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METHYL MERCAPTAN

Product Name
METHYL MERCAPTAN
CAS No.
74-93-1
Chemical Name
METHYL MERCAPTAN
Synonyms
METHANETHIOL;CH3SH;Methanthiol;Methyl Mercaptane;C00409;4Q 1998;FEMA 2716;Methvtiolo;MERCAPTAN C1;Methaanthiol
CBNumber
CB7106671
Molecular Formula
CH4S
Formula Weight
48.11
MOL File
74-93-1.mol
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METHYL MERCAPTAN Property

Melting point:
−123 °C(lit.)
Boiling point:
6 °C(lit.)
Density 
0.8665
vapor density 
1.66 (vs air)
vapor pressure 
1536 mm Hg ( 20 °C)
refractive index 
1.4020 (estimate)
FEMA 
2716 | METHYL MERCAPTAN
Flash point:
<71℃
solubility 
Soluble in alcohol, ether (Weast, 1986), and petroleum naphtha (Hawley, 1981)
pka
10.3(at 25℃)
form 
liquid
Odor
at 0.01 % in propylene glycol. decomposing cabbage garlic
Odor Type
sulfurous
Odor Threshold
0.00007ppm
explosive limit
21.8%
Water Solubility 
23.30 g/L at 20 °C (quoted, Windholz et al., 1983)
0.330 mol/L at 25 °C (Hine and Weimar, 1965)
JECFA Number
508
Merck 
13,5983
BRN 
1696840
Henry's Law Constant
3.03 (Hine and Weimar, 1965)
Exposure limits
TLV-TWA 0.5 ppm (~1.0 mg/m3 ) (ACGIH and MSHA); ceiling 10 ppm (OSHA); IDLH 400 ppm (NIOSH); the revised IDLH is 150 ppm in analogy to H2S.
Stability:
Stable. Highly flammable - note low flash point. Reacts vigorously or explosively with a wide variety of materials - consult a full MSDS data sheet before using. Incompatible with strong oxidizing agents, alkali and alkaline earth metals, epoxides, hydrazines, ketones, lead, mercury (II) oxide, azo- and diazo- compounds, copp
LogP
0.72
CAS DataBase Reference
74-93-1(CAS DataBase Reference)
EPA Substance Registry System
Methyl mercaptan (74-93-1)
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Safety

Hazard Codes 
F+,T,N
Risk Statements 
12-23-50/53
Safety Statements 
16-25-60-61
RIDADR 
UN 2037 2.3
OEL
Ceiling: 0.5 ppm (1 mg/m3) [15-minute]
WGK Germany 
3
RTECS 
PB4375000
13-27
HazardClass 
2.3
Hazardous Substances Data
74-93-1(Hazardous Substances Data)
Toxicity
LC50 (inhalation) for mice 6,530 μg/m3/2-h, rats 675 ppm (quoted, RTECS, 1985).
IDLA
150 ppm
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H220Extremely flammable gas

H280Contains gas under pressure; may explode if heated

H331Toxic if inhaled

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P410+P403Protect from sunlight. Store in a well-ventilated place.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
CHM1054472
Product name
METHYL MERCAPTAN
Purity
95.00%
Packaging
5MG
Price
$454.03
Updated
2021/12/16
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METHYL MERCAPTAN Chemical Properties,Usage,Production

Description

Methanethiol (also known as methyl mercaptan) is a colorless gas with a smell like rotten cabbage. It is a natural substance found in the blood and brain of humans and other animals as well as plant tissues. It is disposed of through animal feces. It occurs naturally in certain foods, such as some nuts and cheese. It is also one of the main chemicals responsible for bad breath and the smell of flatus. The chemical formula for methanethiol is CH3SH; it is classified as a thiol. It is sometimes abbreviated as MeSH. It is very flammable.

Chemical Properties

colourless gas with a garlic-like or rotten cabbage-like smell

Chemical Properties

Methyl mercaptan is a colorless gas or white liquid with a disagreeable odor like garlic or rotten cabbage. Shipped as a liquefied compressed gas. The odor threshold is 0.002 ppm.

Chemical Properties

Methyl mercaptan has an objectionable odor of decomposing cabbage or garlic

Chemical Properties

Methyl mercaptan has an objectionable odor of decomposing cabbage. May be prepared by heating an aqueous solution of potassium methyl sulfate and KHS; from sodium methyl sulfate and potassium sulfhydrate; also from methanol and hydrogen sulfide in the presence of a catalyst.

Physical properties

Colorless gas with a garlic-like or rotten cabbage odor. An experimentally determined odor threshold concentration of 2.1 ppbv was reported by Leonardos et al. (1969). A detection odor threshold concentration of 81 μg/m3 (41 ppbv) was determined by Katz and Talbert (1930).

