2-Bromothioanisole
- Product Name
- 2-Bromothioanisole
- CAS No.
- 19614-16-5
- Chemical Name
- 2-Bromothioanisole
- Synonyms
- (2-bromophenyl)(methyl)sulfane;Benzene, 1-bromo-2-(methylthio)-;2-bromoanisulfide;O-BROMOTHIOANISOLE;2-BROMOTHIOANISOLE;TIMTEC-BB SBB006566;2-BROMOTHIOANISOLE 97%;2-Bromothioanisole,99%;2-Bromothioanisole >2-Bromothioanisole,>97%
- CBNumber
- CB3193194
- Molecular Formula
- C7H7BrS
- Formula Weight
- 203.1
- MOL File
- 19614-16-5.mol
2-Bromothioanisole Property
- Melting point:
- -24 °C (lit.)
- Boiling point:
- 145-146 °C/27 mmHg (lit.)
- Density
- 1.522 g/mL at 25 °C (lit.)
- refractive index
- 1.632-1.634
- Flash point:
- >110°C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Liquid
- Specific Gravity
- 1.522
- color
- Clear colorless to yellow
- BRN
- 2243716
- InChI
- InChI=1S/C7H7BrS/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
- InChIKey
- ALAQDUSTXPEHMH-UHFFFAOYSA-N
- SMILES
- C1(Br)=CC=CC=C1SC
- CAS DataBase Reference
- 19614-16-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 1-bromo-2-(methylthio)-(19614-16-5)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 36/37/38-22
- Safety Statements
- 37/39-26
- RIDADR
- UN 3334
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- IRRITANT, STENCH
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 260851
- Product name
- 2-Bromothioanisole
- Purity
- 97%
- Packaging
- 5g
- Price
- $28.2
- Updated
- 2025/07/31
- Product number
- B2023
- Product name
- 2-Bromothioanisole
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $47
- Updated
- 2025/07/31
- Product number
- B2023
- Product name
- 2-Bromothioanisole
- Purity
- >96.0%(GC)
- Packaging
- 25g
- Price
- $185
- Updated
- 2025/07/31
- Product number
- B697725
- Product name
- 1-Bromo-2-(methylsulfanyl)benzene
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- B697725
- Product name
- 1-Bromo-2-(methylsulfanyl)benzene
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
2-Bromothioanisole Chemical Properties,Usage,Production
Chemical Properties
clear yellow liquid
Uses
2-Bromothioanisole has been used in the preparation of:
- thioether-methyleneborane (PhSCH2B (C6F5)2)2
- 1-dimesitylboryl-2-methylthio-benzene
Synthesis
6320-02-1
74-88-4
19614-16-5
Under argon protection, sodium hydroxide (0.32 g, 7.9 mmol) was dissolved in ethanol (3.0 mL), and 2-bromothiophenol (1.0 g, 5.29 mmol) was added slowly and stirred for 30 min at room temperature. Subsequently, iodomethane (0.5 mL, 7.9 mmol) was added and the reaction continued to be stirred at room temperature for 3 hours. Upon completion of the reaction, the reaction was quenched by the addition of ice water (4.0 mL) and the reaction mixture was extracted with dichloromethane (10 mL x 3). The organic layers were combined, washed with saturated saline, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by fast column chromatography (eluent: petroleum ether) to afford the target compound 2-bromothioanisole.
References
[1] Macromolecules, 2002, vol. 35, # 1, p. 67 - 78
[2] Tetrahedron Asymmetry, 2011, vol. 22, # 5, p. 575 - 579
[3] Patent: WO2015/86525, 2015, A1. Location in patent: Page/Page column 127
[4] Tetrahedron Asymmetry, 1999, vol. 10, # 6, p. 1051 - 1060
[5] Organic Letters, 2005, vol. 7, # 1, p. 143 - 145
2-Bromothioanisole Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Bromothioanisole manufacturers
- Product
- 2-Bromothioanisole 19614-16-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-11-18
- Product
- 2-Bromothioanisole 19614-16-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-27
- Product
- 2-Bromothioanisole 19614-16-5
- Price
- US $8.00/KG
- Min. Order
- 1g
- Purity
- ＞98% HPLC
- Supply Ability
- kg---ton
- Release date
- 2020-02-20