ChemicalBook > CAS DataBase List > 3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96

3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96

Product Name
3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96
CAS No.
16205-98-4
Chemical Name
3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96
Synonyms
3-Carboxycyclohexan-1-one;1-Carboxy-3-oxocyclohexane;3-oxocyclohexanecarboxylate;3-Ketocyclohexyl carboxylate;3-Cyclohexanone carboxylic acid;3-oxo-cyclohexanecarboxylic acid;Cyclohexanecarboxylic acid, 3-oxo-;O**3-OXO-1-CYCLOHEXANECARBOXYLIC ACID;3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96
CBNumber
CB7499777
Molecular Formula
C7H10O3
Formula Weight
142.15
MOL File
16205-98-4.mol
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3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96 Property

Melting point:
76 °C
Boiling point:
309.7±35.0 °C(Predicted)
Density 
1.233±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
solid
pka
4.72±0.20(Predicted)
color 
White
InChI
InChI=1S/C7H10O3/c8-6-3-1-2-5(4-6)7(9)10/h5H,1-4H2,(H,9,10)
InChIKey
WATQNARHYZXAGY-UHFFFAOYSA-N
SMILES
C1(C(O)=O)CCCC(=O)C1
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Safety

WGK Germany 
3
HS Code 
2918300090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
550515
Product name
3-Oxo-1-cyclohexanecarboxylic acid
Purity
93%
Packaging
1g
Price
$272
Updated
2023/06/20
TRC
Product number
O991185
Product name
3-Oxocyclohexanecarboxylicacid
Packaging
25mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
8202AA
Product name
3-Oxocyclohexanecarboxylicacid
Packaging
250mg
Price
$141
Updated
2021/12/16
Oakwood
Product number
022944
Product name
3-Oxo-1-cyclohexanecarboxylic acid
Packaging
250mg
Price
$143
Updated
2021/12/16
AK Scientific
Product number
8202AA
Product name
3-Oxocyclohexanecarboxylicacid
Packaging
1g
Price
$267
Updated
2021/12/16
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3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96 Chemical Properties,Usage,Production

Uses

3-Oxo-1-cyclohexanecarboxylic acid (3-oxocyclohexanecarboxylic acid) may be used in the preparation of 9-(4-chlorobenzoyl)-6-methoxy-2,3,4,9-tetrahydro-1H-carbazole-2-carboxylic acid by reacting with 4-chloro-N-(4-methoxyphenyl)benzohydrazide hydrochloride via Fischer indolization.

General Description

3-Oxo-1-cyclohexanecarboxylic acid is a cyclic keto acid that can be prepared starting from 2-acetoxy-1,4-ethoxycarbonylcyclohex-1-ne.

Synthesis

606488-94-2

16205-98-4

Preparation of Jones oxidizing reagent: Jones reagent was prepared by mixing sulfuric acid (30 mL), CrO3 (8.1 g) and H2O (30 mL) under ice/water bath conditions. The prepared Jones reagent was slowly added dropwise to a solution of 3-hydroxycyclohexane-1-carboxylic acid (11 g, 76.3 mmol, 1.00 eq.) in acetone (150 mL) over 30 min at 0 °C. After the dropwise addition was completed, the reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, the solid impurities were removed by filtration. The filtrate was extracted with dichloromethane (3 x 100 mL). The organic layers were combined, washed with brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give the crude 3-oxocyclohexane-1-carboxylic acid (8.7 g) as a yellow oil.

References

[1] Patent: WO2014/11902, 2014, A1. Location in patent: Paragraph 00282-00283
[2] Patent: WO2014/194242, 2014, A2. Location in patent: Paragraph 00353; 00355

3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96 Preparation Products And Raw materials

Raw materials

Preparation Products

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3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96 Suppliers

China 83 India 4 Switzerland 1 United Kingdom 2 United States 11 Global 101
A.J Chemicals
Tel
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Fax
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Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
Avra Synthesis Pvt Ltd
Tel
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Fax
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Email
info@avrasynthesis.com
Country
India
ProdList
1603
Advantage
30
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View Lastest Price from 3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96 manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
3-Oxocyclohexanecarboxylic acid 16205-98-4
Price
US $3.00-9.00/KG
Min. Order
0.1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-06-24
Shanghai Yongzeng Technology Co.,Ltd
Product
3-Oxocyclohexane-1-carboxylic acid 16205-98-4
Price
US $0.00/gm
Min. Order
100gm
Purity
99%min
Supply Ability
100kgs
Release date
2024-09-09
Pharmahands (Taizhou) Co., Ltd.
Product
3-Oxo-1-Cyclohexanecarboxylic Acid 16205-98-4
Price
US $0.00-0.00/Kg/Drum
Min. Order
1g
Purity
99%
Supply Ability
200KG/MONTH
Release date
2020-11-09

16205-98-4, 3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96Related Search:

3-Oxo-cyclopentanecarbonitrile Diethyl succinosuccinate prohexadione-calcium 2,5-dioxo-1,4-cyclohexanedicarboxylic acid dimethyl ester DIETHYL 2,5-DIOXOBICYCLO[2.2.2]OCTANE-1,4-DICARBOXYLATE 3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96 Trinexapac-ethyl 4,7,7-TRIMETHYL-2,3-DIOXOBICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID 4-ACETYL-3,5-DIOXO-1-METHYLCYCLOHEXANECARBOXYLIC ACID ETHYL 3-OXOCYCLOHEXANE-1-CARBOXYLATE PROHEXADIONE RARECHEM AL BO 1792 2-BROMO-4,7,7-TRIMETHYL-3-OXOBICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID 4-ACETYL-3,5-DIOXO-CHA(1-ME, 1-COOH) IFLAB-BB F1052-0005 AKOS BBS-00001947 AKOS BBS-00001972 ANTI-3-OXOTRICYCLO[2.2.1.0(2,6)]HEPTANE-7-CARBOXYLIC ACID

  • 3-OXO-1-CYCLOHEXANECARBOXYLIC ACID 96
  • 3-oxo-cyclohexanecarboxylic acid
  • 3-Ketocyclohexyl carboxylate
  • 3-Carboxycyclohexan-1-one
  • 3-oxocyclohexanecarboxylate
  • Cyclohexanecarboxylic acid, 3-oxo-
  • 1-Carboxy-3-oxocyclohexane
  • O**3-OXO-1-CYCLOHEXANECARBOXYLIC ACID
  • 3-Cyclohexanone carboxylic acid
  • 16205-98-4
  • C6H9OCO2H
  • Carboxylic Acids
  • Carboxylic Acids
  • Ring Systems
  • C7
  • Carbonyl Compounds