tert-dodecylthiol
- Product Name
- tert-dodecylthiol
- CAS No.
- 25103-58-6
- Chemical Name
- tert-dodecylthiol
- Synonyms
- TDM;Dodecanethiol;TERT-DODECANETHIOL;TERT-DODECYL MERCAPTAN;T-DODECANETHIOL;2,3,3,4,4,5-Hexamethyl-2-hexanethiol;tert-Dodecanet;dodecanethioltertiaire;Tert-Dodecyl Mercaptane;tert-Dodecylmercaptan (mixture of isomers)
- CBNumber
- CB7423916
- Molecular Formula
- C12H26S
- Formula Weight
- 202.4
- MOL File
- 25103-58-6.mol
tert-dodecylthiol Property
- Melting point:
- -7.5°C
- Boiling point:
- 227-248 °C (lit.)
- Density
- 0.86 g/mL at 20 °C (lit.)
- vapor pressure
- 1.33 hPa (25.5 °C)
- refractive index
- 1.4486 (estimate)
- Flash point:
- 195 °F
- storage temp.
- Store below +30°C.
- solubility
- <0.1g/l
- form
- clear liquid
- color
- Colorless to Almost colorless
- Water Solubility
- <0.1 g/100 mL at 23 ºC
- BRN
- 1738382
- InChI
- 1S/C12H26S/c1-9(2)10(3,4)11(5,6)12(7,8)13/h9,13H,1-8H3
- InChIKey
- CXUHLUIXDGOURI-UHFFFAOYSA-N
- SMILES
- SC(C(C(C(C)C)(C)C)(C)C)(C)C
- LogP
- 7.43 at 20℃
- CAS DataBase Reference
- 25103-58-6(CAS DataBase Reference)
- EPA Substance Registry System
- tert-Dodecanethiol (25103-58-6)
Safety
- Hazard Codes
- Xi,N
- Risk Statements
- 36/38-50/53
- Safety Statements
- 26-36-60
- RIDADR
- UN 3082 9/PG 3
- WGK Germany
- 2
- RTECS
- JR3150000
- Autoignition Temperature
- 350 °C
- TSCA
- TSCA listed
- HazardClass
- 9
- PackingGroup
- III
- HS Code
- 29309070
- Storage Class
- 10 - Combustible liquids
- Hazard Classifications
- Aquatic Chronic 1
Skin Irrit. 2
Skin Sens. 1B - Toxicity
- LD50 orally in Rabbit: 6800 mg/kg LD50 dermal Rabbit 12600 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 471585
- Product name
- tert-Dodecylmercaptan
- Purity
- mixture of isomers, 98.5%
- Packaging
- 2l
- Price
- $241
- Updated
- 2025/07/31
- Product number
- 471585
- Product name
- tert-Dodecylmercaptan
- Purity
- mixture of isomers, 98.5%
- Packaging
- 18l
- Price
- $696
- Updated
- 2025/07/31
- Product number
- D0971
- Product name
- tert-Dodecyl Mercaptan (mixture of isomers)
- Purity
- >98.0%(T)
- Packaging
- 25mL
- Price
- $29
- Updated
- 2025/07/31
- Product number
- D0971
- Product name
- tert-Dodecyl Mercaptan (mixture of isomers)
- Purity
- >98.0%(T)
- Packaging
- 500mL
- Price
- $66
- Updated
- 2025/07/31
- Product number
- 471585
- Product name
- tert-Dodecylmercaptan
- Purity
- mixture of isomers, 98.5%
- Packaging
- 100ml
- Price
- $56.6
- Updated
- 2025/07/31
tert-dodecylthiol Chemical Properties,Usage,Production
Uses
Tert-dodecylthiol is used in the polymer industry and as a processing regulator, processing aid (i.e. pH value regulator, flocculant and precipitant), lubricant, for the manufacture of plastic materials, resins, paints, coatings, rubber products, and mining, among other things.
General Description
Clear white to pale yellow liquid with a repulsive odor.
Air & Water Reactions
Sensitive to moisture. Sensitive to prolonged exposure to air. Insoluble in water.
Reactivity Profile
tert-dodecylthiol is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Generate heat and in many cases hydrogen gas and possibly hydrogen sulfide with these materials. May liberate hydrogen sulfide upon decomposition or reaction with an acid. Incompatible with oxygen. Incompatible with strong oxidizing agents . May be sensitive to heat.
Fire Hazard
tert-dodecylthiol is combustible.
Safety Profile
Poison by ingestion. Moderately toxic by intraperitoneal route. A skin and eye irritant. Combustible when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use foam, Con, dry chemical. When heated to decomposition it emitstoxic fumes of SOx,. See also MERCAPTANS and SULFATE
Synthesis
Twelve grams of water and 40 grams of dodecene were introduced into the plant through a funnel. After sealing the plant, the reaction mixing pump was put into operation (speed: 2800 min-1) and then the entire pumping circulation system (including the pump pressure head), which was manufactured in a jacketed design, was restored to its initial temperature. The reaction was initiated by gradually injecting the first 10 bar of carbon dioxide, followed by a gradual injection of 20 bar of hydrogen sulfide gas to a total pressure of about 30 ??C. 31 bar. The H2S feed to the reactor system was kept open during the experiment so that the amount of hydrogen sulfide that had been reacted could be replenished to the reaction system. Over the next 2 hours, the mixture was uniformly heated to 60??C. After an additional 3 hours, all dissolved gaseous components were removed from the biphasic liquid sample by depressurizing at the discharge valve and further heating to 100??C. The composition of the organic liquid phase (upper phase) was analyzed by gas chromatography and it was possible to differentiate between the reactants (olefins), the main product (tertiary dodecyl mercaptan) and the minor components (thioethers).
tert-dodecylthiol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from tert-dodecylthiol manufacturers
- Product
- tert-dodecylthiol 25103-58-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1000kg
- Release date
- 2025-06-21
- Product
- tert-dodecylthiol 25103-58-6
- Price
- US $0.00/KG
- Min. Order
- 175KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-30
- Product
- tert-dodecylthiol 25103-58-6
- Price
- US $25.00/KG
- Min. Order
- 100KG
- Purity
- 99.5%
- Supply Ability
- 100 mt
- Release date
- 2024-11-18