Thioanisole
Uses Use Restriction- Product Name
- Thioanisole
- CAS No.
- 100-68-5
- Chemical Name
- Thioanisole
- Synonyms
- MPS;Methyl(phenyl)sulfane;PHSME;METHYL PHENYL SULFIDE;THIOANISOL;Thioanisole (L);Benzene, (methylthio)-;Thioanisole Vetec(TM) reagent grade, 98%;FEMA 3873;THIOANISOLE
- CBNumber
- CB9233364
- Molecular Formula
- C7H8S
- Formula Weight
- 124.2
- MOL File
- 100-68-5.mol
Thioanisole Property
- Melting point:
- −15 °C(lit.)
- Boiling point:
- 188 °C(lit.)
- Density
- 1.057 g/mL at 20 °C(lit.)
- vapor pressure
- 38.5 Pa (20 °C)
- refractive index
- n20/D 1.587(lit.)
- FEMA
- 3873 | METHYL PHENYL SULFIDE
- Flash point:
- 135 °F
- storage temp.
- Store below +30°C.
- solubility
- <1mg/l
- form
- Liquid
- Specific Gravity
- 1.058
- color
- Clear light yellow to brown-yellow
- Odor
- at 0.10 % in propylene glycol. toluene solvent spicy woody sawdust
- Odor Type
- solvent
- Water Solubility
- INSOLUBLE
- Sensitive
- Stench
- JECFA Number
- 459
- BRN
- 1904179
- Dielectric constant
- 4.7599999999999998
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 2.9 at 25℃
- CAS DataBase Reference
- 100-68-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, (methylthio)-(100-68-5)
- EPA Substance Registry System
- Benzene, (methylthio)- (100-68-5)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36/39-36/37
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- RTECS
- DA6200000
- F
- 13
- Hazard Note
- Harmful/Stench
- TSCA
- Yes
- HazardClass
- 9
- PackingGroup
- III
- HS Code
- 29309070
- Toxicity
- LD50 orally in Rabbit: 891 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H317May cause an allergic skin reaction
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- T28002
- Product name
- Thioanisole
- Purity
- ReagentPlus , ≥99%
- Packaging
- 25g
- Price
- $39.7
- Updated
- 2024/03/01
- Product number
- 8.20825
- Product name
- Methyl phenyl sulfide
- Purity
- for synthesis
- Packaging
- 100mL
- Price
- $69.8
- Updated
- 2024/03/01
- Product number
- 8.20825
- Product name
- Methyl phenyl sulfide
- Purity
- for synthesis
- Packaging
- 500mL
- Price
- $249
- Updated
- 2024/03/01
- Product number
- T0191
- Product name
- Thioanisole
- Purity
- >99.0%(GC)
- Packaging
- 25mL
- Price
- $21
- Updated
- 2024/03/01
- Product number
- T0191
- Product name
- Thioanisole
- Purity
- >99.0%(GC)
- Packaging
- 100mL
- Price
- $42
- Updated
- 2024/03/01
Thioanisole Chemical Properties,Usage,Production
Uses
- Thioanisole is an important raw material of light curing initiator UV-907.
- High efficiency startup agent, used for acid catalytic cracking of N-Z and protective groups of O-benzyl and O-methyl.
- Thioanisole is used as pesticide, medicine, dye intermediate.
Use Restriction
FEMA(mg/kg)：Baked products 0.06 ~ 1; non-alcoholic beverages 0.2～2.0 ; grease0.01～0.04 ; gelatin, pudding, sauce, 0.1～1.0 ; meat products 0.4～4.0; seasoning spices0.5～1.0.
Description
Thioanisole is a chiral organosulfide with a wide range of uses in the chemical, pharmaceutical, flavour and fragrance and food industries. Its use in combination with biocatalysts in immobilised cells eliminates the 2-day preparation phase and results in complete bioconversion of thioanisole within 24 hours. Degradative halogenation of thioanisoles by iodine at temperatures between 100 and 150°C produces diphenyl sulfide, diphenyl disulfide, thianthrene and trimethylsulfonium iodide, as well as small amounts of hydrogen sulfide, hydrogen iodide, iodomethane and dimethyl sulfide.
Chemical Properties
Colorless to yellow liquid
Chemical Properties
Methyl phenyl sulfide has an unpleasant odor.
Occurrence
Reported found in coffee.
Uses
Thioanisole is used in oxidative biotransformations.
Uses
Intermediate, solvent for polymeric systems.
Definition
ChEBI: Thioanisole is an aryl sulfide that is thiophenol in which the hydrogen of the thiol group has been replaced by a methyl group. It is an aryl sulfide and a member of benzenes. It is functionally related to a thiophenol.
Aroma threshold values
Aroma characteristics at 0.1% EtoH: toluene solvent, spicy, pungent, woody sawdust.
Taste threshold values
Taste characteristics at .02 to 0.5 ppm: solventy, woody, roasted coffee.
Synthesis Reference(s)
Journal of the American Chemical Society, 112, p. 186, 1990 DOI: 10.1021/ja00157a030
The Journal of Organic Chemistry, 33, p. 4290, 1968 DOI: 10.1021/jo01275a070
Flammability and Explosibility
Non flammable
Thioanisole Preparation Products And Raw materials
Raw materials
Preparation Products
Thioanisole Suppliers
- Tel
- --
- Fax
- --
- info@acros.com
- Country
- Belgium
- ProdList
- 6772
- Advantage
- 81
- Tel
- --
- Fax
- --
- nfo@alkemi.be
- Country
- Belgium
- ProdList
- 2201
- Advantage
- 58
- Tel
- --
- Fax
- --
- fo@acros.com
- Country
- Belgium
- ProdList
- 3824
- Advantage
- 58
View Lastest Price from Thioanisole manufacturers
- Product
- Methyl phenyl sulfide 100-68-5
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-22
- Product
- Thioanisole 100-68-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 10ton
- Release date
- 2024-07-22
- Product
- 2-Chloropyrazine 100-68-5
- Price
- US $10.00/PCS
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2021-03-15