irritant. Questionable carcinogen. When heated to decomposition it emits acrid smoke and irritating fumes. See also POLYMERS, INSOLUBLE.

Solubility in organics

Chloroform, dichloromethane, hexane, MEK, toluene

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Styrene Butadiene Rubber Suppliers

Guangdong Shengke Biochemical Technology Co., Ltd.
Tel
189-25112307 18925113981
Email
3809205144@qq.com
Country
China
ProdList
10000
Advantage
58
Shandong Yilai New Materials Technology Development Co., Ltd
Tel
13296445501 13296445501
Email
15339964588@163.com
Country
China
ProdList
99
Advantage
58
JINANHAIHAO
Tel
13001706530
Email
753164080@qq.com
Country
China
ProdList
11
Advantage
58
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
9387
Advantage
52
BOC Sciences
Tel
1-631-485-4226; 16314854226
Email
info@bocsci.com
Country
United States
ProdList
14055
Advantage
65
HangZhou YuHao Chemical Technology Co., Ltd.
Tel
0571-82693216
Fax
0571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
2028
Advantage
58
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Hubei Jusheng Technology Co.,Ltd
Tel
027-59599241 18871490274
Fax
027-59599241
Email
1400878000@qq.com
Country
China
ProdList
9958
Advantage
58
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View Lastest Price from Styrene Butadiene Rubber manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Styrene Butadiene Rubber 9003-55-8
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-30
airuikechemical co., ltd.
Product
pOlystyrene-b-pOlybutadiene-b-pOlystyrene 9003-55-8
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-08
Henan Fengda Chemical Co., Ltd
Product
Styrene Butadiene Rubber 9003-55-8
Price
US $50.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-22

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