(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&

Reaction

Product Name: (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
CAS No.: 307926-51-8
Chemical Name: (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
Synonyms: (S,S)Salen AI;(S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-;(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride,98%;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%;Aluminum,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (9CI)
CBNumber: CB7504613
Molecular Formula: C36H52AlClN2O2
Formula Weight: 607.254
MOL File: 307926-51-8.mol

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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Property

Melting point:: >350 °C(lit.)
form: Powder
color: yellow

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 531979
Product name: (S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Packaging: 1g
Price: $82.4
Updated: 2024/03/01

Strem Chemicals

Product number: 13-5801
Product name: (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
Packaging: 1g
Price: $186
Updated: 2024/03/01

Strem Chemicals

Product number: 13-5801
Product name: (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
Packaging: 5g
Price: $741
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0000048
Product name: (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
Purity: 95.00%
Packaging: 1G
Price: $671.25
Updated: 2021/12/16

Ambeed

Product number: A913279
Product name: (S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
Purity: 98%
Packaging: 25g
Price: $1365
Updated: 2021/12/16

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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Chemical Properties,Usage,Production

Reaction

Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
Catalyst used for the asymmetric hydrocyanation of nitroolefins.
Catalyst used in the reaction of epoxides with heterocumulenes.

Uses

(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:

In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
In the cyanation of α,β-unsaturated imides to yield saturated imides.

(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Preparation Products And Raw materials

Raw materials

Preparation Products

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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Suppliers

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307926-51-8, (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&Related Search:

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE

(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&

(S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-

(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%

(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride

(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride

(S,S)Salen AI

Aluminum,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (9CI)

(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride

(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%

(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride,98%

307926-51-8

Jacobsen Metal