Thioanisole

Uses Use Restriction

Product Name: Thioanisole
CAS No.: 100-68-5
Chemical Name: Thioanisole
Synonyms: MPS;Methyl(phenyl)sulfane;PHSME;METHYL PHENYL SULFIDE;THIOANISOL;Thioanisole (L);Benzene, (methylthio)-;Thioanisole Vetec(TM) reagent grade, 98%;FEMA 3873;THIOANISOLE
CBNumber: CB9233364
Molecular Formula: C7H8S
Formula Weight: 124.2
MOL File: 100-68-5.mol

More

Less

Thioanisole Property

Melting point:: −15 °C(lit.)
Boiling point:: 188 °C(lit.)
Density: 1.057 g/mL at 20 °C(lit.)
vapor pressure: 38.5 Pa (20 °C)
refractive index: n20/D 1.587(lit.)
FEMA: 3873 | METHYL PHENYL SULFIDE
Flash point:: 135 °F
storage temp.: Store below +30°C.
solubility: <1mg/l
form: Liquid
Specific Gravity: 1.058
color: Clear light yellow to brown-yellow
Odor: at 0.10 % in propylene glycol. toluene solvent spicy woody sawdust
Odor Type: solvent
Water Solubility: INSOLUBLE
Sensitive: Stench
JECFA Number: 459
BRN: 1904179
Dielectric constant: 4.7599999999999998
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
LogP: 2.9 at 25℃
CAS DataBase Reference: 100-68-5(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, (methylthio)-(100-68-5)
EPA Substance Registry System: Benzene, (methylthio)- (100-68-5)

More

Less

Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38
Safety Statements: 26-36/39-36/37
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
RTECS: DA6200000
F: 13
Hazard Note: Harmful/Stench
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29309070
Toxicity: LD50 orally in Rabbit: 891 mg/kg

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: T28002
Product name: Thioanisole
Purity: ReagentPlus , ≥99%
Packaging: 25g
Price: $39.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20825
Product name: Methyl phenyl sulfide
Purity: for synthesis
Packaging: 100mL
Price: $69.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20825
Product name: Methyl phenyl sulfide
Purity: for synthesis
Packaging: 500mL
Price: $249
Updated: 2024/03/01

TCI Chemical

Product number: T0191
Product name: Thioanisole
Purity: >99.0%(GC)
Packaging: 25mL
Price: $21
Updated: 2024/03/01

TCI Chemical

Product number: T0191
Product name: Thioanisole
Purity: >99.0%(GC)
Packaging: 100mL
Price: $42
Updated: 2024/03/01

More

Less

Thioanisole Chemical Properties,Usage,Production

Uses

Thioanisole is an important raw material of light curing initiator UV-907.
High efficiency startup agent, used for acid catalytic cracking of N-Z and protective groups of O-benzyl and O-methyl.
Thioanisole is used as pesticide, medicine, dye intermediate.

Use Restriction

FEMA(mg/kg)：Baked products 0.06 ~ 1; non-alcoholic beverages 0.2～2.0 ; grease0.01～0.04 ; gelatin, pudding, sauce, 0.1～1.0 ; meat products 0.4～4.0; seasoning spices0.5～1.0.

Chemical Properties

Colorless to yellow liquid

Chemical Properties

Methyl phenyl sulfide has an unpleasant odor.

Occurrence

Reported found in coffee.

Uses

Thioanisole is used in oxidative biotransformations.

Uses

Intermediate, solvent for polymeric systems.

Definition

ChEBI: Thioanisole is an aryl sulfide that is thiophenol in which the hydrogen of the thiol group has been replaced by a methyl group. It is an aryl sulfide and a member of benzenes. It is functionally related to a thiophenol.

Aroma threshold values

Aroma characteristics at 0.1% EtoH: toluene solvent, spicy, pungent, woody sawdust.

Taste threshold values

Taste characteristics at .02 to 0.5 ppm: solventy, woody, roasted coffee.

Synthesis Reference(s)

Journal of the American Chemical Society, 112, p. 186, 1990 DOI: 10.1021/ja00157a030
The Journal of Organic Chemistry, 33, p. 4290, 1968 DOI: 10.1021/jo01275a070

Flammability and Explosibility

Non flammable

Thioanisole Preparation Products And Raw materials

Raw materials

Preparation Products

Octreotide acetate 3-METHYLBENZO[B]THIOPHENE 2-Bromo-1-[4-(methylsulfonyl)phenyl]-1-ethanone 2-ACETYL-3-METHYLBENZO[B]THIOPHENE 6-Acetyl-4,4-dimethylthio-chroman 3-METHYLBENZO[B]THIOPHENE-2-CARBOXALDEHYDE 2-Methyl-4-(phenylthio)-2-butanol

More

Less

Thioanisole Suppliers

Belgium 3 China 285 Europe 3 France 1 Germany 5 India 20 Japan 12 Norway 1 Slovakia 1 South Korea 1 Switzerland 3 The Netherlands 1 Ukraine 2 United Kingdom 14 United States 45 Global 397

Shanghai Rolead Chemical Technology Co., Ltd.