Occurrence

Methanethiol is released from decaying organic matter in marshes and is present in the natural gas of certain regions, in coal tar, and in some crude oils.
In surface seawater, methanethiol is the primary breakdown product of the algal metabolite dimethylsulfoniopropionate (DMSP). Marine bacteria appear to obtain most of their protein sulfur by the breakdown of DMSP and incorporation of methanethiol, despite the fact that methanethiol is present in seawater at much lower concentrations than sulfate (~0.3 nM vs. 28 mM). Bacteria in oxic and anoxic environments can also convert methanethiol to dimethyl sulfide (DMS), although most DMS in surface seawater is produced by a separate pathway. Both DMS and methanethiol can be used by certain microbes as substrates for methanogenesis in some anaerobic soils.
Methanethiol is a weak acid, with a pKa of ~10.4. This acidic property makes it reactive with dissolved metals in aqueous solutions. The environmental chemistry of these interactions in seawater or fresh water environments such as lakes has yet to be fully investigated.
A material safety data sheet (MSDS) lists methanethiol as a colorless, flammable gas with an extremely strong and repulsive smell. At very high concentrations it is highly toxic and affects the central nervous system. Its penetrating odor provides warning at dangerous concentrations. An odor threshold of 1 ppb has been reported. The United States OSHA Ceiling Limit is listed as 10 ppm.

Uses

Methanethiol is mainly used to produce methionine, which is used as a dietary component in poultry and animal feed. Methanethiol is also used in the plastics industry and as a precursor in the manufacture of pesticides. It is released as a by-product of wood pulping in pulp mills.
Methanethiol is also used for communication in mining operations . Releasing the substance into the ventilation system is generally the most efficient and reliable means to alert all workers of an emergency , and is referred to as "releasing the pest" ,This substance's strong odor alerts the miners to immediately go to a saferoom.
Since natural gas and propane are colorless and odorless, a small amount of methyl mercaptan or ethyl mercaptan is added to make it easy to detect a gas leak.

Uses

Methanethiol is used in the manufacture ofpesticides and fungicides and as an intermediate in the manufacture of jet fuels (Watkinset al. 1989); it is added to natural gas to giveodor. It is used in the synthesis of methionine.

Uses

Methanethiol is an Intermediate in manufacturing of jet fuels, pesticides, fungicides, plastics; synthesis of methionine; emission from paper pulp mills, odoriferous additive to natural gas.

Definition

ChEBI: Methanethiol is an alkanethiol. It has a role as a human metabolite and a Saccharomyces cerevisiae metabolite.

Preparation

Methanethiol is prepared commercially by the reaction of methanol with hydrogen sulfide gas over an acidic solid catalyst, such as alumina. It can be prepared by the reaction of methyl iodide with thiourea.

Aroma threshold values

Detection: 0.02 to 4 ppb. Aroma characteristics at 1.0%: vegetable oil, alliaceous, eggy, creamy with savory nuances

Taste threshold values

Taste characteristics at 1 ppm: sulfurous, alliaceous, creamy with a surface-ripened cheese top note and a clean, savory, meaty depth

Air & Water Reactions

Highly flammable. Reacts with water, steam or acids to produce toxic, flammable vapors [Lewis].

Reactivity Profile

METHYL MERCAPTAN is a reducing agent--can react vigorously with oxidizing agents. Dangerous fire or explosion hazard when exposed to heat, flame, sparks or strong oxidizing agents (e.g., calcium hypochlorite). When heating to decomposition emits highly toxic fumes of oxides of sulfur [Lewis, 3rd ed., 1993, p. 862]. Violent reaction with mercury(II) oxide [Klason P., Ber., 1887, 20, p. 3410].

Hazard

Flammable, dangerous fire risk. Explosive limits in air 3.9–21.8%. Strong irritant. Liver damage.

Health Hazard

Can cause death by respiratory paralysis. It is an eye and respiratory tract irritant. Exposure results in pulmonary edema and hepatic and renal damage.

Health Hazard

The acute toxicity of methanethiol is simi-lar to that of hydrogen sulfide. Inhalation ofthis gas can cause narcosis, headache, nau-sea, pulmonary irritation, and convulsions inhumans. Other symptoms noted are acutehemolytic anemia, methemoglobinemia, andcyanosis. In humans, several hours exposure to about 5 ppm concentration of thisgas can cause headache and nausea. Exposure to high concentrations can result inrespiratory paralysis and death. The 2-hour inhalation LC50 value in mice is within therange 650 mg/m3.
Shults et al. (1970) reported a case of ahuman death from overexposure to methane-thiol. The victim developed acute hemolyticanemia and methemoglobinemia and re-mainedindeepcomauntil deaththatoccurred28 days after the accident from emptying gascylinders.

Fire Hazard

Combustion produces irritating sulfur dioxide. Flash back along vapor track may occur. Very dangerous when exposed to heat, flame, or oxidizers. On decomposition METHYL MERCAPTAN emits highly toxic fumes of sulfur oxides. METHYL MERCAPTAN will react with water, steam or acids to produce toxic and flammable vapors; and can react vigorously with oxidizing materials. Irritating sulfur dioxide is produced upon combustion. When heated to decomposition, METHYL MERCAPTAN emits highly toxic fumes and flammable vapors. Incompatible with mercuric oxide and oxidizing materials. Avoid direct sunlight, and areas of high fire hazards. Hazardous polymerization may not occur.

