ChemicalBook > CAS DataBase List > 2-Bromothioanisole

2-Bromothioanisole

Product Name
2-Bromothioanisole
CAS No.
19614-16-5
Chemical Name
2-Bromothioanisole
Synonyms
(2-bromophenyl)(methyl)sulfane;Benzene, 1-bromo-2-(methylthio)-;2-bromoanisulfide;O-BROMOTHIOANISOLE;2-BROMOTHIOANISOLE;TIMTEC-BB SBB006566;2-BROMOTHIOANISOLE 97%;2-Bromothioanisole,99%;2-Bromothioanisole >2-Bromothioanisole,>97%
CBNumber
CB3193194
Molecular Formula
C7H7BrS
Formula Weight
203.1
MOL File
19614-16-5.mol
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2-Bromothioanisole Property

Melting point:
-24 °C (lit.)
Boiling point:
145-146 °C/27 mmHg (lit.)
Density 
1.522 g/mL at 25 °C (lit.)
refractive index 
1.632-1.634
Flash point:
>110°C
storage temp. 
Inert atmosphere,Room Temperature
form 
Liquid
Specific Gravity
1.522
color 
Clear colorless to yellow
BRN 
2243716
InChI
InChI=1S/C7H7BrS/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
InChIKey
ALAQDUSTXPEHMH-UHFFFAOYSA-N
SMILES
C1(Br)=CC=CC=C1SC
CAS DataBase Reference
19614-16-5(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-2-(methylthio)-(19614-16-5)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-22
Safety Statements 
37/39-26
RIDADR 
UN 3334
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
IRRITANT, STENCH
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
260851
Product name
2-Bromothioanisole
Purity
97%
Packaging
5g
Price
$28.2
Updated
2025/07/31
TCI Chemical
Product number
B2023
Product name
2-Bromothioanisole
Purity
>96.0%(GC)
Packaging
5g
Price
$47
Updated
2025/07/31
TCI Chemical
Product number
B2023
Product name
2-Bromothioanisole
Purity
>96.0%(GC)
Packaging
25g
Price
$185
Updated
2025/07/31
TRC
Product number
B697725
Product name
1-Bromo-2-(methylsulfanyl)benzene
Packaging
500mg
Price
$65
Updated
2021/12/16
TRC
Product number
B697725
Product name
1-Bromo-2-(methylsulfanyl)benzene
Packaging
100mg
Price
$45
Updated
2021/12/16
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2-Bromothioanisole Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Uses

2-Bromothioanisole has been used in the preparation of:

  • thioether-methyleneborane (PhSCH2B (C6F5)2)2
  • 1-dimesitylboryl-2-methylthio-benzene

Synthesis

6320-02-1

74-88-4

19614-16-5

Under argon protection, sodium hydroxide (0.32 g, 7.9 mmol) was dissolved in ethanol (3.0 mL), and 2-bromothiophenol (1.0 g, 5.29 mmol) was added slowly and stirred for 30 min at room temperature. Subsequently, iodomethane (0.5 mL, 7.9 mmol) was added and the reaction continued to be stirred at room temperature for 3 hours. Upon completion of the reaction, the reaction was quenched by the addition of ice water (4.0 mL) and the reaction mixture was extracted with dichloromethane (10 mL x 3). The organic layers were combined, washed with saturated saline, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by fast column chromatography (eluent: petroleum ether) to afford the target compound 2-bromothioanisole.

References

[1] Macromolecules, 2002, vol. 35, # 1, p. 67 - 78
[2] Tetrahedron Asymmetry, 2011, vol. 22, # 5, p. 575 - 579
[3] Patent: WO2015/86525, 2015, A1. Location in patent: Page/Page column 127
[4] Tetrahedron Asymmetry, 1999, vol. 10, # 6, p. 1051 - 1060
[5] Organic Letters, 2005, vol. 7, # 1, p. 143 - 145

2-Bromothioanisole Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromothioanisole Suppliers

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View Lastest Price from 2-Bromothioanisole manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2-Bromothioanisole 19614-16-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-18
Henan Aochuang Chemical Co.,Ltd.
Product
2-Bromothioanisole 19614-16-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-27
Career Henan Chemical Co
Product
2-Bromothioanisole 19614-16-5
Price
US $8.00/KG
Min. Order
1g
Purity
＞98% HPLC
Supply Ability
kg---ton
Release date
2020-02-20

19614-16-5, 2-BromothioanisoleRelated Search:

Bensulfuron methyl Tetrabromobisphenol A bis(dibromopropyl ether) Thioacetamide Dimethyl sulfide Guaiacol Hydrogen Sulfide Kresoxim-methyl Decabromodiphenyl oxide Sodium sulfide Butylated hydroxyanisole Methylparaben Anisole 2-Bromoanisole 4-Methoxyphenol Thioanisole CARBONYL SULFIDE Thiophanate-methyl Anise oil

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  • 2-BROMOTHIOANISOLE / 2-BROMOPHENYL METHYL SULPHIDE
  • Benzene, 1-bromo-2-(methylthio)-
  • 2-(methylthio)bromobenzene
  • (2-bromophenyl)(methyl)sulfane
  • 2-Bromothioanisole, 98+%
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  • 2-Bromothioanisole,>97%
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  • 19614-16-5
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