Tel: 021-69992220 13701886816
Fax: 021-69992237
Email: roleadchem@163.com
Country: China
ProdList: 4759
Advantage: 50

ShangHai Siyan Biological Technology Co., Ltd.

Tel: 021-50908862，442785678，326799392 18721037013
Fax: 021-50908862
Email: siyansales@126.com
Country: China
ProdList: 9638
Advantage: 58

Shanghai Pin Research Chemical Co., Ltd.

Tel: 15900489257
Email: 271793832@qq.com
Country: China
ProdList: 36
Advantage: 58

Wuhan xinyangruihe Chemical Technology Co., Ltd.

Tel: 027-83850375 18120580375
Fax: 027-83850375
Email: 669797270@qq.com
Country: China
ProdList: 5130
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94838
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
Fax: (+86)-10-88425546
Email: sales@dhltchem.com
Country: China
ProdList: 793
Advantage: 59

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Beijing dtftchem Technology Co., Ltd.

Tel: 010-60275820 13031183356
Fax: 010-60270825
Email: elainezt@sina.com
Country: China
ProdList: 1392
Advantage: 62

More

Less

View Lastest Price from Thioanisole manufacturers

Hebei Duling International Trade Co. LTD

Product: Thioanisole 100-68-5
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 300MT/month
Release date: 2022-11-23

Hebei Guanlang Biotechnology Co,.LTD

Product: Methyl phenyl sulfide 100-68-5
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2023-06-06

Hebei Guanlang Biotechnology Co., Ltd.

Product: 2-Chloropyrazine 100-68-5
Price: US $10.00/PCS
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2021-03-15

100-68-5, ThioanisoleRelated Search:

Anise oil Tri(o-tolyl)phosphine Borane-methyl sulfide complex Methyl salicylate Dimethyl sulfide Hydrogen Sulfide CARBONYL SULFIDE Butylated hydroxyanisole tert-Butyl methyl ether Chlorodimethylphenylsilane Triton X-100 Glycidyl phenyl ether Diphenyl sulfide Sodium sulfide POLY(1,4-PHENYLENE SULFIDE) Thiophanate-methyl Silicone oil (high temperature) Methyl

Thioanisole ReagentPlus(R), >=99%

Thioanisole Vetec(TM) reagent grade, 98%

(1-Thiaethyl)benzene

(Methylsulfanyl)benzene

(methylthio)-benzen

1-Phenyl-1-thiaethane

Anisole, thio-

Methyl phenyl sulphide

methylphdenylsulfide

Methyl phenyl sulfide MPS

Benzene, (methylthio)-

THIOMETHYLBENZENE

Thioanisole99%

THIOANISOLE / METHYL PHENYL SULPHIDE

MPS

Methyl phenyl sulfide, Thioanisole

Methylmercaptobenzene

Thioanisole,Methyl phenyl sulfide

Methyl phenyl sulfide,Methyl phenyl sulfide, Thioanisole

Thioanisole, 99% 25GR

Thioanisole, 99% 500GR

Thioanisole (L)

Methyl Phenyl Sulfide Methylthiobenzene

Methyl phenyl sulphide, (Methylsulphanyl)benzene, (Methylthio)benzene

Methyl(phenyl)sulfane

PHENYL METHYL SULFIDE

PHSME

Methylphenylsulfid

METHYLTHIOBENZENE

METHYL PHENYL SULFIDE

FEMA 3873

THIOANISOL

THIOANISOLE

THIOANISOLE, REAGENTPLUS, 99%

METHYL PHENYL SULFIDE 99+%

methylphenylthioether

Phenylthiomethane

Sulfide, methyl phenyl

sulfide,methylphenyl

Thioanisole &gt

Thioanisole, 99%, for synthesis

Thioanisole USP/EP/BP

Thioanisole 100-68-5

THIOANISOLE Extra pure

Methylparaben Impurity 10

100-68-5

100-86-5

C6H5SCH3

CH3SC6H5

Building Blocks

Sulfur Compounds

Sulfides/Disulfides

Organic Building Blocks

Drug Discovery

Other Reagents

sulfide Flavor

Intermediates

bc0001