Safety Profile

Poison by inhalation. Mutation data reported. A common air contaminant. Very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidzing materials. Explosive in the form of vapor when exposed to heat or flame. Reacts with water, steam, or acids to produce toxic and flammable vapors. Violent reaction with mercury(II) oxide. To fight fire, use alcohol foam, CO2, dry chemical. Upon decomposition it emits highly toxic fumes of SOx.

Synthesis

By heating an aqueous solution of potassium methyl sulfate and KHS; from sodium methyl sulfate and potassium sulfhydrate; also from methanol and hydrogen sulfide in the presence of a catalyst

Potential Exposure

Methyl mercaptan is used in methionine synthesis, and widely as an intermediate in pesticide manufacture. A foul-smelling odorant usually added to chemicals, including pesticides.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at leastIf this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least

Source

Occurs naturally in kohlrabi stems (Brassica oleracea var. gongylodes) and potato plants (Duke, 1992)

Environmental Fate

Biological. After 20 d, methyl mercaptan started to degrade in anaerobic sediments and sludges producing stoichiometric amounts of methane. Complete degradation was achieved after 20 d. Under anaerobic freshwater conditions, methyl mercaptan were degraded by methanogenic archea (van Leerdam et al., 2006).
Photolytic. Sunlight irradiation of a methyl mercaptan-nitrogen oxide mixture in an outdoor chamber yielded formaldehyde, sulfur dioxide, nitric acid, methyl nitrate, methanesulfonic acid, and an inorganic sulfate (Grosjean, 1984a).
Chemical/Physical. In the presence of nitric oxide, gaseous methyl mercaptan reacted with OH radicals forming methyl sulfenic acid and methyl thionitrite. The rate constant for this reaction is 2.1 x 10-11 cm3/molecule?sec at 20 °C (MacLeod et al., 1984). Forms a crystalline hydrate with water (Patnaik, 1992).

storage

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with this chemical you should be trainedon its proper handling and storage. Before entering confinedspace where this chemical may be present, check to makesure that an explosive concentration does not exist. Methylmercaptan must be stored to avoid contact with water,steam, or strong acids (such as hydrochloric, sulfuric, andnitric) because toxic flammable vapors will be released. Itshould not contact oxidizers (such as perchlorates, peroxides, permanganates, chlorates, and nitrates) since violentreactions occur. Store in tightly closed containers in a cool,well-ventilated area away from heat or sparks. Sources ofignition, such as smoking and open flames, are prohibitedwhere methyl mercaptan is handled, used, or stored. Metalcontainers involving the transfer of 5 gallons or more ofmethyl mercaptan should be grounded and bonded. Drumsmust be equipped with self-closing valves, pressure vacuumbungs, and flame arresters. Use only nonsparking tools andequipment, especially when opening and closing containersof methyl mercaptan. Procedures for the handling, use, andstorage of cylinders should be in compliance with OSHA1910.101 and 1910.169, as with the recommendations ofthe Compressed Gas Association.

Shipping

UN1064 Methyl mercaptan, Hazard Class: 2.3; Labels: 2.3-Poisonous gas, 2.1-Flammable gas, Inhalation Hazard Zone C. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

Asparagus

Methanethiol is a byproduct produced by the metabolism of asparagus. The ability to produce methanethiol in urine after eating asparagus was once thought to be a genetic trait. However recent research suggests that the peculiar odor is in fact produced by all humans after consuming asparagus, while the ability to detect it (methanethiol being one of many components in "asparagus pee") is in fact the genetic trait. The chemical components responsible for the change in the odor of urine show as soon as 15 minutes after eating asparagus.

Incompatibilities

Violent reaction with strong oxidizers, bleaches, copper, nickel and their alloys; aluminum. Reacts with acids producing flammable and toxic hydrogen sulfide

Waste Disposal

Return refillable compressed gas cylinders to supplier. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration followed by effective scrubbing of the effluent gas.

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METHYL MERCAPTAN Suppliers

Central China Special Gas (CCSG) Co., Ltd
Tel
0734-8755555 15674722888
Fax
0734-8123618
Email
lyq@ccsg.cn
Country
China
ProdList
282
Advantage
58
Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1686
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
Country
China
ProdList
9658
Advantage
60
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View Lastest Price from METHYL MERCAPTAN manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
METHYL MERCAPTAN 74-93-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
METHYL MERCAPTAN 74-93-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08
Career Henan Chemical Co
Product
METHYL MERCAPTAN 74-93-1
Price
US $100.00/KG
Min. Order
25KG
Purity
98%
Supply Ability
1000KG
Release date
2018-07-30

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